O,O,O-tribenzyl phosphorothioate | 81633-39-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: O,O,O-tribenzyl phosphorothioate
• 英文别名: Tris(phenylmethoxy)-sulfanylidene-lambda5-phosphane；tris(phenylmethoxy)-sulfanylidene-λ5-phosphane
• CAS: 81633-39-8
• 化学式: C₂₁H₂₁O₃PS
• 分子量: 384.436
• InChiKey: HVNCOMPGIGIHBG-UHFFFAOYSA-N

物化性质

• 熔点：
  48.5-49.5 °C
• 沸点：
  498.8±55.0 °C(Predicted)
• 密度：
  1.235±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  亚磷酸二苄酯 、 O,O,O-tribenzyl phosphorothioate 在 磺酰氯 作用下， 生成 tetrabenzyl symmetrical monothiopyrophosphate
  参考文献：
  名称：

  Symmetrical monothiopyrophosphate

  摘要：

  DOI：

  10.1021/ja00348a054
• 作为产物：
  描述：

  亚磷酸三苄酯 在 吡啶 、 sulfur 作用下， 反应 3.5h， 以70%的产率得到O,O,O-tribenzyl phosphorothioate
  参考文献：
  名称：

  Symmetrical monothiopyrophosphate

  摘要：

  DOI：

  10.1021/ja00348a054

文献信息

• Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
  申请人：TAYCA CORPORATION

  公开号：US10208160B2

  公开（公告）日：2019-02-19

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.

  本发明提供了一种用于生产导电聚合物的氧化剂掺杂剂及其溶液，它们能够生产导电聚合物，适用于生产泄漏电流较低的电解质电容器。此外，还提供了使用其中任一种制备的导电聚合物。还提供了一种具有低泄漏电流的电解质电容器。氧化剂掺杂剂包括：有机铁磺酸盐；以及至少一种选自磷酸、磷酸盐、磷酸、亚磷酸盐、硼酸、硼酸盐、硫代磷酸、硫代磷酸、二硫代磷酸和二硫代磷酸组成的组。溶液包括溶解在水、醇或水与醇混合物中的氧化剂掺杂剂。导电聚合物是通过单体（如噻吩或其衍生物）的氧化聚合而制备的。导电聚合物用作电解质，以提供电解质电容器。
• Method for preparing an electrolyte capacitor
  申请人：TAYCA CORPORATION

  公开号：US10336859B2

  公开（公告）日：2019-07-02

  The method for preparing an electrolyte capacitor includes: providing an oxidant dopant agent for preparing the conductive polymer including: ferric naphthalenesulfonate; and at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate. The method also includes preparing a conductive polymer by using the oxidant dopant agent to obtain an electrolyte comprising the conductive polymer.

  制备电解质电容器的方法包括：提供用于制备导电聚合物的氧化剂掺杂剂，包括：萘磺酸铁；以及至少一种选自磷酸盐、亚磷酸盐、硼酸盐、硫代磷酸盐和二硫代磷酸盐的化合物。该方法还包括使用氧化剂掺杂剂制备导电聚合物，以获得包含导电聚合物的电解液。
• LOEWUS, D. I.;ECKSTEIN, F., J. AMER. CHEM. SOC., 1983, 105, N 10, 3287-3292
  作者：LOEWUS, D. I.、ECKSTEIN, F.

  DOI：——

  日期：——
• OXIDANT DOPANT AGENT FOR CONDUCTIVE POLYMER PRODUCTION, AND A SOLUTION THEREOF, AND A CONDUCTIVE POLYMER PREPARED BY USING EITHER OF THEM, AS WELL AS AN ELECTROLYTE CAPACITOR USING THE CONDUCTIVE POLYMER AS AN ELECTROLYTE
  申请人：TAYCA CORPORATION

  公开号：US20160355636A1

  公开（公告）日：2016-12-08

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.
• Symmetrical monothiopyrophosphate
  作者：David I. Loewus、Fritz Eckstein

  DOI：10.1021/ja00348a054

  日期：1983.5