(2,4-Dimethylphenyl) 6-[4-(3-prop-2-enoyloxypropoxy)benzoyl]oxynaphthalene-2-carboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (2,4-Dimethylphenyl) 6-[4-(3-prop-2-enoyloxypropoxy)benzoyl]oxynaphthalene-2-carboxylate
• 英文别名: (2,4-dimethylphenyl) 6-[4-(3-prop-2-enoyloxypropoxy)benzoyl]oxynaphthalene-2-carboxylate
• 化学式: C₃₂H₂₈O₇
• 分子量: 524.57
• InChiKey: MAPOGOYOEVKZML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  39
• 可旋转键数：
  13
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  88.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  6-乙酰基-2-萘甲酸 在 4-二甲氨基吡啶 、 正丁胺 、 三乙胺 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 9.5h， 生成 (2,4-Dimethylphenyl) 6-[4-(3-prop-2-enoyloxypropoxy)benzoyl]oxynaphthalene-2-carboxylate
  参考文献：
  名称：

  JP5988087

  摘要：

  公开号：

文献信息

• COMPOUND CONTAINING MESOGENIC GROUP, AND MIXTURE, COMPOSITION, AND OPTICALLY ANISOTROPIC BODY USING SAID COMPOUND
  申请人：DIC Corporation

  公开号：EP3088426A1

  公开（公告）日：2016-11-02

  The present invention relates to a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a polymerizable mixture having the polymerizable compound, and a polymer, an optically anisotropic body, and a phase difference film using the polymerizable composition. According to the present invention, it is possible to obtain the optically anisotropic body and the phase difference film having satisfactory scratch resistance and adhesion, by using the polymerizable composition composed of the compound containing a mesogenic group, which includes a silicon compound at a low concentration. The polymer obtained by polymerizing the polymerizable liquid crystal composition of the present invention in a state where the composition is horizontally aligned, vertically aligned, or aligned in a hybrid manner or aligned in a cholesteric manner can be used as the optically anisotropic body having alignment performance, or as an optical compensation film, a phase difference film, a wide viewing angle film, a luminance-enhancing film, a reflective film, and a polarizing film.

  本发明涉及一种含有介原基的化合物，其中包括低浓度硅化合物、含有介原基的可聚合化合物、使用这些化合物的混合物和组合物、含有可聚合化合物的可聚合混合物以及聚合物、光学各向异性体和使用可聚合组合物的相位差薄膜。 根据本发明，通过使用由含有中生基的化合物组成的可聚合组合物（其中包括低浓度的硅化合物），可以获得具有令人满意的抗划伤性和粘附性的光学各向异性体和相位差膜。 本发明的可聚合液晶组合物在水平排列、垂直排列、混合排列或胆固醇排列的状态下聚合得到的聚合物可用作具有排列性能的光学各向异性体，或用作光学补偿膜、相位差膜、广视角膜、亮度增强膜、反射膜和偏振膜。
• Production method for polymerizable liquid crystal composition
  申请人：DIC CORPORATION

  公开号：US10196568B2

  公开（公告）日：2019-02-05

  The present invention provides a method for producing a polymerizable liquid crystal composition which produces films being uncolored and having no cissing and good alignment when applied to a substrate, and also provides a polymerizable liquid crystal composition produced by the method and an optically anisotropic body using the polymerizable liquid crystal composition. Specifically, the present invention provides a method for producing a polymerizable liquid crystal composition, the method comprising a step (I) of preparing a polymerizable solution by mixing at least one polymerizable compound having at least one polymerizable functional group and one or two or more organic solvents and heating and stirring the resultant mixture; and a step (II) of mixing the polymerizable solution with a polymerization initiator, and also provides a polymerizable liquid crystal composition produced by the method and an optically anisotropic body using the polymerizable liquid crystal composition.

  本发明提供了一种生产可聚合液晶组合物的方法，该方法生产的薄膜在涂覆到基底上时不着色、无裂缝且对位良好；本发明还提供了一种由该方法生产的可聚合液晶组合物以及使用该可聚合液晶组合物的光学各向异性体。具体地说，本发明提供了一种生产可聚合液晶组合物的方法，该方法包括步骤(I)，通过混合至少一种具有至少一种可聚合官能团的可聚合化合物和一种或两种或多种有机溶剂并加热和搅拌所得混合物来制备可聚合溶液；以及步骤(II)，将可聚合溶液与聚合引发剂混合，还提供了一种通过该方法生产的可聚合液晶组合物和一种使用该可聚合液晶组合物的光学各向异性体。
• Compound containing mesogenic group, and mixture, composition, and optically anisotropic body using said compound
  申请人：DIC Corporation

  公开号：US10473820B2

  公开（公告）日：2019-11-12

  There is provided a compound containing a mesogenic group, which includes a silicon compound at a low concentration, a polymerizable compound containing the mesogenic group, a mixture and a composition using these compounds, a polymerizable mixture having the polymerizable compound, and a polymer, an optically anisotropic body, and a phase difference film using the polymerizable composition. It is possible to obtain the optically anisotropic body and the phase difference film having satisfactory scratch resistance and adhesion, by using the polymerizable composition composed of the compound containing a mesogenic group, which includes a silicon compound at a low concentration.

  本发明提供了一种含有介原基的化合物（其中包括低浓度硅化合物）、一种含有介原基的可聚合化合物、一种使用这些化合物的混合物和组合物、一种含有可聚合化合物的可聚合混合物以及一种聚合物、一种光学各向异性体和一种使用该可聚合组合物的相位差薄膜。通过使用由包含低浓度硅化合物的含有介原基的化合物组成的可聚合组合物，可以获得具有令人满意的抗划伤性和粘附性的光学各向异性体和相位差膜。
• POLYMERIZABLE COMPOUND HAVING LATERAL SUBSTITUENT IN TERMINAL RING STRUCTURE
  申请人：Kusumoto Tetuo

  公开号：US20140080990A1

  公开（公告）日：2014-03-20

  An object of the invention is to provide a polymerizable compound having small refractive index anisotropy and having high storage stability and high alignment properties when constituting a polymerizable liquid crystal composition, and provide a polymerizable liquid crystal composition containing the polymerizable compound. Further, the object is to provide a polymer produced by polymerizing the polymerizable liquid crystal composition and an optically anisotropic body including the polymer. The present invention provides a polymerizable compound represented by general formula (I), a polymerizable liquid crystal composition containing the compound as a constituent component, and further provides a polymer produced by polymerizing the polymerizable liquid crystal composition and an optically anisotropic body including the polymer.
• US20140256896A1
  申请人：——

  公开号：US20140256896A1

  公开（公告）日：2014-09-11