1-ethyl-piperidine-3,5-diol

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1-ethyl-piperidine-3,5-diol
• 英文别名: 1-Aethyl-piperidin-3,5-diol；1-Ethylpiperidine-3,5-diol；1-ethylpiperidine-3,5-diol
• 化学式: C₇H₁₅NO₂
• 分子量: 145.202
• InChiKey: SPSPKIBLEWRJKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,4-戊二烯 在 次氯酸叔丁酯 、 溶剂黄146 作用下， 生成 1-ethyl-piperidine-3,5-diol
  参考文献：
  名称：

  Paul; Tchelitcheff, Bulletin de la Societe Chimique de France, 1948, p. 896,900

  摘要：

  DOI：

文献信息

• GLASS FILLER-CONTAINING POLYCARBONATE RESIN COMPOSITION, AND MOLDED BODY THEREOF
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP3617272A1

  公开（公告）日：2020-03-04

  Provided is a polycarbonate-based resin composition including: an aliphatic polycarbonate-based resin (A) containing a specific repeating unit; and a glass filler (B) having specific composition and having a total content of Li2O, Na2O, K2O, and Cs2O of 5 mass% or less, wherein the refractive index of the aliphatic polycarbonate-based resin (A) for light having a wavelength of 589.3 nm is 1.480 or more and 1.520 or less, wherein the refractive index of the glass filler (B) for light having a wavelength of 589.3 nm is 1.485 or more and 1.520 or less, and wherein a difference in refractive index between the aliphatic polycarbonate-based resin (A) and the glass filler (B) is 0.003 or less for light having a wavelength of 486.1 nm, is 0.001 or less for light having a wavelength of 589.3 nm, and is 0.001 or less for light having a wavelength of 656.3 nm. Provided are a polycarbonate-based resin composition that can provide a molded body having excellent transparency, and a molded body excellent in transparency.

  提供了一种聚碳酸酯基树脂组合物，包括：含有特定重复单元的脂肪族聚碳酸酯基树脂（A）；以及具有特定成分且Li2O、Na2O、K2O和Cs2O的总含量为5质量％或以下的玻璃填料（B），其中脂肪族聚碳酸酯基树脂（A）对于波长为589.3 nm的光的折射率为1.480或以上且1.520 或以下，其中玻璃填料 (B) 对于波长为 589.3 纳米的光的折射率为 1.485 或以上和 1.520 或以下，其中脂肪族聚碳酸酯基树脂 (A) 和玻璃填料 (B) 之间的折射率差为 0.对于波长为 486.1 纳米的光，折射率差为 0.003 或以下；对于波长为 589.3 纳米的光，折射率差为 0.001 或以下；对于波长为 656.3 纳米的光，折射率差为 0.001 或以下。本发明提供了一种聚碳酸酯基树脂组合物，该组合物可提供透明度极佳的模塑体和透明度极佳的模塑体。
• METHOD FOR PRODUCING POLYCARBONATE RESIN COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP3663356A1

  公开（公告）日：2020-06-10

  Provided is a method of producing a polycarbonate-based resin composition, including mixing an aliphatic polycarbonate-based resin (A) containing a specific repeating unit (A-1), and at least one kind of aromatic thermoplastic resin (S) selected from the group consisting of an aromatic polycarbonate-based resin (B) containing a polycarbonate block formed of a specific repeating unit, an aromatic polyester-based resin (C) having a specific structural unit, and a polyarylate resin (D) having a specific structural unit in the presence of a transesterification catalyst at a temperature at which the resin components melt.

  本发明提供了一种生产聚碳酸酯基树脂组合物的方法，包括将含有特定重复单元（A-1）的脂肪族聚碳酸酯基树脂（A）与至少一种芳香族热塑性树脂（S）混合，该芳香族热塑性树脂（S）选自以下一组：含有由特定重复单元形成的聚碳酸酯嵌段的芳香族聚碳酸酯基树脂（B）、具有特定结构单元的芳香族聚酯基树脂（C）和具有特定结构单元的聚芳基酯树脂（D）、具有特定结构单元的芳香族聚酯基树脂 (C) 和具有特定结构单元的聚芳基酯树脂 (D)。
• POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER, METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION COMPRISING THE COPOLYMER
  申请人：Idemitsu Kosan Co.,Ltd.

