(n-Bu4N)(ReOCl4(H2O)) | 128955-64-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (n-Bu4N)(ReOCl4(H2O))
• CAS: 128955-64-6
• 化学式: C₁₆H₃₆N*Cl₄H₂O₂Re
• 分子量: 604.502
• InChiKey: FBGMHOMUTVQIJT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (n-Bu4N)(ReOCl4(H2O)) 、 2-(((3-(diphenylphosphaneyl)propyl)amino)methyl)phenol 以 甲醇 为溶剂， 以10%的产率得到
  参考文献：
  名称：

  Complexes of rhenium(V) with tridentate ligands having o, n and p donor atoms. The x-ray crystal structures of ReOCl2[OC6H4-2-CHN(CH2)3PPh2] and its reduced counterpart ReOCl2[OC6H4-2-CH2NH(CH2)3PPh2]

  摘要：

  The tridentate ligand HOC6H4-2-CH2NH(CH2)3PPh2, which contains both "hard" and "soft" potential donor atoms, has been synthesized along with its rehenium(V) complex ReOCl2[OC6H4-2-CH2NH(CH2)3PPh2]. Single crystal X-ray diffraction studies show that this molecule has a qualitatively similar structure to its Schiff base counterpart ReOCl2[OC6H4-2-CH = N(CH2)3PPh2], despite the change in bonding at the central ligating nitrogen atom from sp3 to sp2. At a more detailed level, significant differences in structural parameters are found to occur. In both cases the coordination site trans to the Re = O oxygen [Re = O = 1.680(7) and 1.695(9) angstrom, respectively] is occupied by the phenolic oxygen [Re-O = 1.943(7) and 1.953(9) angstrom, respectively] and the rhenium atom has a distorted octahedral coordination environment. The Re-N distance lengthens on reduction of the ligand [Re-N(H)- = 2.224(8) angstrom, Re-N = = 2.111(11) angstrom] while the Re-N = C(sp2.) bond angle decreases by 12.7-degrees on reduction.

  DOI：

  10.1016/s0277-5387(00)81595-8

文献信息

• The synthesis and X-ray crystal structure of the trinuclear complex [{ORe(OC6H4-2-CMeNCH2-)2(-μ-O)} 2Re(OC6H4-2-CMeNCH2-)2]Cl· H2O·0.5CH2Cl2ag]
  作者：Hilary J. Banbery、Ferida S. McQuillan、Thomas A. Hamor、Christopher J. Jones、Jon.A. McCleverty

  DOI：10.1016/s0020-1693(00)80404-1

  日期：1990.4
• Incomplete coordination to rhenium(V) by a facultative quinquedentate ligand. The x-ray crystal structure of [ReO(OMe){2′-(NC4H3-2-CHN(CH2)3NMe(Ch2)3CHN)C4H3NH}]PF6
  作者：Hilary J. Banbery、Ferida S. McQuillan、Thomas A. Hamor、Christopher J. Jones、Jon A. McCleverty

  DOI：10.1016/s0277-5387(00)86242-7

  日期：1990.1