1,4-dimethyl-7-isopropyl-1,4,7-triazacyclononane | 257945-20-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4-dimethyl-7-isopropyl-1,4,7-triazacyclononane
• 英文别名: 1,4-Dimethyl-7-propan-2-yl-1,4,7-triazonane
• CAS: 257945-20-3
• 化学式: C₁₁H₂₅N₃
• 分子量: 199.34
• InChiKey: BWHWQMZSTZUDBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 1,4-dimethyl-7-isopropyl-1,4,7-triazacyclononane 、 双氧水 、 manganese(ll) chloride 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以4.8%的产率得到[Mn(IV)2(μ-O)3(1,4-dimethyl-7-isopropyl-1,4,7-triazacyclononane)2](PF6)2 * (KPF6)0.75 * (H2O)0.25
  参考文献：
  名称：

  Synthesis and properties of hydrophobic [MnIV2(μ-O)3(L)2]2+ complexes, derived from alkyl substituted 1,4,7-triazacyclononane ligands

  摘要：

  A series of manganese complexes of 1,4,7,-trimethyl-1,4,7-triazacyclononane homologues has been prepared. The ligand bears on position 1 or 2, alkyl and/or benzyl substituents resulting in an increase of lipophilicity of the coordination complex measured by the log P values. The lipophilic complexes dissolve well in organic solvents like dichloromethane. This permits them to be used as homogenous catalysts in two phase epoxidation of lipophilic substrate like styrene and dodecene using hydrogen peroxide as oxidant. Also the most lipophilic complexes activate hydrogen peroxide for bactericidal activity. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00378-3

文献信息

• Synthesis and properties of hydrophobic [MnIV2(μ-O)3(L)2]2+ complexes, derived from alkyl substituted 1,4,7-triazacyclononane ligands
  作者：Jean H. Koek、E.W.M.J. Kohlen、Stephen W. Russell、Lodewijk van der Wolf、Pieter F. ter Steeg、Johan C. Hellemons

  DOI：10.1016/s0020-1693(99)00378-3

  日期：1999.11

  A series of manganese complexes of 1,4,7,-trimethyl-1,4,7-triazacyclononane homologues has been prepared. The ligand bears on position 1 or 2, alkyl and/or benzyl substituents resulting in an increase of lipophilicity of the coordination complex measured by the log P values. The lipophilic complexes dissolve well in organic solvents like dichloromethane. This permits them to be used as homogenous catalysts in two phase epoxidation of lipophilic substrate like styrene and dodecene using hydrogen peroxide as oxidant. Also the most lipophilic complexes activate hydrogen peroxide for bactericidal activity. (C) 1999 Elsevier Science S.A. All rights reserved.