N-butyl-N-(2-vinyloxy-ethyl)-aniline | 107778-81-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-butyl-N-(2-vinyloxy-ethyl)-aniline
• 英文别名: N-Butyl-N-(2-vinyloxy-aethyl)-anilin；N-butyl-N-(2-ethenoxyethyl)aniline
• CAS: 107778-81-4
• 化学式: C₁₄H₂₁NO
• 分子量: 219.327
• InChiKey: DPPXRPDYAVQXFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-butyl-N-(2-vinyloxy-ethyl)-aniline 在 镍 作用下， 生成 N-(2-乙氧基乙基)-N-丁基苯胺
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：
• 作为产物：
  描述：

  N-丁基-N-羟乙基苯胺 、 乙炔 在 氢氧化钾 、 正丁醇 作用下， 150.0~160.0 ℃ 、1.96 MPa 条件下， 生成 N-butyl-N-(2-vinyloxy-ethyl)-aniline
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• Liquid inks comprising treated colorant particles
  申请人：Samsung

  公开号：US20020086916A1

  公开（公告）日：2002-07-04

  A process of making a liquid ink comprising the steps of: (a) dissolving a polymer comprising units derived from at least a nitrogen-containing polymerizable monomer in a solvent with a Kauri-Butanol number greater than 30 to form a polymer solution; (b) dispersing colorant pigment particles in said polymer solution to form a colorant pigment dispersion; (c) removing at least some of said solvent from said colorant pigment dispersion to form treated colorant pigment particles; and (d) dispersing said treated colorant pigment particles in an organosol containing a carrier liquid having a Kauri-Butanol number less than 30.

  制备液体墨水的过程包括以下步骤：(a)将由至少一种含氮可聚合单体衍生的单元组成的聚合物溶解于Kauri-Butanol值大于30的溶剂中，形成聚合物溶液；(b)将颜料颗粒分散于聚合物溶液中，形成颜料分散液；(c)从颜料分散液中去除至少一部分溶剂，形成处理后的颜料颗粒；(d)将处理后的颜料颗粒分散于含有Kauri-Butanol值小于30的载体液体的有机溶胶中。
• Liquid inks comprising surface-treated colorant particles and manufacturing method thereof
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：EP1205815A1

  公开（公告）日：2002-05-15

  A liquid ink including a colorant surface-treated with a polymer comprising units derived from at least a nitrogen-containing polymerizable monomer and a process of making the same are provided. The liquid ink includes a carrier liquid, an organosol, and a colorant surface-treated by a polymer comprising units derived from at least a nitrogen-containing polymerizable monomer. Since the liquid ink includes the colorant surface-treated by a polymer comprising units derived from at least a nitrogen-containing polymerizable monomer, it exhibits improved chargeability, reduced conductivity variability and improved dispersion stability at a lower amount of charge control additive.

  本发明提供了一种液体墨水，包括用聚合物处理过的着色剂表面，该聚合物包含至少由含氮可聚合单体衍生的单元，还提供了制造该液体墨水的工艺。该液体墨水包括载液、有机溶剂和表面经过至少一种含氮可聚合单体衍生单元组成的聚合物处理的着色剂。由于液体墨水包括由至少一种含氮可聚合单体衍生的单元组成的聚合物所处理的着色剂表面，因此在电荷控制添加剂用量较低的情况下，液体墨水的电荷性得到改善，导电性变化减小，分散稳定性提高。
• Organosol and liquid inks comprising the same
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：EP1229057A2

  公开（公告）日：2002-08-07

  An organosol and a liquid ink containing the organosol are provided. The liquid ink includes: a carrier liquid; a graft copolymer including a (co)polymeric steric stabilizer covalently bonded to a thermoplastic (co)polymeric core that is insoluble in the carrier liquid; and a colorant, wherein the steric stabilizer includes units derived from 3,3,5-trimethylcyclohexyl methacrylate, and the thermoplastic (co)polymeric core includes units derived from at least one polymerizable monomer selected from the group consisting of (meth)acrylate monomers having aliphatic amino radicals, nitrogen-containing heterocyclic vinyl monomers, N-vinyl substituted ring-like amide monomers, aromatic substituted ethylene monomers containing amino radicals, and nitrogen-containing vinylether monomers.

