[O=ReTPP]2O | 128709-68-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: [O=ReTPP]2O
• 英文别名: μ-oxo-bis[(oxo)-(5,10,15,20-tetraphenyl-21H,23H-porphinato)rhenium(V)]；μ-oxo-bis[(oxo)(5,10,15,20-tetraphenyl-21H,23H-porphinato)]rhenium(V)；μ-oxo-bis[(oxo)(5,10,15,20-tetraphenyl-21H,23H-porphinato)rhenium(V)]；(5,10,15,20-tetraphenylporphinato)chloro rhodium(III)；{ReO(TPP)}2O
• CAS: 128709-68-2
• 化学式: C₈₈H₅₆N₈O₃Re₂
• 分子量: 1645.88
• InChiKey: RKQYEOTVUFKLHV-OTNZCFKPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [O=ReTPP]2O 、 一水合肼 以 乙醇 、 氯仿 为溶剂， 以50-70的产率得到NRe(5,10,15,20-tetraphenylporphyrinate)
  参考文献：
  名称：

  Buchler, Johann W.; Cian, Andre de; Fischer, Jean, Chemische Berichte, 1990, vol. 123, p. 2247 - 2254

  摘要：

  DOI：
• 作为产物：
  描述：

  benzoato(5, 10, 15, 20-meso-tetraphenylporphyrinato)oxo-rhenium 以 二氯甲烷 为溶剂， 以95 %的产率得到[O=ReTPP]2O
  参考文献：
  名称：

  一种合成含氧铼 (V) 卟啉的新策略：合成、表征、理论计算和电化学方面

  摘要：

  开发了一种新的合成程序，用于使用熔融苯甲酸制备氧代-铼 (V) 卟啉。在这里，我们使用三种代表性化合物证明了这种方法，即 O=Re V (TPP)(OOCPh) ( 1 )、O=Re V (TMP)(OOCPh) ( 2 ) 和 O=Re V (TCP)(OOCPh) ( 3 ) [其中 TPP = 5,10,15,20- meso -四苯基卟啉，TMP = 5, 10, 15, 20 -meso-四（对甲氧基）苯基卟啉和 TCP = 5, 10, 15, 20- meso -四（p-氯）苯基卟啉]。收益率高于之前报道的任何其他方法。所有化合物都通过 C、H 和 N 微量分析、ESI-MS、IR、UV-vis 和1 H NMR 光谱技术进行了很好的表征。用吡啶、咪唑、地尔等温和碱处理。NH 4 OH 化合物 1 立即转化为µ -oxo 桥联二聚氧铼 (V) 络合物µ -O-[ReO(TPP)]

  DOI：

  10.1016/j.ica.2022.121344

文献信息

• Use of chemical kinetics for the description of metal porphyrin reactivity
  作者：Tatyana N. Lomova、Mariya E. Klyueva、Elena Yu. Tyulyaeva、Nataliya G. Bichan

  DOI：10.1142/s1088424612500769

  日期：2012.9

  chemical kinetics receptions, approaches and methods for the study of porphyrins and their metal complexes reactivity are discussed on an example of oxidation, acid-basic, and catalytic reactions of rhodium, palladium, and rhenium complexes of porphyrin in liquid solutions. The peculiarity of the porphyrin reaction rates is analyzed in a brief context of general provisions of the chemical kinetics. The

  以卟啉的铑、钯和铼配合物在液体溶液中的氧化、酸碱和催化反应为例，讨论了使用化学动力学接收、方法和方法研究卟啉及其金属配合物反应性的结果. 在化学动力学一般规定的简要背景下分析了卟啉反应速率的特殊性。显示了在定义金属卟啉参与的反应动力学方程时使用准平稳性原理的机会。探讨了从过程动力学描述到考虑其机理的转变。
• Buchler, Johann W.; Kruppa, Steffen B., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1990, vol. 45, # 4, p. 518 - 530
  作者：Buchler, Johann W.、Kruppa, Steffen B.

  DOI：——

  日期：——
• The state of 5,10,15,20-tetraphenyl-21H,23H-porphine rhenium(V) complexes in solutions of acids
  作者：E. Yu. Tyulyaeva、N. G. Bichan、T. N. Lomova

  DOI：10.1134/s0036023613110223

  日期：2013.11

  The spectral properties (UV/Vis, IR, H-1 NMR) and stability of diverse forms of 5,10,15,20-tetraphenyl-21H,23H-porphine rhenium(V) complexes in neutral and protolytic solvents have been studied. Quantitative characteristics have been obtained for the reactions of formation and interconversion of the mu-oxo dimeric and monomeric rhenium(V) complex species in the benzene-AcOH system and dissociation at the coordination center of the H+-associated form of the monomeric rhenium(V) complex in mixed H2O-H2SO4 solvents in a wide range of component concentrations. It has been shown that the stability of the coordination center of the rhenium(V) complexes sharply depends on the nature of a second acido ligand, in addition to the coordinated porphyrin.
• Coordination of 5,10,15,20-tetraphenyl-21H,23H-porphin by rhenium in various oxidation states
  作者：E. Yu. Tyulyaeva、N. G. Bichan、T. N. Lomova、E. G. Mozhzhukhina

  DOI：10.1134/s0036023612090203

  日期：2012.9

  A method was developed for the synthesis of three rhenium complexes, (5,10,15,20-tetraphenyl-21H,23H-porphinato)(phenoxo)rhenium(III) (PhO)ReTPP, (5,10,15,20-tetraphenyl-21H,23H-porphi-nato)(chloro)rhenium(III) (Cl)ReTPP, and mu-oxo-bis[(oxo)-(5,10,15,20-tetraphenyl-21H,23H-porphi-nato)rhenium(V)] [O=ReTPP](2)O, by one reaction between porphyrin H2TPP and H2ReCl6 in boiling phenol. In the complex formation reaction accompanied by the redox process, only the metal cation is involved in the transformation. Rhenium(IV) as chlororhenic acid dispropoportionates without participation of solvent or porphyrin to give Re(III) and Re(V) complexes. The chemical structures of the products were established by spectral and elemental analysis. Characteristics of the UV, Vis, IR, and H-1 NMR spectra, the chromatographic mobility, and stability of the complexes were determined.
• One-pot synthesis of 5,10,15,20-tetraphenyl-21H,23H-porphyrin complexes with rhenium and iridium in various oxidation states
  作者：Tatyana N. Lomova、Elena G. Mozhzhukhina、Elena Yu. Tyulyaeva、Natalia G. Bichan

  DOI：10.1016/j.mencom.2012.06.008

  日期：2012.7

  The complexes of 5,10,15,20-tetrapheny1-21H,23H-porphyrin with Ir-I/Ir-III or Re-III/Re-V have been obtained in one-pot synthesis due to redox properties of the solvent or metal ion.