thiomethylphenol | 468055-59-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: thiomethylphenol
• 英文别名: thio-o-cresol；Thio-salicylaldehyde；2-hydroxythiobenzaldehyde
• CAS: 468055-59-6
• 化学式: C₇H₆OS
• 分子量: 138.19
• InChiKey: NTJTUMLSEVWWTI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  香叶基溴 、 thiomethylphenol 生成 3,7-dimethyl-octa-2,6-dienyl o-tolyl sulphide
  参考文献：
  名称：

  Phenyl derivatives

  摘要：

  苯氧基、苯基亚砜基、苯基硫基、苯基磺基、苄氧基、苄硫基、苄亚砜基或苄磺基、烷基或烯基衍生物，其中烷基或烯基基团含有至少7个碳原子，可用于通过扰乱昆虫激素平衡来杀灭和防止昆虫的增殖。

  公开号：

  US03944531A1

文献信息

• [EN] THIO-SALALEN CATALYST<br/>[FR] CATALYSEUR THIO-SALALEN
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2014204624A1

  公开（公告）日：2014-12-24

  Catalysts comprising thio-salalen ligands. Also, catalyst systems comprising the catalyst and an activator; methods to prepare the ligands, catalysts and catalyst systems; processes to polymerize olefins using the catalysts and/or catalyst systems; and the olefin polymers prepared according to the processes.

  含有硫代萨雷伦配体的催化剂。还有包括催化剂和活化剂的催化剂体系；制备配体、催化剂和催化剂体系的方法；使用这些催化剂和/或催化剂体系聚合烯烃的工艺；以及根据这些工艺制备的烯烃聚合物。
• METHOD FOR PREPARING THIOMETHYLPHENOLS
  申请人：Lee Hyung-Jae

  公开号：US20080081929A1

  公开（公告）日：2008-04-03

  The present invention relates to a process for preparing thiomethylphenol derivatives, and particularly to a simple process of preparing thiophenol derivatives by performing a reaction of a phenol derivative, a mercaptan derivative and paraformaldehyde in a solvent in the presence of a given amount of heterocyclic amine base and acids, thereby capable of maintaining a mild reaction condition and providing thiomethylphenol derivatives with an improved discoloration by purification using acids.

  本发明涉及一种制备硫代甲基苯衍生物的方法，特别是一种简单的方法，通过在溶剂中在异环胺碱和酸的存在下，将苯酚衍生物、巯基衍生物和多聚甲醛反应，从而能够保持温和的反应条件，并通过使用酸进行纯化，提供具有改善褪色性能的硫代甲基苯衍生物。
• Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
  申请人：Mitsui Chemicals, Inc.

  公开号：US20030004290A1

  公开（公告）日：2003-01-02

  An olefin polymerization catalyst having a high polymerization activity at high temperatures and a process for olefin polymerization using the catalyst are disclosed. The olefin polymerization catalyst comprises a transition metal compound which is represented by the following formula (I) and in which the net charge parameter of the central metal is not more than 2.00 . 1 wherein M is a transition metal atom of Group 4 to Group 5 of the periodic table, m is an integer of 1 to 5, Q is —N═or —C(R 2 )═, A is —0—, —S—, —Se— or —N(R 5 )—, R 1 is an aliphatic hydrocarbon group or an alicyclic hydrocarbon group, R 2 to R 5 are each a hydrogen atom, a hydrocarbon group, an oxygen-containing group or the like, n is a number satisfying a valence of M, and X is a hydrogen atom, a halogen atom, a hydrocarbon group or the like.

  本文披露了一种在高温下具有高聚合活性的烯烃聚合催化剂及使用该催化剂进行烯烃聚合的方法。该烯烃聚合催化剂包括一种过渡金属化合物，其由下式(I)表示，其中中心金属的净电荷参数不超过2.00.1，M是周期表中第4至第5族的过渡金属原子，m是1至5的整数，Q是—N═或—C(R2)═，A是—0—、—S—、—Se—或—N(R5)—，R1是脂肪烃基或脂环烃基，R2到R5分别是氢原子、烃基、含氧基团或类似物，n是满足M的价的数字，X是氢原子、卤素原子、烃基或类似物。
• 3'-or 2'-hydroxymethyl substituted nucleoside derivatives for treatment of hepatites virus infections
  申请人：——

  公开号：US20020055483A1

  公开（公告）日：2002-05-09

  The present invention relates to a composition for and a method of treating hepatitis B virus (HBV) infection, hepatitis C virus (HCV) infection, hepatitis D virus (HDV) infection or a proliferative disorder in a patient using an effective amount of a compound selected from the group consisting of formulas [I]- [IV] below and mixtures of two or more thereof: 1 wherein the substituents are as defined herein. Pharmaceutical compositions comprising these compounds in combination with other HBV, HCV, or HDV agents is also disclosed.

  本发明涉及一种用于治疗患有乙型肝炎病毒（HBV）感染、丙型肝炎病毒（HCV）感染、丁型肝炎病毒（HDV）感染或患有增生性疾病的患者的组合物和方法，所述方法使用从下面的公式I-IV中选择的化合物或两个或两个以上化合物的混合物的有效量：其中，取代基如本文所定义。还公开了包含这些化合物与其他HBV、HCV或HDV药物组合的制药组合物。
• Ethylene (co) polymer and its use
  申请人：Takahashi Mamoru

  公开号：US20060047096A1

  公开（公告）日：2006-03-02

  An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13 C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR −0.192 in the case of MFR<1 and the relation; [η]>1.85×MFR −0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.

  本发明的乙烯(co)聚合物是一种具有优异的成型性和机械性能的(co)聚合物，可以是乙烯均聚物或乙烯和4至20个碳原子的α-烯烃的共聚物。该(co)聚合物在13C-NMR下测量，每1,000个碳原子的甲基支链少于0.1个，并且在GPC下测量的Mw/Mn不低于1.8且低于4.5。该(co)聚合物可以是乙烯均聚物或乙烯和3至20个碳原子的α-烯烃的共聚物。熔融张力(MT)和膨胀比(SR)满足关系式; log(MT)>12.9−7.15×SR; 内禀粘度([η])和熔体流动速率(MFR)满足关系式; 当MFR<1时，[η]>1.85×MFR−0.192，当MFR≧1时，[η]>1.85×MFR−0.213。这种乙烯(co)聚合物可用于各种成型应用，特别适用于管道。