4-Methyltetrathiafulvalen | 54397-94-3

• 物质功能分类: 化学试剂 - 有机试剂 - 烯烃（环状与无环状）
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: 4-Methyltetrathiafulvalen
• 英文别名: monomethyltetrathiofulvalene；monomethyltetrathiafulvalene；methyl-[2,2']bi[1,3]dithiolylidene；2-(1,3-Dithiol-2-ylidene)-4-methyl-1,3-dithiole
• CAS: 54397-94-3
• 化学式: C₇H₆S₄
• 分子量: 218.389
• InChiKey: VNXFVCPHSMUBDE-UHFFFAOYSA-N

物化性质

• 沸点：
  243.5±40.0 °C(Predicted)
• 密度：
  1.528±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-Methyltetrathiafulvalen 在 sodium hydroxide 、 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 2-(4-methyl-1,3-dithiol-2-ylidene)-1,3-dithiole-4-carboxylic acid
  参考文献：
  名称：

  Mora, Henri; Fabre, Jean-Marc; Giral, Louis, Bulletin des Societes Chimiques Belges, 1992, vol. 101, # 8, p. 741 - 750

  摘要：

  DOI：
• 作为产物：
  描述：

  tetrathiafulvalenyllithium 、 硫酸二甲酯 以80%的产率得到
  参考文献：
  名称：

  GREEN D. C., J. ORG. CHEM., 1979, 44, NO 9, 1476-1479

  摘要：

  DOI：

文献信息

• POLYMER, MIXTURE AND COMPOUND CONTAINING SAME, AND ORGANIC ELECTRONIC DEVICE AND MONOMER THEREOF
  申请人：Guangzhou Chinaray Optoelectronic Materials Ltd.

  公开号：EP3229288A1

  公开（公告）日：2017-10-11

  Disclosed are a polymer, a compound containing same, and an organic electronic device and application thereof; the polymer comprises on its side chain a repeating structure unit E, which has thermally activated delayed fluorescence (TADF), i.e. Δ(S1(E)-T1(E))≤0.35eV Thus a TADF polymer suitable for printing processes is provided, thereby reducing OLED manufacturing costs.

  公开了一种聚合物、含有该聚合物的化合物和一种有机电子设备及其应用；该聚合物的侧链上包含一个重复结构单元 E，它具有热激活延迟荧光（TADF），即 Δ(S1(E)-T1(E))≤0.35eV 因此提供了一种适用于印刷工艺的 TADF 聚合物，从而降低了 OLED 制造成本。
• Mora, Henri; Fabre, Jean-Marc; Giral, Louis, Bulletin des Societes Chimiques Belges, 1992, vol. 101, # 2, p. 137 - 146
  作者：Mora, Henri、Fabre, Jean-Marc、Giral, Louis、Montginoul, Claude

  DOI：——

  日期：——
• ORGANIC SEMICONDUCTOR COMPOUND, SEMICONDUCTOR ELEMENT, SOLAR BATTERY, AND PROCESS FOR PRODUCING ORGANIC SEMICONDUCTOR COMPOUND
  申请人：Saigo Kazuhiko

  公开号：US20110040106A1

  公开（公告）日：2011-02-17

  Disclosed is, for example, a compound that can be a material which can control many functions. According to a first aspect of the present invention, there is provided an organic semiconductor compound characterized in that the organic semiconductor compound is produced by forming a salt of organic molecules as a donor with an inorganic acid or an inorganic base and causes self-accumulation. According to the above constitution, the organic semiconductor compound can be obtained in a simple manner. According to a second aspect of the present invention, there is provided an organic compound characterized by being produced by deriving an ammonia salt or a hydroxyamine salt from a compound having a tetrathiafulvalene analogue site in the skeleton thereof and containing a protonic acid functional group. According to the above constitution, an organic compound which can control many functions can be obtained.
• ORGANIC SEMICONDUCTOR COMPOUND, SEMICONDUCTOR DEVICE, SOLAR CELL AND PRODUCING METHOD OF ORGANIC SEMICONDUCTOR COMPOUND
  申请人：National Institute for Materials Science

  公开号：US20140012017A1

  公开（公告）日：2014-01-09

  There is provided a compound or the like which can become a material in which many functions are controllable. A first aspect of the present invention lies in an organic semiconductor compound, characterized in that an organic molecule which becomes a donor is formed by being salt-formed with an inorganic acid or an inorganic base and self assembly is accomplished. According to this configuration, there can be obtained an organic semiconductor compound by a simple technique. A second aspect of the present invention lies in an organic compound, characterized in that a compound containing a tetrathiafulvalene affinity region in a framework thereof and having a protic acid functional group is formed by being induced to a salt with ammonia or a salt with hydroxyamine. According to this configuration, there can be obtained an organic compound in which many functions are controllable.
• SENSOR MOLECULE
  申请人：University of Malta

  公开号：US20160169850A1

  公开（公告）日：2016-06-16

  The present invention relates to a method of measuring the acidity and redox potential of a sample, which method comprises: (i) contacting a compound of formula (A) with the sample: Acc(-L 1 -) a Fluo(-L 2 -) b Redox   (A); wherein: Acc is a proton acceptor moiety; Fluo is a fluorophore; Redox is a redox unit; each L 1 is a first spacer group which is bonded to Acc and Fluo; each L 2 is a second spacer group which is bonded to Fluo and Redox; a is 1 or 2; and b is 1 or 2; and (ii) exposing the sample to a light source, measuring fluorescence and thereby determining the acidity and redox potential of the sample. Compounds and the use of such compounds are also described.