1,2,2,6,6-pentamethylpiperidine | 60812-96-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1,2,2,6,6-pentamethylpiperidine
• 英文别名: 1,2,2,6-tetramethyl-piperidine；1,2,2,6-Tetramethyl-piperidin；1,2,2,6-Tetramethylpiperidine
• CAS: 60812-96-6
• 化学式: C₉H₁₉N
• 分子量: 141.257
• InChiKey: HVJKLCOHVAENRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  对甲苯磺酸甲酯 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1,2,2,6,6-pentamethylpiperidine
  参考文献：
  名称：

  Sterically Hindered Phenolic Buffers. Application to Determination of Rates of Amidation of Ethyl Chloroformate¹

  摘要：

  DOI：

  10.1021/ja01577a029
• 作为试剂：
  描述：

  硫代氯甲酸苯酯 、 alpha-d-吡喃半乳糖苷甲酯 在 1,2,2,6,6-pentamethylpiperidine 、 四丁基碘化铵 、 二辛基锡 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以90%的产率得到methyl 3-O-phenoxythiocarbonyl-α-L-fucopyranoside
  参考文献：
  名称：

  JP5669643

  摘要：

  公开号：

文献信息

• ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS
  申请人：UOP LLC

  公开号：US20160159760A1

  公开（公告）日：2016-06-09

  Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

  描述了新型的1-oxa-4-azonium环己烷盐。这些化合物可用作结构导向剂，并且克服了与OSDA合成和随后的沸石合成相关许多典型问题。还描述了从各种起始材料合成1-oxa-4-azonium环己烷盐的方法。 将取代的烃加入水中形成混合物，然后加入1-oxa-4-azacyclohexane衍生物。搅拌反应混合物，直到获得含有1-oxa-4-azonium环己烷盐的溶液。
• Organo-1-oxa-4-azonium cyclohexane compounds
  申请人：UOP LLC

  公开号：US10597373B2

  公开（公告）日：2020-03-24

  Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

  本文介绍了新型 1-oxa-4-azonium 环己烷盐。 这些化合物可用作结构引导剂，克服了与 OSDA 合成和后续沸石合成相关的许多典型问题。 此外，还介绍了从各种起始材料合成 1-oxa-4-azonium 环己烷盐的方法。 将取代的碳氢化合物加入水中形成混合物，然后加入 1-oxa-4-azacyclohexane 衍生物。 搅拌反应混合物，直到得到含有 1-oxa-4-azium 环己烷盐的溶液。
• Aluminosilicate zeolite UZM-50
  申请人：UOP LLC

  公开号：US10632454B2

  公开（公告）日：2020-04-28

  A new aluminosilicate zeolite designated UZM-50, methods of making the zeolite, and its use as a catalyst in hydrocarbon conversion processes are described. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M is selected from the group consisting of hydrogen, sodium, potassium, magnesium, calcium or combinations thereof, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is an amine essentially incapable of undergoing pyramidal inversion and having 7 or fewer carbon atoms, and R2 is a dihaloalkane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. UZM-50 has utility in various hydrocarbon conversion reactions such as conversion of an aromatic molecule to another aromatic molecule.

  本文介绍了一种名为 UZM-50 的新型铝硅酸盐沸石、制造这种沸石的方法及其在碳氢化合物转化过程中作为催化剂的用途。这种沸石的经验公式为 M+mRrAl1-xExSiyOz 其中，M 选自氢、钠、钾、镁、钙或它们的混合物组成的组；R 是有机结构引导剂或由反应物 R1 和 R2 衍生的剂，其中 R1 是基本上不能发生金字塔形反转且具有 7 个或更少碳原子的胺，R2 是二卤代烃；E 是选自镓、铁、硼和它们的混合物组成的组的元素。UZM-50 可用于各种烃类转化反应，如将芳香分子转化为另一种芳香分子。
• Hydrocarbon conversion using UZM-50
  申请人：UOP LLC

  公开号：US10888851B2

  公开（公告）日：2021-01-12

  A new aluminosilicate zeolite designated UZM-50, methods of making the zeolite, and its use as a catalyst in hydrocarbon conversion processes are described. This zeolite is represented by the empirical formula: M+mRrAl1−xExSiyOz where M is selected from the group consisting of hydrogen, sodium, potassium, magnesium, calcium or combinations thereof, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is an amine essentially incapable of undergoing pyramidal inversion and having 7 or fewer carbon atoms, and R2 is a dihaloalkane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. UZM-50 has utility in various hydrocarbon conversion reactions such as conversion of an aromatic molecule to another aromatic molecule.

  本文介绍了一种名为 UZM-50 的新型铝硅酸盐沸石、制造这种沸石的方法及其在碳氢化合物转化过程中作为催化剂的用途。这种沸石的经验公式为 M+mRrAl1-xExSiyOz 其中，M 选自氢、钠、钾、镁、钙或它们的混合物组成的组；R 是有机结构引导剂或由反应物 R1 和 R2 衍生的剂，其中 R1 是基本上不能发生金字塔形反转且具有 7 个或更少碳原子的胺，R2 是二卤代烃；E 是选自镓、铁、硼和它们的混合物组成的组的元素。UZM-50 可用于各种烃类转化反应，如将芳香分子转化为另一种芳香分子。
• Unsaturated Amines. X. The Mercuric Acetate Route to Substituted Piperidines, Δ²-Tetrahydropyridines and Δ²-Tetrahydroanabasines
  作者：Nelson J. Leonard、Fred P. Hauck

  DOI：10.1021/ja01576a056

  日期：1957.10