  公开号：EP3957673A1

  公开（公告）日：2022-02-23

  Provided is a polycarbonate-polyorganosiloxane copolymer that a sufficient amount of a siloxane block can be introduced into the main chain of the polymer, and as a result, high dynamic properties are expressed. The polycarbonate-polyorganosiloxane copolymer, comprising a polyorganosiloxane block (A-1) including a specific structural unit and a polycarbonate block (A-2) formed of a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies one of the following conditions (A) and (B): condition (A): a hexane extraction amount of the polycarbonate-polyorganosiloxane copolymer is 150 ppm by mass or less; and condition (B): average weights of polyorganosiloxane blocks in polycarbonate-polyorganosiloxane copolymers obtained by separating the polycarbonate-polyorganosiloxane copolymer with a gel permeation chromatograph satisfy a specific expression.

  本发明提供了一种聚碳酸酯-聚有机硅氧烷共聚物，它可以在聚合物主链中引入足量的硅氧烷嵌段，从而表现出较高的动态特性。 聚碳酸酯-聚有机硅氧烷共聚物，由包括特定结构单元的聚有机硅氧烷嵌段（A-1）和由特定重复单元形成的聚碳酸酯嵌段（A-2）组成，其中聚碳酸酯-聚有机硅氧烷共聚物满足以下条件（A）和（B）之一： 条件（A）：聚碳酸酯-聚有机硅氧烷共聚物的己烷萃取量为 150 ppm（质量）或以下；以及 条件(B)：用凝胶渗透色谱仪分离聚碳酸酯-聚有机硅氧烷共聚物而得到的聚碳酸酯-聚有机硅氧烷共聚物中的聚有机硅氧烷嵌段的平均重量满足特定表达式。
• POLYCARBONATE/POLYORGANOSILOXANE COPOLYMER AND RESIN COMPOSITION INCLUDING SAID COPOLYMER
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP4071195A1

  公开（公告）日：2022-10-12

  Provided is a polycarbonate-polyorganosiloxane copolymer, which is produced by using a diol monomer (a1) and a polyorganosiloxane (a2) satisfying the following condition, including: a polyorganosiloxane block (A-1) including a specific repeating unit; and a polycarbonate block (A-2) formed of a specific repeating unit: a mixture, which is obtained by bringing the diol monomer (a1), the polyorganosiloxane (a2), a carbonic acid diester, and a basic catalyst present at the same amount ratio as that at a time of production of the polycarbonate-polyorganosiloxane copolymer into contact with each other at from 100°C to 250°C for from 0.5 hour to 5 hours, has a haze value of 30 or less measured under conditions of 23°C and an optical path length of 10 mm in conformity with ISO 14782:1999.

  本发明提供了一种聚碳酸酯-聚有机硅氧烷共聚物，它是通过使用满足以下条件的二元醇单体（a1）和聚有机硅氧烷（a2）制得的，包括：包括特定重复单元的聚有机硅氧烷嵌段（A-1）；以及由特定重复单元形成的聚碳酸酯嵌段（A-2）：将二元醇单体 (a1)、聚有机硅氧烷 (a2)、碳酸二酯和碱性催化剂以与生产聚碳酸酯-聚有机硅氧烷共聚物时相同的量比在 100°C 至 250°C 的温度下相互接触 0.根据 ISO 14782:1999 标准，在 23°C、光程长度为 10 毫米的条件下测得的混浊值为 30 或以下。
• POLYCARBONATE RESIN COMPOSITION AND MOLDED ARTICLE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2915849B1

  公开（公告）日：2018-03-28