di-μ-(ethane-1,2-dithiolato)bis(diethyldithiocarbamato)antimony(III) | 194411-42-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: di-μ-(ethane-1,2-dithiolato)bis(diethyldithiocarbamato)antimony(III)
• 英文别名: [2-[bis(diethylcarbamothioylsulfanyl)stibanylsulfanyl]ethylsulfanyl-(diethylcarbamothioylsulfanyl)stibanyl] N,N-diethylcarbamodithioate
• CAS: 194411-42-2
• 化学式: C₂₂H₄₄N₄S₁₀Sb₂
• 分子量: 928.778
• InChiKey: GEMCUHZZIONPFQ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  7.86
• 重原子数：
  38.0
• 可旋转键数：
  13.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  12.96
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为产物：
  描述：

  bis(diethyldithiocarbamato)antimony(III) chloride 、 1,2-乙二硫醇 以 苯 为溶剂， 反应 5.0h， 以90%的产率得到di-μ-(ethane-1,2-dithiolato)bis(diethyldithiocarbamato)antimony(III)
  参考文献：
  名称：

  Bis(Diethyldithiocarbamato)Antimony(III) Derivatives with Oxygen- and Sulfur-Donor Ligands: Synthesis, Esi-Mass, and Spectral Characterization

  摘要：

  Replacement reactions of bis(diethyldithiocarbamato)antimony(III) chloride have been carried out with oxygen and sulfur donor ligands such as disodium oxalate, sodium acetate, sodium salicylate, benzoic acid, thioglycolic acid, acetylacetone, thiphenol, ethane-1,2-dithiol, and 2,2-dimethylpropane-1,3-diol to give mixed bis(diethyldithiocarbamato)antimony(III) derivatives of the corresponding ligands. These derivatives have been characterized by the physicochemical [melting point and molecular weight determination, elemental analysis (C, H, N, S, and Sb)], spectral [FT-IR, far-IR, NMR (H-1 and C-13)], ESI-mass, powder XRD, and SEM studies. [Supplementary materials are available for this article. Go to the publisher's online edition ofPhosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional figures and tables]

  DOI：

  10.1080/10426507.2013.777729

文献信息

• SYNTHESIS AND CHARACTERIZATION OF SOME DITHIOLATOANTIMONY(III) DIALKYLDITHIOCARBAMATES
  作者：S. Chourasia、B. Nahar、H. P. S. Chauhan

  DOI：10.1080/10426509608043466

  日期：1996.12

  yielded compounds of the type (R2NCS2)2Sb-SCH2-CH2S-Sb (S2CNR2)2 [where R = Me, Et and R2 = (CH2)4]. These newly synthesised derivatives are soluble in organic solvents like benzene, chloroform and carbon tetrachloride. These derivatives have been characterised by elemental analysis (C. H, N, Sb and S). melting points as well as IR, 1H NMR and 13C NMR spectral studies.

  摘要 乙烷-1,2-二硫代氯化锑和甲苯-3,4-二硫代氯化锑与摩尔比为 1:1 的二烷基二硫代氨基甲酸钠在无水苯中的置换反应产生 [其中 R = Me , Et 和 R2 = (CH2)+1，和 -AA- = - - - 和 。氯锑 (III) 双（二烷基二硫代氨基甲酸酯）和二硫醇钠在无水苯中以 2:1 的摩尔比反应生成 (R2NCS2)2Sb-S - S-Sb (S2CNR2)2 类型的化合物 [其中 R = Me、Et 和 R2 = ( )4]。这些新合成的衍生物可溶于苯、氯仿和​​四氯化碳等有机溶剂。这些衍生物已通过元素分析（C. H、N、Sb 和 S）进行了表征。熔点以及 IR、1H NMR 和 13C NMR 光谱研究。