N-(1-chloronaphthalen-2-yl)indole-1-carbothioamide | 135085-70-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-(1-chloronaphthalen-2-yl)indole-1-carbothioamide
• CAS: 135085-70-0
• 化学式: C₁₉H₁₃ClN₂S
• 分子量: 336.845
• InChiKey: IIJUNDDWVPPKIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(1-chloronaphthalen-2-yl)indole-1-carbothioamide 生成 2-Indol-1-ylbenzo[g][1,3]benzothiazole
  参考文献：
  名称：

  Photochemical Synthesis of s-Triazolo[3,4-b]benzothiazole and Mechanistic Studies on Benzothiazole Formation

  摘要：

  A general photochemical synthesis of s-triazolo[3,4-b]benzothiazoles from 4,5-disubstituted 1,2,4-triazole-3-thione is described. Steady photolysis, quantum yield determination, and laser flash photolysis experiments have been carried out. An intramolecular electron transfer mechanism has been proposed.

  DOI：

  10.1021/jo962190v
• 作为产物：
  描述：

  吲哚 、 1-chloro-2-naphthyl isothiocyanate 在 氢化钾 作用下， 生成 N-(1-chloronaphthalen-2-yl)indole-1-carbothioamide
  参考文献：
  名称：

  Muthusamy, Sengoden; Paramasivam, Rangasamy; Ramakrishnan, Vayalakkavoor T., Journal of Heterocyclic Chemistry, 1991, vol. 28, # 3, p. 759 - 763

  摘要：

  DOI：

文献信息

• Muthusamy, Sengoden; Paramasivam, Rangasamy; Ramakrishnan, Vayalakkavoor T., Journal of Heterocyclic Chemistry, 1991, vol. 28, # 3, p. 759 - 763
  作者：Muthusamy, Sengoden、Paramasivam, Rangasamy、Ramakrishnan, Vayalakkavoor T.

  DOI：——

  日期：——
• Photochemical Synthesis of s-Triazolo[3,4-<i>b</i>]benzothiazole and Mechanistic Studies on Benzothiazole Formation
  作者：G. Jayanthi、S. Muthusamy、R. Paramasivam、V. T. Ramakrishnan、N. K. Ramasamy、P. Ramamurthy

  DOI：10.1021/jo962190v

  日期：1997.8.1

  A general photochemical synthesis of s-triazolo[3,4-b]benzothiazoles from 4,5-disubstituted 1,2,4-triazole-3-thione is described. Steady photolysis, quantum yield determination, and laser flash photolysis experiments have been carried out. An intramolecular electron transfer mechanism has been proposed.