copper(III) 5,15-bis(pentafluorophenyl)-10-(3-methynyl-(4-methanol-1,2,3-triazol-1-yl)phenyl)corrole | 1620028-03-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡唑类
• 英文名称: copper(III) 5,15-bis(pentafluorophenyl)-10-(3-methynyl-(4-methanol-1,2,3-triazol-1-yl)phenyl)corrole
• CAS: 1620028-03-6
• 化学式: C₄₁H₁₈CuF₁₀N₇O
• 分子量: 878.17
• InChiKey: XEGLWPOAEHZOET-OVLUYCMXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-(溴甲基)苯甲醛 在 盐酸 、 sodium azide 、 苄基三乙基氯化铵 、 copper (I) acetate 作用下， 以 甲醇 、 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 1.5h， 生成 copper(III) 5,15-bis(pentafluorophenyl)-10-(3-methynyl-(4-methanol-1,2,3-triazol-1-yl)phenyl)corrole
  参考文献：
  名称：

  Corroles That “Click”: Modular Synthesis of Azido- and Propargyl-Functionalized Metallocorrole Complexes and Convergent Synthesis of a Bis-corrole Scaffold

  摘要：

  Bis-corroles have been prepared through a convergent synthesis using a copper-catalyzed azide-alkyne cycloaddition. Synthesis of the final homo- and heterobimetallic complexes has been achieved in three to four steps from commercially available materials in good overall yield. Meso-substituted corroles functionalized with a single azido or propargyl group were used as key starting materials. (C6F5)(2)(p-O(CH2CCH)Ph)corroleH(3) (I) and ((C6F5)2(m-CH2N3)Ph)corroleH(3) (3) were metalated with copper or iron and attached by Huisgen azide-alkyne cycloaddition ("click" reaction) first to small substrates and then to each other, demonstrating a convergent synthesis of bimetallic bis-corrole molecules.

  DOI：

  10.1021/ic500714h