四硫杂富瓦烯-D4 | 51751-16-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 中文名称: 四硫杂富瓦烯-D4
• 英文名称: tetrathiafulvalene-d4
• 英文别名: Tetrathiafulvalen-d4；Tetrathiofulven-d4；Tetrathiofulvalen-d4；tetradeuterio-[2,2']bi[1,3]dithiolylidene；4,5-dideuterio-2-(4,5-dideuterio-1,3-dithiol-2-ylidene)-1,3-dithiole
• CAS: 51751-16-7
• 化学式: C₆H₄S₄
• 分子量: 208.33
• InChiKey: FHCPAXDKURNIOZ-RHQRLBAQSA-N

物化性质

• 熔点：
  117.0 to 121.0 °C

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  tetrakis(trimethylsilyl)tetrathiafulvalene 在 乙醇-D1 、 重水 、 potassium carbonate 、 potassium hydrogencarbonate 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以95%的产率得到四硫杂富瓦烯-D4
  参考文献：
  名称：

  Synthesis and reactivities of trimethylsilyl-substituted tetrathia- and tetraselenafulvalenes

  摘要：

  DOI：

  10.1021/jo00215a041

文献信息

• OKAMOTO, YOSHIYUKI;LEE, HUNG, SUI;ATTARWALA, S. T., J. ORG. CHEM., 1985, 50, N 15, 2788-2790
  作者：OKAMOTO, YOSHIYUKI、LEE, HUNG, SUI、ATTARWALA, S. T.

  DOI：——

  日期：——
• BARRIERS AND FILMS
  申请人：Iwamoto Takashi

  公开号：US20130091803A1

  公开（公告）日：2013-04-18

  Provided herein are various bathers and methods of making and using them. In some embodiments, the barriers include a porous crystalline charge-transfer complex and a filler.
• US9260574B2
  申请人：——

  公开号：US9260574B2

  公开（公告）日：2016-02-16
• [EN] BARRIERS AND FILMS<br/>[FR] BARRIÈRES ET FILMS
  申请人：EMPIRE TECHNOLOGY DEV LLC

  公开号：WO2013058744A1

  公开（公告）日：2013-04-25

  Resin composites (10), which may be used as oxygen barrier films for preserving foods, include oxygen-resistant fillers (41), being filler materials (40) coated with porous crystalline charge-transfer complexes (CTCs) (20), that inhibit the passage of foreign molecules such as water or oxygen (30) through the film from an external side (50) to an internal side (60) by increasing the path (35) by which the molecules must travel. The composites may contain other resin or polymer components (25). The fillers may be flaked, oxygen-resistant fillers such as montmorillonite, bentonite, smectite, or artificial smectite. The CTCs may be derived from an organic acceptor such as tetracyanquinodimethane (TCNQ), trichloroethylene (TCE), and/or bis dithiobenzyl nickel; an organic electron donor such as bipyridine, pyridine, quinoline, isoquinoline, or tetrathiafulvalene (TTF); and a metal ion such as zinc, copper, iron, or nickel.
• Synthesis and reactivities of trimethylsilyl-substituted tetrathia- and tetraselenafulvalenes
  作者：Yoshiyuki Okamoto、Hung Sui Lee、S. T. Attarwala

  DOI：10.1021/jo00215a041

  日期：1985.7