1-[(tetrahydro-3-furanyl)methyl]-2-(nitroimino) imidazolidine | 174458-03-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-[(tetrahydro-3-furanyl)methyl]-2-(nitroimino) imidazolidine
• 英文别名: 1-[(tetrahydro-3-furanyl)methyl]-2-(nitroimino)-imidazolidine；1-[(Tetrahydro-3-furanyl)methyl]-2-(nitroimino)imidazolidine；N-[1-(oxolan-3-ylmethyl)imidazolidin-2-ylidene]nitramide
• CAS: 174458-03-8
• 化学式: C₈H₁₄N₄O₃
• 分子量: 214.224
• InChiKey: CZFYGUKMSVUSPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  82.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  丁酰氯 、 1-[(tetrahydro-3-furanyl)methyl]-2-(nitroimino) imidazolidine 以 乙腈 为溶剂， 生成 1-(propylcarbonyl)-2-(nitroimino)-3-[(tetrahydro-3-furanyl) methyl]imidazolidine
  参考文献：
  名称：

  Insecticidal tetrahydrofuran-compound

  摘要：

  本文披露了一种四氢呋喃化合物，其化学式表示为(1) ##STR1## 其中X.sub.1和X.sub.2分别是氢原子或甲基基团，Y是氢原子或由1至4个碳原子的低碳基（Y'）取代的羰基基团（-COY'），n为2或3，并且包含该四氢呋喃化合物作为有效成分的杀虫剂。

  公开号：

  US05614527A1
• 作为产物：
  描述：

  1-(1-propenyl)-2-nitroimino-3-[(tetrahydro-3-furanyl)methyl]imidazolidine 在 盐酸 作用下， 以 乙醇 为溶剂， 生成 1-[(tetrahydro-3-furanyl)methyl]-2-(nitroimino) imidazolidine
  参考文献：
  名称：

  Insecticidal tetrahydrofuran-compound

  摘要：

  本文披露了一种四氢呋喃化合物，其化学式表示为(1) ##STR1## 其中X.sub.1和X.sub.2分别是氢原子或甲基基团，Y是氢原子或由1至4个碳原子的低碳基（Y'）取代的羰基基团（-COY'），n为2或3，并且包含该四氢呋喃化合物作为有效成分的杀虫剂。

  公开号：

  US05614527A1

文献信息

• Oil dispersions of nAChR binding neonicotinoids
  申请人：GAT Microencapsulation GmbH

  公开号：EP2225940B1

  公开（公告）日：2014-03-12
• OIL DISPERSIONS OF nAChR BINDING NEONICOTINOIDS
  申请人：Casaña Giner Victor

  公开号：US20120004104A1

  公开（公告）日：2012-01-05

  Selective insect neonicotinoids is a class of pesticide active ingredients that share some characteristics in their chemical structures and bind to the nAChR acetylcholine receptors. Formulation of such compounds in oil suspension or oil dispersion is challenging due to their electrostatic interactions of the heteroatoms in oily media, that lead to irreversible flocculation or diminished homogeneicity and bleeding of such oil dispersions. Imidacloprid, Thiamethoxam, Thiachloprid, Nitenpyram, Acetamiprid, Clothianidin and Dinetofuran and derivatives thereof with nAChR binding ability are successfully formulated in oil suspension with the use of certain copolymeric anionic fatty-acid based dispersants, sorbitan derivatives, ionic surfactants, other non-ionic surfactants and inorganic polyvalent cationic salt dispersed in the oil. The formulations this way produced show excellent storage stability properties regarding physiochemical parameters, including stability of the neonicotinoid active ingredient, reduced bleeding, and complete redispersibility. Further, they show excellent biological efficacy due to the reduced and homogeneous particle size below 2 μm when diluted—emulsified—in water.
• US5614527A
  申请人：——

  公开号：US5614527A

  公开（公告）日：1997-03-25
• US8293733B2
  申请人：——

  公开号：US8293733B2

  公开（公告）日：2012-10-23
• [EN] OIL DISPERSIONS OF NACHR BINDING NEONICOTINOIDS<br/>[FR] DISPERSIONS DANS L'HUILE DE NÉONICOTINOÏDES SE LIANT À NACHR
  申请人：GAT MICROENCAPSULATION AG

  公开号：WO2010099965A2

  公开（公告）日：2010-09-10

  Selective insect neonicotinoids is a class of pesticide active ingredients that share some characteristics in their chemical structures and bind to the nAChR acetylcholine receptors. Formulation of such compounds in oil suspension or oil dispersion is challenging due to their electrostatic interactions of the heteroatoms in oily media, that lead to irreversible flocculation or diminished homogeneicity and bleeding of such oil dispersions. Imidacloprid, Thiamethoxam, Thiachloprid, Nitenpyram, Acetamiprid, Clothianidin and Dinetofuran and derivatives thereof with nAChR binding ability are successfully formulated in oil suspension with the use of certain copolymeric anionic fatty-acid based dispersants, sorbitan derivatives, ionic surfactants, other non-ionic surfactants and inorganic polyvalent cationic salt dispersed in the oil. The formulations this way produced show excellent storage stability properties regarding physiochemical parameters, including stability of the neonicotinoid active ingredient, reduced bleeding, and complete redispersibility. Further, they show excellent biological efficacy due to the reduced and homogeneous particle size below 2 μm when diluted -emulsified- in water.