1,1,2,2,3,3,4,4,5-nonafluorocyclohexane | 882-45-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1,1,2,2,3,3,4,4,5-nonafluorocyclohexane
• 英文别名: 1H,1H,2H-Nonafluor-cyclohexan
• CAS: 882-45-1
• 化学式: C₆H₃F₉
• 分子量: 246.075
• InChiKey: HSXGEEMQVFBDOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  十氟环己烯 在 lithium aluminium tetrahydride 、 cobalt (III) fluoride 作用下， 以 乙醚 为溶剂， 生成 1,1,2,2,3,3,4,4,5-nonafluorocyclohexane
  参考文献：
  名称：

  922.氟环己烷。第八部分。十氟环己烯的氢化铝锂还原

  摘要：

  DOI：

  10.1039/jr9630004828

文献信息

• Porous calcium fluoride, its producing method, catalyst for hydrogenation reaction, and method for producing trihydrofluorocarbon
  申请人：Sekiya Akira

  公开号：US20050080303A1

  公开（公告）日：2005-04-14

  Porous calcium fluoride having a large surface area, a method for producing the same, a catalyst (for hydrogenation reaction in particular) using the porous calcium fluoride as a carrier with superior activity, selectivity, and durability, and a method for producing trihydrofluorocarbon using the catalyst. The porous calcium fluoride having a BET surface area of 20 m 2 /g to 200 m 2 /g is prepared by reacting soda lime with hydrogen fluoride. The carried cataryst (for hydrogenation reaction in particurar) is obtained by causing a metal or metal compound to be carried on carrier formed of the porous calcium fluoride. Trihydrofluorocarbon (2) is produced by causing a fluooroalkene ( 1 ) to contact hydrogen in the presence of the catalyst for hydrogenation reaction. wherein X denotes a halogen atom, Rf 1 and Rf 2 individually denote a fluorine or a parafluoroalkyl group, and Rf 1 may be bonded to Rf 2 to form a ring.

  具有大表面积的多孔氟化钙，生产该多孔氟化钙的方法，以多孔氟化钙作为载体的催化剂（特别用于氢化反应），具有优越活性、选择性和耐久性，以及使用该催化剂生产三氟碳化氢的方法。具有20 m2/g至200 m2/g的BET表面积的多孔氟化钙是通过氢氟酸与苏打石灰反应制备的。携带的催化剂（特别用于氢化反应）是通过使金属或金属化合物携带在多孔氟化钙形成的载体上而获得的。在催化剂存在下，通过使氟烯烃（1）与氢气接触来生产三氟碳化氢（2），其中X表示卤素原子，Rf1和Rf2分别表示氟原子或对氟烷基基团，且Rf1可能与Rf2结合形成环。
• FLUORINATED, SATURATED HYDROCARBONS
  申请人：JAPAN as Represented by DIRECTOR GENERAL OF AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY

  公开号：EP0982281A1

  公开（公告）日：2000-03-01

  A fluorinated saturated hydrocarbon which is an acyclic or cyclic fluorinated saturated hydrocarbon characterized by comprising less than 95 mol% of a trihydrofluorinated saturated hydrocarbon represented by the following formula (I)         Rf1-R1-Rf2     (I) (wherein R1 represents a carbon chain in which CHF and CH2 are bound, Rf1 and Rf2 each represents a perfluoroalkyl group, a fluorine atom or a hydrogen atom, at least one thereof is a perfluoroalkyl group, and further Rf1 and Rf2 may be bound to each other to form a ring by a perfluoroalkylene chain) and the balance of a tetrahydrofluorinated saturated hydrocarbon having the same carbon number and the same carbon structure as the trihydrofluorinated saturated hydrocarbon, as represented by the following formula (II)         Rf1-R2-Rf2     (II) (wherein R2 represents a carbon chain in which CH2 and CH3 are bound, and Rf1 and Rf2 are as defined above) is provided as a fluorinated saturated hydrocarbon containing, in a high proportion, trihydrofluorocarbon which is excellent especially in the chemical stability and high in the safety for living bodies among hydrofluorocarbons (HFC) known to have zero ozone depletion potential and to have a small global warming potential.

