Pt(2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene]-1,3-dithiole-4,5-dithiolate(2-))(N-decyl-pyridine-2-carbaldimine) | 220375-70-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Pt(2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene]-1,3-dithiole-4,5-dithiolate(2-))(N-decyl-pyridine-2-carbaldimine)
• CAS: 220375-70-2
• 化学式: C₂₄H₃₀N₂PtS₈
• 分子量: 798.124
• InChiKey: GACWRQWLCXKHHU-UVVJDXDRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  碘 、 Pt(2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene]-1,3-dithiole-4,5-dithiolate(2-))(N-decyl-pyridine-2-carbaldimine) 以 二氯甲烷 为溶剂， 以75%的产率得到[Pt(4,5-disulfanyl-1,3-dithiole-2-thionate(2-))(N-decyl-pyridine-2-carbaldimine)](I3)1.1
  参考文献：
  名称：

  Properties of Pt(II) complexes containing both a pyridyl N–N chelate ligand having a long alkyl chain and a sulfur-rich dithiolate ligand and their molecular interactions in the solid state

  摘要：

  Reactions of PtCl2(N-alkyl-pyridine-2-carbaldimine) [alkyl = C10H21 and C16H33; C-10-PYa and C-16-pya] with Na2C3S5 [C3S52- = 4,5-disulfanyl-1,3-dithiole-2-thionate(2-)] or Na2C8H4S8 [C8H4S82- = 2-{(4,5-ethylenedithio)-1,3-dithiole-2-ylidene}-1,3-dithiole-4,5-dithiolate(2-)] in methanol or ethanol afforded Pt(C3S5)(C-10-pya), Pt(C3S5)(C-16-pya) and Pt(C8H4S8)(C-10-pya). Their electronic absorption spectra exhibited mixed metal/ligand-to-ligand charge transfer bands in the region of 570-780 nm in solution which are sensitive to a solvent. The C3S5 complexes show almost reversible redox waves around +0.62 V (versus SCE) and the C8H4S8 complex at +0.17 and +0.51 V (versus SCE). They were reacted with excess amounts of iodine to afford [Pt(C3S5)(C-10-pya and C-16-pya)] (I-3)(0.7), [Pt(C3S5)(C-10-pya)] (I-3)(1.1) and [Pt(C8H4S8)(C-10-pya)] (I-3)(1.5), which exhibited electrical conductivities of 1 x (10(-7) - 10(-3)) S cm(-1) measured for compacted pellets at room temperature. Molecular interactions of the complexes and their oxidized species in the solid state are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00276-x
• 作为产物：
  描述：

  PtCl2(N-decyl-pyridine-2-carbaldimine) 、 4,5-bis(cyanoethylthio)-1,3-dithiole-2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene] 在 Na 作用下， 以 乙醇 为溶剂， 以55%的产率得到Pt(2-[(4,5-ethylenedithio)-1,3-dithiole-2-ylidene]-1,3-dithiole-4,5-dithiolate(2-))(N-decyl-pyridine-2-carbaldimine)
  参考文献：
  名称：

  Properties of Pt(II) complexes containing both a pyridyl N–N chelate ligand having a long alkyl chain and a sulfur-rich dithiolate ligand and their molecular interactions in the solid state

  摘要：

  Reactions of PtCl2(N-alkyl-pyridine-2-carbaldimine) [alkyl = C10H21 and C16H33; C-10-PYa and C-16-pya] with Na2C3S5 [C3S52- = 4,5-disulfanyl-1,3-dithiole-2-thionate(2-)] or Na2C8H4S8 [C8H4S82- = 2-{(4,5-ethylenedithio)-1,3-dithiole-2-ylidene}-1,3-dithiole-4,5-dithiolate(2-)] in methanol or ethanol afforded Pt(C3S5)(C-10-pya), Pt(C3S5)(C-16-pya) and Pt(C8H4S8)(C-10-pya). Their electronic absorption spectra exhibited mixed metal/ligand-to-ligand charge transfer bands in the region of 570-780 nm in solution which are sensitive to a solvent. The C3S5 complexes show almost reversible redox waves around +0.62 V (versus SCE) and the C8H4S8 complex at +0.17 and +0.51 V (versus SCE). They were reacted with excess amounts of iodine to afford [Pt(C3S5)(C-10-pya and C-16-pya)] (I-3)(0.7), [Pt(C3S5)(C-10-pya)] (I-3)(1.1) and [Pt(C8H4S8)(C-10-pya)] (I-3)(1.5), which exhibited electrical conductivities of 1 x (10(-7) - 10(-3)) S cm(-1) measured for compacted pellets at room temperature. Molecular interactions of the complexes and their oxidized species in the solid state are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00276-x