1,1,2,2-tetrachloro-2-fluoroethane-sulfenyl chloride | 52176-71-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: 1,1,2,2-tetrachloro-2-fluoroethane-sulfenyl chloride
• 英文别名: 2-fluoro-1,1,2,2-tetrachloroethanesulphenyl chloride；2-fluoro-1,1,2,2-tetrachloroethylsulfenyl chloride；2-fluoro-1,1,2,2-tetrachloroethanesulfenyl chloride；(1,1,2,2-tetrachloro-2-fluoroethyl) thiohypochlorite
• CAS: 52176-71-3
• 化学式: C₂Cl₅FS
• 分子量: 252.351
• InChiKey: LNQOARMFZBNCHR-UHFFFAOYSA-N

物化性质

• 沸点：
  170.9±35.0 °C(Predicted)
• 密度：
  1.828±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1,2,2-tetrachloro-2-fluoroethane-sulfenyl chloride 生成 bis[(1,1,2,2-tetrachloro-2-fluoroethyl)disulfanyl]methanethione
  参考文献：
  名称：

  HANSEN, H. C.;SENNING, AL.;HAZELL, R. G., TETRAHEDRON, 1985, 41, N 22, 5145-5158

  摘要：

  DOI：

文献信息

• Synthesis, structure, and reactions of thiocarbonic acid derivatives new pentathiodipercarbonates, (RSS)2 CS, α,α,α-tris(disulfides), and the first α,α,α-tris(trisulfide)
  作者：Holger C. Hansen、Alexander Senning、Rita G. Hazell

  DOI：10.1016/s0040-4020(01)96759-6

  日期：1985.1

  Novel bis(perhaloalkyl) pentathiodipercarbonates have been synthesized by reaction of sulfenyl chlorides with metal trithiocarbonates, and the heptathio analog was prepared similarly. Lenthionine is the main product when diiodomethane is treated with sodium tetrathiopercarbonate. A rearrangement of bis(alkyldithio)chloromethanesulfenyl chlorides to alkyldithio) (alkyltrithio)dichloromethanes has been

  通过亚磺酰氯与金属三硫代碳酸酯的反应合成了新型的双（全卤代烷基）五硫代二过碳酸酯，并且类似地制备了七硫代类似物。当用四硫代过碳酸钠处理二碘甲烷时，硫代赖氨酸是主要产物。已经观察到双（烷基二硫代）氯甲烷亚磺酰氯重排为烷基二硫代）（烷基三硫代）二氯甲烷。将亚硫酰氯和硫代亚硫酰氯加到硫代羰基化合物中，并在乙腈中实现。第一结晶五硫代二过碳酸盐和α，α，α-三（二硫化物）的结构以及首次报道的α，α，α-三（三硫化物）的结构 已经通过X射线晶体学确定。
• N-tetrachlorofluoroethylthio-halo-benzoyl anilides and their use as
  申请人：Stauffer Chemical Company

  公开号：US04097512A1

  公开（公告）日：1978-06-27

  N-tetrachlorofluoroethylthio-halo-benzoyl anilide compounds having the formula ##STR1## in which R is chlorine, bromine, iodine or trifluoromethyl and R.sub.1 is hydrogen, halogen, trifluoromethyl, alkyl having 1 to 5 carbon atoms, alkoxy having 1 to 2 carbon atoms or alkylthio having 1 to 2 carbon atoms; and their use as fungicides.

  具有以下化学式的N-四氯氟乙硫基-卤代苯甲酰苯胺化合物：其中R为氯、溴、碘或三氟甲基，R.sub.1为氢、卤素、三氟甲基、具有1至5个碳原子的烷基、具有1至2个碳原子的烷氧基或具有1至2个碳原子的烷硫基；以及它们作为杀菌剂的用途。
• N-Haloethylthio-furanilides and their use as fungicides and acaricides
  申请人：Stauffer Chemical Company

  公开号：US04199594A1

  公开（公告）日：1980-04-22

  Compounds of the formula ##STR1## wherein X is chlorine or fluorine and Y is hydrogen or fluorine which are useful as foliar fungicides and acaricides.

  公式为##STR1##的化合物，其中X为氯或氟，Y为氢或氟，可用作叶面杀菌剂和杀螨剂。
• (Tetrachloro-fluoro-ethyl-thio)N-phenyl sulfonamides and their use in
  申请人：Stauffer Chemical Company

  公开号：US04092429A1

  公开（公告）日：1978-05-30

  Compounds of the formula ##STR1## IN WHICH R.sub.1 is a lower alkyl, lower haloalkyl or lower alkenyl group, R.sub.2 is hydrogen, halogen, lower alkoxy, lower alkyl, cyano, or a nitro group, and n is an integer between 1 and 5, R.sub.2 being the same or different when n is greater than 1; and their use in controlling pests, e.g. acarids, fungi, helminths and protozoa which cause coccidiosis.

  化合物的公式为## STR1 ##，其中R.sub.1是较低的烷基，较低的卤代烷基或较低的烯基基团，R.sub.2是氢，卤素，较低的烷氧基，较低的烷基，氰基或硝基基团，n是1到5之间的整数，当n大于1时，R.sub.2可以相同或不同;及其在控制害虫，例如螨虫，真菌，蠕虫和引起球虫病的原虫方面的用途。
• Pesticidal compositions and processes for treating plants
  申请人：Imperial Chemical Industries Limited

  公开号：US04307098A1

  公开（公告）日：1981-12-22

  A method and pesticidal composition for the preventative, protectant, prophylactic and eradicant treatment of plant fungi and bacteria comprises applying an effective amount to plants or seeds of a pesticidal composition containing in an inert carrier a compound of the formula ##STR1## wherein R is hydrogen, methyl or ethyl; R.sup.1 is polyhaloalkyl or polyhalovinyl; R.sup.2 is lower alkyl, lower alkoxy, bromo, chloro, fluoro, lower haloalkyl, cyano, nitro, lower alkylthio, lower alkylcarbonyl, lower alkoxycarbonyl or cycloalkyl; R.sup.3 is hydrogen or independently selected from the values of R.sup.2 ; R.sup.4 is hydrogen or independently selected from the values of R.sup.2 ; X is hydrogen, carbamoyl or cyano; and y is zero, one or two.

  一种用于预防、保护、预防和根除植物真菌和细菌的方法和杀虫剂组合物，包括将含有公式##STR1## 中化合物的惰性载体的杀虫剂组合物的有效量应用于植物或种子上，其中R为氢、甲基或乙基；R.sup.1为多卤代烷基或多卤代乙烯基；R.sup.2为较低的烷基、较低的烷氧基、溴、氯、氟、较低的卤代烷基、氰基、硝基、较低的烷基硫基、较低的烷基羰基、较低的烷氧羰基或环烷基；R.sup.3为氢或独立于R.sup.2的值选择；R.sup.4为氢或独立于R.sup.2的值选择；X为氢、氨基甲酰基或氰基；y为零、一或二。