  一种含氟饱和烃，它是一种无环或环状含氟饱和烃，其特征在于它包含 95 摩尔%以下的三氢氟饱和烃，由下式（I）表示 Rf1-R1-Rf2 (I) (其中 R1 代表结合有 CHF 和 CH2 的碳链，Rf1 和 Rf2 各自代表全氟烷基、氟原子或氢原子，其中至少一个是全氟烷基，而且 Rf1 和 Rf2 可通过全氟亚烷基链相互结合形成环) 以及与三氢氟饱和烃具有相同碳数和相同碳结构的四氢氟饱和烃的余量，如下式 (II) 所示 Rf1-R2-Rf2 (II) (其中 R2 代表结合有 CH2 和 CH3 的碳链，Rf1 和 Rf2 如上定义) 是一种含氟饱和碳氢化合物，其中含有高比例的三氢氟碳，其化学稳定性特别好，对生物体的安全性也很高，是已知的臭氧消耗潜能值为零和全球变暖潜能值较小的氢氟碳化物（HFC）之一。
• FLUORINATED HYDROCARBONS, DETERGENTS, DETERGING METHOD, POLYMER-CONTAINING FLUIDS, AND METHOD OF FORMING POLYMER FILMS
  申请人：Nippon Zeon Co., Ltd.

  公开号：EP0994089A1

  公开（公告）日：2000-04-19

  Providing a fluorinated hydrocarbon with excellent cleaning action, incombustibility and high stability in alkali or water and heat; and a polymer-containing solution prepared by dissolving or dispersing a polymer with film-forming potency, preferably a fluoropolymer, in a solvent containing trihydrofluorocarbon. More specifically, a fluorinated hydrocarbon containing trihydrofluorocarbon with 4 to 6 carbon atoms at 95 % or more, as represented by the following formula, is provided, together with a polymer-containing solution containing the same:         Rf1-R1-Rf2     (I) wherein R1 represents a carbon chain of CHF and CH2, bound to each other; Rf1 and Rf2 independently represent a perfluoroalkyl group; and Rf1 and Rf2 may be bound to each other, to form a ring.

  提供一种在碱或水和热中具有优异清洁作用、不燃性和高稳定性的含氟碳氢化合物；以及一种含聚合物的溶液，其制备方法是将一种具有成膜能力的聚合物（最好是含氟聚合物）溶解或分散在一种含三氢氟碳的溶剂中。更具体地说，本发明提供了由下式表示的含 4 至 6 个碳原子的含氟碳氢化合物，其碳原子数在 95% 或以上，以及含有该碳氢化合物的聚合物溶液： Rf1-R1-Rf2 (I) 其中 R1 代表相互结合的 CHF 和 CH2 碳链；Rf1 和 Rf2 独立地代表全氟烷基；Rf1 和 Rf2 可以相互结合，形成一个环。
• PROCESS FOR THE PREPARATION OF COMPOUNDS HAVING -CH2-CHF- GROUPS
  申请人：Nippon Zeon Co., Ltd.

  公开号：EP1043297A1

  公开（公告）日：2000-10-11

  A compound having at least 4 carbon atoms and a -ClC=CF-group is hydrogenated in the liquid phase or the vapor phase in the presence of a noble metal catalyst to give a compound having at least 4 carbon atoms and a -CH2-CHF- group. The compound having at least 4 carbon atoms and a -ClC=CF- group is preferably an alicyclic compound having 4 to 10 carbon atoms, and is prepared by allowing a compound having at least 4 carbon atoms and a -ClC=CCl- group to react with a fluorinating agent.

  具有至少 4 个碳原子和一个-ClC=CF-基团的化合物在贵金属催化剂存在下，在液相或气相中氢化，得到具有至少 4 个碳原子和一个-CH2-CHF-基团的化合物。具有至少 4 个碳原子和一个-ClC=CF-基团的化合物最好是具有 4 至 10 个碳原子的脂环族化合物，其制备方法是使具有至少 4 个碳原子和一个-ClC=CCl-基团的化合物与氟化剂反应。
• Process for preparation of optical information recording disc, optical information recording disc and dye solution
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1056078A1

  公开（公告）日：2000-11-29

  An optical information recording disc showing good recording characteristics is prepared by the steps of coating a dye solution of a laser light-sensitive dye in a fluorinated cyclic alkane or alkene on a transparent substrate disc and drying the coated dye solution. The fluorinated cyclic alkane or alkene can be employed in combination with other organic solvents.

  一种具有良好记录特性的光学信息记录光盘是通过以下步骤制备的：将激光光敏染料在含氟环烷或烯中的染料溶液涂布在透明基片光盘上，然后将涂布的染料溶液干燥。含氟环烷或烯可与其他有机溶剂结合使用。