  提供了一种有机溶剂和含有该有机溶剂的液体墨水。液体墨水包括载液；接枝共聚物，包括与不溶于载液的热塑性（共）聚合物芯共价键合的（共）聚合物立体稳定剂；和着色剂，其中立体稳定剂包括衍生自 3，3，5-三甲基环己基甲基丙烯酸酯的单元，热塑性（共）聚合物芯包括衍生自至少一种可聚合单体的单元，该单体选自由以下组成的组群：具有脂肪族氨基基的（甲基）丙烯酸酯单体、含氮杂环乙烯基单体、N-乙烯基取代的环状酰胺单体、含有氨基基的芳香族取代的乙烯单体和含氮乙烯基醚单体。
• Liquid inks comprising stabilizing organosols
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：EP1327915A1

  公开（公告）日：2003-07-16

  The present invention provides a liquid ink for developing electrophotography images comprises: a) a carrier liquid having a Kauri-Butanol number less than 30; b) a grafted co-polymer comprising a (co)polymeric steric stabilizer covalently bonded to a thermoplastic (co)polymeric core that is insoluble in the carrier liquid, wherein the grafted co-polymer is derived from at least a polymerizable organic compound having at least one acid group or at least one acid group; c) a dispersant having, respectively, at least an amine group or at least one acid group to form an acid-base copolymer-dispersant system or a base-acid copolymer-dispersant system, wherein the mole ratio of the amine group to the acid group is between 0.3 and 1.5 in the acid-base copolymer-dispersant system and the mole ratio of the acid group to the amine group in the base-acid copolymer-dispersant system is between 0.3 and 1.5; and d) a positive charge director with the acid-base copolymer-dispersant system and a negative charge director with the base-acid copolymer-dispersant system.

  本发明提供了一种用于显影电子照相图像的液体墨水，包括 a) Kauri-Butanol 数值小于 30 的载液； b) 接枝共聚物，包括与不溶于载液的热塑性（共）聚合物芯共价键合的（共）聚合物立体稳定剂，其中接枝共聚物至少来源于具有至少一个酸基或至少一个酸基的可聚合有机化合物； c) 分别具有至少一个胺基团或至少一个酸基团的分散剂，以形成酸碱共聚物-分散剂体系或碱酸共聚物-分散剂体系，其中，在酸碱共聚物-分散剂体系中，胺基团与酸基团的摩尔比在 0.3 和 1.5 之间，在碱酸共聚物-分散剂体系中，酸基团与胺基团的摩尔比在 0.3 和 1.5 之间；以及 d) 酸碱共聚分散剂体系中的正电荷引导剂和碱酸共聚分散剂体系中的负电荷引导剂。
• Liquid inks comprising a stable organosol
  申请人：——

  公开号：US20020128349A1

  公开（公告）日：2002-09-12

  A liquid ink comprises (a) a carrier liquid having a Kauri-Butanol number less than 30; (b) a graft copolymer comprising a (co)polymeric steric stabilizer covalently bonded to a thermoplastic (co)polymeric core that is insoluble in the carrier liquid; and (c) a colorant, wherein the steric stabilizer comprises units derived from 3,3,5-trimethylcyclohexyl methacrylate, and the thermoplastic (co)polymeric core comprising units derived from at least a polymerizable monomer selected from the group consisting of (meth)acrylates having aliphatic amino radicals, nitrogen-containing heterocyclic vinyl monomers, N-vinyl substituted ring-like amide monomers, aromatic substituted ethylene monomers containing amino radicals, and nitrogen-containing vinylether monomers. The organosol provides improved liquid electrophotographic and electrographic ink compositions with improved dispersion stability, chargeability, and blocking resistance so that improved print quality or ink transfer performance are obtained.

  一种液体墨水包括：(a) Kauri-Butanol 数小于 30 的载液；(b) 接枝共聚物，包括与不溶于载液的热塑性（共）聚合物芯共价键合的（共）聚合物立体稳定剂；(c) 着色剂，其中立体稳定剂包括从甲基丙烯酸 3,3,5-三甲基环己基酯衍生的单元，热塑性(共)聚合物芯包括从至少一种可聚合单体衍生的单元，该可聚合单体选自由以下组群：具有脂肪族氨基基的(甲基)丙烯酸酯、含氮杂环乙烯基单体、N-乙烯基取代的环状酰胺单体、含有氨基基的芳香族取代的乙烯单体和含氮乙烯基醚单体。该有机溶胶可提供更好的液态电子照相和电子印刷油墨组合物，具有更好的分散稳定性、荷电性和抗阻塞性，从而提高印刷质量或油墨转移性能。