1-[Bis(4-fluorophenyl)methyl]-4-[[4-[bis(4-fluorophenyl)methyl]phenyl]methyl]benzene | 1310713-66-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 1-[Bis(4-fluorophenyl)methyl]-4-[[4-[bis(4-fluorophenyl)methyl]phenyl]methyl]benzene
• 英文别名: 1-[bis(4-fluorophenyl)methyl]-4-[[4-[bis(4-fluorophenyl)methyl]phenyl]methyl]benzene
• CAS: 1310713-66-6
• 化学式: C₃₉H₂₈F₄
• 分子量: 572.645
• InChiKey: XYCBWUUJPBEREZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  43
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,4'-二氟二苯甲烷 在 三氟甲磺酸 、 tetrabutylammonium tetrafluoroborate 作用下， 以 二氯甲烷 为溶剂， 反应 1.83h， 生成 1-[Bis(4-fluorophenyl)methyl]-4-[[4-[bis(4-fluorophenyl)methyl]phenyl]methyl]benzene
  参考文献：
  名称：

  Electrochemical synthesis of dendritic diarylcarbenium ion pools

  摘要：

  Dendritic diarylcarbenium ion pools were synthesized by the low temperature electrochemical oxidation of the corresponding dendritic (diarylmethyl)trimethylsilanes, which were prepared by use of the iterative method consisting of electrochemical activation and Friedel Crafts type coupling. Time-course NMR studies revealed that thermal stability of dendritic diarylcarbenium ions depends both on the generation of the dendritic structure and on the para-substituents of the terminal phenyl groups. Dendritic diarylcarbenium ions up to the third generation exhibited high reactivity as a carbon electrophile. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.04.065

文献信息

• Electrochemical synthesis of dendritic diarylcarbenium ion pools
  作者：Toshiki Nokami、Takashi Watanabe、Naoki Musya、Takafumi Suehiro、Tatsuya Morofuji、Jun-ichi Yoshida

  DOI：10.1016/j.tet.2011.04.065

  日期：2011.6

  Dendritic diarylcarbenium ion pools were synthesized by the low temperature electrochemical oxidation of the corresponding dendritic (diarylmethyl)trimethylsilanes, which were prepared by use of the iterative method consisting of electrochemical activation and Friedel Crafts type coupling. Time-course NMR studies revealed that thermal stability of dendritic diarylcarbenium ions depends both on the generation of the dendritic structure and on the para-substituents of the terminal phenyl groups. Dendritic diarylcarbenium ions up to the third generation exhibited high reactivity as a carbon electrophile. (C) 2011 Elsevier Ltd. All rights reserved.