fluorocarbonic acid-(2-fluoro-ethyl ester) | 462-29-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: fluorocarbonic acid-(2-fluoro-ethyl ester)
• 英文别名: Fluorokohlensaeure-(2-fluor-aethylester)；1-Fluor-2-fluorcarbonyloxy-aethan；Fluoroethyl fluoroformate；2-fluoroethyl carbonofluoridate
• CAS: 462-29-3
• 化学式: C₃H₄F₂O₂
• 分子量: 110.06
• InChiKey: MYEUCHBYOMOJQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  fluorocarbonic acid-(2-fluoro-ethyl ester) 、 环己胺 在 sodium acetate 、 溶剂黄146 作用下， 生成 cyclohexyl-carbamic acid-(2-fluoro-ethyl ester)
  参考文献：
  名称：

  Cross-Cultural Perspectives: Implications for Attachment Theory and Family Therapy

  摘要：

  Cross‐cultural perspectives have always been useful for understanding behavior. They clarify the distinction between aspects that are essentially part of the human condition and those that are the most responsive to variation. The interesting article by Rothbaum and his colleagues is in that tradition, contrasting the cultural values and family patterns in Japanese society with those of Western cultures, including our own, and suggesting that these differences shape the nature and course of attachment. It stimulates questions about what we have taken for granted in our theories and in our evaluations of dysfunctional behavior.

  DOI：

  10.1111/j.1545-5300.2002.41316.x
• 作为产物：
  描述：

  2-氟乙基氯甲酸 在 potassium fluoride 、 硝基苯 作用下， 生成 fluorocarbonic acid-(2-fluoro-ethyl ester)
  参考文献：
  名称：

  Cross-Cultural Perspectives: Implications for Attachment Theory and Family Therapy

  摘要：

  Cross‐cultural perspectives have always been useful for understanding behavior. They clarify the distinction between aspects that are essentially part of the human condition and those that are the most responsive to variation. The interesting article by Rothbaum and his colleagues is in that tradition, contrasting the cultural values and family patterns in Japanese society with those of Western cultures, including our own, and suggesting that these differences shape the nature and course of attachment. It stimulates questions about what we have taken for granted in our theories and in our evaluations of dysfunctional behavior.

  DOI：

  10.1111/j.1545-5300.2002.41316.x

文献信息

• Process for the preparation of fluoroalkyl (fluoro)alkyl carbonates and carbamates
  申请人：Bomkamp Martin

  公开号：US20120116111A1

  公开（公告）日：2012-05-10

  Fluoroalkyl alkyl carbonates and fluorosubstituted carbamates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective alcohol or amine. Methanol is the preferred alcohol, dimethylamine and diethylamine are preferred amines. Fluoromethyl methyl carbonate is the preferred compound to be produced. Fluoroalkyl fluoroformates can be prepared from aldehydes and carbonyl fluoride.

  氟烷基烷基碳酸酯和氟代氨基甲酸酯，可用作锂离子电池中的添加剂或溶剂。它们是由氟烷基氟甲酸酯和相应的醇或胺制备而成。甲醇是首选醇，二甲胺和二乙胺是首选胺。氟甲基甲基碳酸酯是首选要制备的化合物。氟烷基氟甲酸酯可以由醛和羰基氟制备。
• PROCESS FOR THE PREPARATION OF FLUOROALKYL (ALKYL CARBONATES AND CARBAMATES
  申请人：SOLVAY FLUOR GMBH

  公开号：US20150191414A1

  公开（公告）日：2015-07-09

  Fluoroalkyl alkyl carbonates and fluorosubstituted carbamates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and the respective alcohol or amine. Methanol is the preferred alcohol, dimethylamine and diethylamine are preferred amines. Fluoromethyl methyl carbonate is the preferred compound to be produced. Fluoroalkyl fluoroformates can be prepared from aldehydes and carbonyl fluoride.

  氟烷基烷基碳酸酯和氟代氨基甲酸酯可用作锂离子电池中的添加剂或溶剂，它们是由氟烷基氟甲酸酯和相应的醇或胺制备而成。甲醇是首选的醇，二甲胺和二乙胺是首选的胺。氟甲基甲基碳酸酯是首选的化合物。氟烷基氟甲酸酯可以由醛和羰基氟制备。