2,2',2''-trimethyl-4,4',4''-methanetriyl-tri-phenol | 146368-30-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 2,2',2''-trimethyl-4,4',4''-methanetriyl-tri-phenol
• 英文别名: 2,2',2''-Trimethyl-4,4',4''-methantriyl-tri-phenol；4.4'.4''-Trioxy-3.3'.3''-trimethyl-triphenylmethan；1,1,1-tris(3-methyl-4-hydroxyphenyl)-methane；tris(3-methyl-4-hydroxyphenyl)methane；4-[Bis(4-hydroxy-3-methylphenyl)methyl]-2-methylphenol
• CAS: 146368-30-1
• 化学式: C₂₂H₂₂O₃
• 分子量: 334.415
• InChiKey: ZGMJQQCFUSKSNH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,2',2''-trimethyl-4,4',4''-methanetriyl-tri-phenol 、 乙酸酐 在 sodium acetate 作用下， 生成 tris-(4-acetoxy-3-methyl-phenyl)-methane
  参考文献：
  名称：

  Debasement and faking bad on the Millon Clinical Multi-axial Inventory III: An examination of characteristics, circumstances and motives of forensic patients

  摘要：

  Purpose. This article constitutes the first effort to consider debasement employing the Millon Clinical Multi‐axial Inventory III (MCMI‐III) in a forensic clinical population and incorporating the recommendations of Van Denburg and Choca (1997). It considers the proposition (Rogers, 1990a) that the pathogenic and criminological models of malingering can be rejected in favour of the adaptional model. Methods. A total of 142 MCMI‐III profiles were collected over a 17‐month period by a forensic psychology service. Of these, 47 had Debasement scale scores greater than 74. From the remaining 75, a group of 47 were randomly selected for comparative purposes. Of the total sample there were 75 males and 19 females, 68 were out‐patients and 26 were in‐patients, the latter having been detained under the Mental Health Act 1983, applicable to England and Wales. The two groups were compared on personality variables, offending history, presenting problems and referral circumstances. Results. There is tentative support for Rogers (1990a) in that situational variables appear to have a significant impact on debasement as would be predicted by the adaptional model of malingering. However, this was insufficient evidence to reject the pathogenic and criminological models of malingering. Conclusions. It is suggested that a longitudinal study examining the impact of different stages of the mental health or criminal justice system on debasement, and other validity scales, would illuminate the adaptional model further. Factors that influence the inclination to exaggerate psychopathology and which could be manipulated experimentally are also noted. Some speculation about the possible combined use of Debasement and Histrionic, Narcissistic and Compulsive scales in distinguishing between malingerers is offered.

  DOI：

  10.1348/135532500167985
• 作为产物：
  描述：

  tris(4-hydroxy-3-morpholinomethylphenyl)methane 在 palladium 10% on activated carbon 氢气 作用下， 以 异丙醇 为溶剂， 127.0~130.0 ℃ 、1.32 MPa 条件下， 反应 3.0h， 以99.2%的产率得到2,2',2''-trimethyl-4,4',4''-methanetriyl-tri-phenol
  参考文献：
  名称：

  METHOD OF PRODUCING POLY(ORTHO-METHYLPHENOL)

  摘要：

  聚(正甲基苯酚)可通过工业过程获得高纯度和高收率，方法是首先使二级胺和甲醛与多酚反应（第一步），然后在氢化催化剂的存在下通过氢解分解所得的聚(正甲基氨甲基苯酚)的氨甲基基团（第二步）。

  公开号：

  US20070197832A1

文献信息

• POLYCARBONATE RESIN COMPOSITION AND FORMED PRODUCT THEREOF
  申请人：Monden Toshiki

  公开号：US20110245388A1

  公开（公告）日：2011-10-06

  In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

  在含有聚碳酸酯树脂和聚碳硅烷化合物的聚碳酸酯树脂组合物中，使用聚碳硅烷化合物可以改变聚碳酸酯树脂组合物的表面特性，而不会对聚碳酸酯树脂的固有特性产生不利影响，如透明度、耐热性和机械性能（例如冲击强度）。含有100质量部聚碳酸酯树脂、0.001至1质量部金属盐化合物和0.005至5质量部聚碳硅烷化合物的聚碳酸酯树脂组合物具有显著提高的阻燃性和高透明度，显著减少气体排放和模具污染，同时不会损失冲击强度和耐热性。
• [EN] HIGH HEAT MONOMERS AND METHODS OF USE THEREOF<br/>[FR] MONOMÈRES À CHALEUR ÉLEVÉE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2016014536A1

  公开（公告）日：2016-01-28

  High purity epoxide compounds, methods for preparing the high purity epoxide compounds, and compositions derived from the epoxide compounds are provided. Also provided are materials and articles derived from the epoxide compounds.

  本发明提供了高纯度环氧化合物、制备高纯度环氧化合物的方法以及从环氧化合物衍生的组合物。还提供了从环氧化合物衍生的材料和物品。
• METHOD FOR PRODUCING NEW POLYNUCLEAR POLY(FORMYLPHENOL)
  申请人：Yoshitomo Akira

  公开号：US20090182175A1

  公开（公告）日：2009-07-16

  Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.

  在工业环境中，通过在酸的存在下使多核聚氢甲基酚或多核聚烷氧甲基酚与六亚甲基四胺反应，然后水解所得的反应产物，轻松高纯度地制备目标物质或由通式（2）表示的多核聚甲酰苯酚。
• Trisoxetane compound, process for producing the same, and optical waveguide using the same
  申请人：Hikita Takami

  公开号：US20070237963A1

  公开（公告）日：2007-10-11

  The present invention relates to a trisoxetane compound represented by the following formula (1): wherein R 1 and R 3 to R 8 are the same or different and each represents a hydrogen atom or an alkyl group having 1 to 6 carbon atom(s) with the proviso that at least one of R 3 to R 8 is an alkyl group having 1 to 6 carbon atom(s); R 2 represents a divalent aliphatic chained organic group having 0 to 16 carbon atom(s); and R 9 's each represents a hydrogen atom or an alkyl group having 1 to 6 carbon atom(s), a process for producing the same, and an optical waveguide including the same.

  本发明涉及一种三噁烷化合物，其表示为以下式子（1）：其中，R1和R3至R8相同或不同，每个代表氢原子或具有1至6个碳原子的烷基基团，但至少有一个R3至R8代表具有1至6个碳原子的烷基基团；R2表示具有0至16个碳原子的二价脂肪链有机基团；R9的每个代表氢原子或具有1至6个碳原子的烷基基团，还涉及其制备方法和包括其的光波导。
• Branched polycarbonate and process for production thereof
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP0411433A2

  公开（公告）日：1991-02-06

  Novel branched polycarbonates having (1) intrinsic viscosity [η], (2) branching parameter G and (3) degree of branching λ in certain ranges are disclosed. Further, novel branched polycarbonates having (4) taking-off parameter A in addition to the above (1) to (3) is in a certain range are, also disclosed. Such novel branched polycarbonates are effective as raw materials for various moldings, particularly blow moldings such as large-sized blow moldings.

  本发明公开了具有(1)固有粘度[η]、(2)支化参数 G 和(3)支化度 λ 在一定范围内的新型支化聚碳酸酯。此外，还公开了除上述(1)至(3)之外，(4)起飞参数 A 在一定范围内的新型支化聚碳酸酯。 此类新型支化聚碳酸酯可有效用作各种模塑的原材料，尤其是吹塑模塑，如大型吹塑模塑。