1-[3,5-bis(1-aminoethyl)phenyl]ethan-1-amine | 108903-62-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-[3,5-bis(1-aminoethyl)phenyl]ethan-1-amine
• 英文别名: 1,3,5-tris-(1-amino-ethyl)-benzene；1,3,5-Tris-(1-amino-aethyl)-benzol；1-[3,5-Bis(1-aminoethyl)phenyl]ethanamine
• CAS: 108903-62-4
• 化学式: C₁₂H₂₁N₃
• 分子量: 207.319
• InChiKey: BNAQTBZMMRXRAH-UHFFFAOYSA-N

物化性质

• 沸点：
  316.9±37.0 °C(Predicted)
• 密度：
  1.030±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  78.1
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  三乙酰基苯 在 乙醇 、 氨 作用下， 120.0 ℃ 、14.71 MPa 条件下， 生成 1-[3,5-bis(1-aminoethyl)phenyl]ethan-1-amine
  参考文献：
  名称：

  DE949566

  摘要：

  公开号：

文献信息

• Polyolefin polymer with good mechanical properties
  申请人：DSM N.V.

  公开号：EP0856542A1

  公开（公告）日：1998-08-05

  Polyolefin polymer in the form of a comb, star, nanogel or structural combinations thereof comprising a plurality of polyolefin arms, each independently selected from the group consisting of homo- and copolymers of substituted and unsubstituted 1-alkenes, coupled to a polymeric backbone, said backbone having repeating units containing a group selected from the group consisting of aliphatic groups, aromatic groups, heteroatom-containing groups and combinations thereof, the polyolefin polymer having a weight average molecular weight (Mw) of at least 250*103 g/mol and less than 800*103 g/mol, the polyolefin arm, before coupling, having a molecular weight (Mw) of at least 20*103 g/mol, the ratio between the molecular weight (Mw) of the polyolefin polymer and the molecular weight of the polyolefin arm, before coupling, (Mw, polymer/Mw, arm) being higher than 2 and the molecular weight distribution of the polyolefin arm, before coupling, being at least 2 and at most 20.

  梳状、星形、纳米凝胶或其结构组合形式的聚烯烃聚合物，包括多个聚烯烃臂，每个聚烯烃臂均独立地选自取代和未取代的 1-烯的均聚物和共聚物组成的组，与聚合物骨架偶联，所述骨架具有重复单元，重复单元含有选自脂肪族基团、芳香族基团、含杂原子基团及其组合组成的组的基团、聚烯烃聚合物的重量平均分子量（Mw）至少为 250*103 g/mol，小于 800*103 g/mol，偶联前聚烯烃臂的分子量（Mw）至少为 20*103 g/mol，聚烯烃聚合物的分子量（Mw）与偶联前聚烯烃臂的分子量之比（Mw，聚合物/Mw，臂）大于 2，偶联前聚烯烃臂的分子量分布至少为 2，最多为 20。
• Polyolefin polymer with high molecular weight
  申请人：DSM N.V.

  公开号：EP0856545A1

  公开（公告）日：1998-08-05

  Polyolefin polymer with high molecular weight in the form of a comb, star, nanogel or structural combinations thereof comprising a plurality of polyolefin arms each independently selected from the group consisting of homo- and copolymers of substituted and unsubstituted 1-alkenes linked to a polymer backbone, said backbone having repeating units containing a group selected from the group consisting of aliphatic groups, aromatic groups, heteroatom-containig groups and combinations thereof, in which the polyolefin polymer has a molecular weight (Mw) of at least 0.8*106 g/mol, the polyolefin arm has a molecular weight (Mw) of at least 5*103 g/mol. The ratio between the molecular weight (Mw) of the polyolefin polymer and the molecular weight (Mw) of the pre-arm (Mw, polymer/Mw, pre-arm) is at least 4 and the molecular weight distribution of the pre-arm is at least 4 and at most 20.

  具有高分子量的梳状、星状、纳米凝胶状或其结构组合形式的聚烯烃聚合物，包括多个各自独立选自与聚合物骨架相连的取代和未取代 1-烯的均聚物和共聚物组成的组的聚烯烃臂，所述骨架具有包含选自脂肪族基团、芳香族基团、含杂原子基团及其组合组成的组的基团的重复单元，其中聚烯烃聚合物的分子量（Mw）至少为 0.8*106 g/mol，聚烯烃臂的分子量（Mw）至少为 5*103 g/mol。聚烯烃聚合物的分子量（Mw）与预臂的分子量（Mw）之比（Mw，聚合物/Mw，预臂）至少为 4，预臂的分子量分布至少为 4，最多为 20。
• Structural Aspects of Nucleation Inhibitors for Diastereomeric Resolutions and the Relationship to Dutch Resolution
  作者：Michel Leeman、Giuseppina Brasile、Edith Gelens、Ton Vries、Bernard Kaptein、Richard Kellogg

  DOI：10.1002/anie.200704021

  日期：2008.2.1
• PROCESS FOR THE PREPARATION OF A DENDRITIC MACROMOLECULE
  申请人：DSM N.V.

  公开号：EP0707611B1

  公开（公告）日：1997-09-10
• [EN] PROCESS FOR THE PREPARATION OF A DENDRITIC MACROMOLECULE<br/>[FR] PROCEDE DE PREPARATION D'UNE MACROMOLECULE DENDRITIQUE
  申请人：DSM N.V.

  公开号：WO1995002008A1

  公开（公告）日：1995-01-19

  (EN) The invention relates to a process for the preparation of a dendritic macromolecule, wherein an amount of a core molecule comprising at least one functional group is dissolved in a solvent, after which alternatingly an addition reaction and a hydrogenation reaction are carried out, during the addition reaction vinyl cyanide units being added to the solution which react with the functional groups in such a manner that a dendritic macromolecule with terminal cyanide groups is formed, and during the hydrogenation reaction the cyanide groups being reduced in solution by means of hydrogen and a suitable catalyst in such a manner that functional amine groups are formed, wherein the solvent in which the hydrogenation reaction takes place is an alcohol which contains an amount of ammonia, the molar ratio between the amount of ammonia and the number of cyanide groups being higher than 0.8.(FR) Procédé de préparation d'une macromolécule dendritique, consistant à dissoudre dans un solvant une certaine quantité d'une molécule de noyau comportant au moins un groupe fonctionnel, puis à réaliser en alternance une réaction d'addition et une réaction d'hydrogénation. Pendant la réaction d'addition, on ajoute à la solution des motifs de cyanure vinylique qui réagissent avec les groupes fonctionnels de manière à former une macromolécule dendritique à groupes cyanures terminaux. Pendant la réaction d'hydrogénation, les groupes cyanures sont réduits en solution par hydrogène et par un catalyseur approprié de manière à former des groupes aminés fonctionnels. Le solvant dans lequel se déroule la réaction d'hydrogénation est un alcool renfermant une certaine quantité d'ammoniac, le rapport molaire entre la quantité d'ammoniac et le nombre de groupes cyanures étant supérieur à 0,8.