1-bromo-4-[8-(4-bromophenyl)-2,7-diphenylocta-1,7-dienyl]benzene | 265137-31-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-bromo-4-[8-(4-bromophenyl)-2,7-diphenylocta-1,7-dienyl]benzene
• CAS: 265137-31-3
• 化学式: C₃₂H₂₈Br₂
• 分子量: 572.382
• InChiKey: RHYIERAWNADJKO-UHFFFAOYSA-N

物化性质

• 沸点：
  654.9±55.0 °C(Predicted)
• 密度：
  1.356±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.55
• 重原子数：
  34.0
• 可旋转键数：
  9.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1-bromo-4-[8-(4-bromophenyl)-2,7-diphenylocta-1,7-dienyl]benzene 在 碘 、 methyloxirane 作用下， 以 甲苯 为溶剂， 以30%的产率得到3-Bromo-9-[4-(3-bromophenanthren-9-yl)butyl]phenanthrene
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y
• 作为产物：
  描述：

  己二酰氯 在 正丁基锂 、 三氯化铝 作用下， 以 四氢呋喃 为溶剂， 生成 1-bromo-4-[8-(4-bromophenyl)-2,7-diphenylocta-1,7-dienyl]benzene
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y

文献信息

• Synthesis and fluorescence emission behavior of novel anti-[2.n](3,9)phenanthrenophanes
  作者：Yosuke Nakamura、Takahiro Fujii、Jun Nishimura

  DOI：10.1016/s0040-4039(99)02306-0

  日期：2000.2

  Novel syn- and anti-[2.n](3,9)phenanthrenophanes (n=3,4) were successfully prepared by the intramolecular [2+2] photocycloaddition of alpha,omega-bis(3-vinyl-9-phenanthryl)alkanes. The anti-isomer of n=3 was found to give excimer fluorescence in spite of the only partially overlapping phenanthrene rings, although that of n=4 gave monomer fluorescence. (C) 2000 Elsevier Science Ltd. All rights reserved.