N,N'-bis(4-diethylaminosalicylidene)-2,2-dimethylpropanediamine | 1298037-74-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis(4-diethylaminosalicylidene)-2,2-dimethylpropanediamine
• 英文别名: 5,5'-Bis(diethylamino)-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol；5-(diethylamino)-2-[[3-[[4-(diethylamino)-2-hydroxyphenyl]methylideneamino]-2,2-dimethylpropyl]iminomethyl]phenol
• CAS: 1298037-74-7
• 化学式: C₂₇H₄₀N₄O₂
• 分子量: 452.64
• InChiKey: PEBVKMGZKSWBRZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  33
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  71.7
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  dichloro(1,2-dimethoxyethane)dioxotungsten(VI) 、 N,N'-bis(4-diethylaminosalicylidene)-2,2-dimethylpropanediamine 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以55.1%的产率得到
  参考文献：
  名称：

  [EN] TUNGSTEN (VI) COMPLEXES FOR OLED APPLICATION
  [FR] COMPLEXES DE TUNGSTÈNE (VI) POUR APPLICATION OLED

  摘要：

  具有结构I复合物的OLED发射器。该复合物具有钨（VI）中心和两个独立或连接在一起的配位单元。每个配位单元通过氮-钨键和氧-钨键与中心配位。钨（VI）发射器可用于发光装置。

  公开号：

  WO2018033024A1
• 作为产物：
  描述：

  二甲基丙二胺 、 4-(二乙氨基)水杨醛 在 甲酸 作用下， 以 乙醇 为溶剂， 反应 12.0h， 以70%的产率得到N,N'-bis(4-diethylaminosalicylidene)-2,2-dimethylpropanediamine
  参考文献：
  名称：

  Structural, spectral, electrochemical and catalytic reactivity studies of a series of N2O2 chelated palladium(II) complexes

  摘要：

  A series of neutral salicylaldiminato Pd(II) complexes have been synthesized and characterized. Spectral and electrochemical properties of the complexes in the solution phase have been investigated. The structure of complex 9 has been confirmed by X-ray analysis. Spectroscopic characteristics were determined by visible absorption spectra. Cyclic voltammetry analysis has been performed to determine the energy levels of the compounds. The coordination of the Schiff base, according to the spectroscopic techniques, appears to occur through the two azomethine nitrogens and two o-OH groups. The salen type Pd(II) complexes have been used as catalysts for the formation of cyclic organic carbonates from carbon dioxide and liquid epoxides, which served as both reactant and solvent. The more electron donating substituents on the backbone and the aryl ring of the ligand system, in particular, effectively promote carbon dioxide activation with liquid epoxides under homogeneous conditions. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.02.035

文献信息

• Structural, spectral, electrochemical and catalytic reactivity studies of a series of N2O2 chelated palladium(II) complexes
  作者：Mahmut Ulusoy、Özgül Birel、Onur Şahin、Orhan Büyükgüngör、Bekir Cetinkaya

  DOI：10.1016/j.poly.2012.02.035

  日期：2012.5

  A series of neutral salicylaldiminato Pd(II) complexes have been synthesized and characterized. Spectral and electrochemical properties of the complexes in the solution phase have been investigated. The structure of complex 9 has been confirmed by X-ray analysis. Spectroscopic characteristics were determined by visible absorption spectra. Cyclic voltammetry analysis has been performed to determine the energy levels of the compounds. The coordination of the Schiff base, according to the spectroscopic techniques, appears to occur through the two azomethine nitrogens and two o-OH groups. The salen type Pd(II) complexes have been used as catalysts for the formation of cyclic organic carbonates from carbon dioxide and liquid epoxides, which served as both reactant and solvent. The more electron donating substituents on the backbone and the aryl ring of the ligand system, in particular, effectively promote carbon dioxide activation with liquid epoxides under homogeneous conditions. (C) 2012 Elsevier Ltd. All rights reserved.
• [EN] TUNGSTEN (VI) COMPLEXES FOR OLED APPLICATION<br/>[FR] COMPLEXES DE TUNGSTÈNE (VI) POUR APPLICATION OLED
  申请人：UNIV HONG KONG

  公开号：WO2018033024A1

  公开（公告）日：2018-02-22

  An OLED emitter having a complex of Structure I. The complex has a tungsten (VI) center and two coordination units which are independent or connected together. Each coordination unit coordinates to the center with a nitrogen-tungsten bond and an oxygen-tungsten bond. The tungsten (VI) emitter can be used in light-emitting devices.

  具有结构I复合物的OLED发射器。该复合物具有钨（VI）中心和两个独立或连接在一起的配位单元。每个配位单元通过氮-钨键和氧-钨键与中心配位。钨（VI）发射器可用于发光装置。