benzylidine acenaphthenone | 70312-09-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: benzylidine acenaphthenone
• 英文别名: benzylideneacenaphthenone；(2E)-2-benzylideneacenaphthylen-1-one
• CAS: 70312-09-3
• 化学式: C₁₉H₁₂O
• 分子量: 256.304
• InChiKey: XBJNICKWRVOQIS-SFQUDFHCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙烯基异丁醚 、 benzylidine acenaphthenone 在 臭氧 作用下， 以 二氯甲烷 为溶剂， 以10%的产率得到1,8-萘二甲酸酐
  参考文献：
  名称：

  Synthesis of 3-vinyl-1,2,4-trioxolanes by a [3 + 2] cycloaddition of carbonyl oxides with .alpha.,.beta.-unsaturated carbonyl compounds

  摘要：

  The [3 + 2] cycloaddition of a carbonyl oxide, generated by the ozonolysis of a vinyl ether, to an alpha,beta-unsaturated aldehyde gave the 3-vinyl-1,2,4-trioxolane (alpha-vinyl ozonide) in moderate yield. In contrast, alpha,beta-unsaturated ketones showed a very poor reactivity with carbonyl oxides. Benzylidenecyclohexanones were exceptions, from which the corresponding 3-vinyl-1,2,4-trioxolanes were obtained in excellent yields. Reaction of the 3-vinyl-1,2,4-trioxolanes with ozone led to the formation of the corresponding diozonides.

  DOI：

  10.1021/jo00032a010
• 作为产物：
  描述：

  苯甲醛 、 1-苊酮 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 1.0h， 以87%的产率得到benzylidine acenaphthenone
  参考文献：
  名称：

  Parshad; Sharma, Journal of the Indian Chemical Society, 1989, vol. 66, # 2, p. 106 - 109

  摘要：

  DOI：

文献信息

• Compound, organic electroluminescent element material using same, organic electroluminescent element using this material, and electronic device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10763442B2

  公开（公告）日：2020-09-01

  A compound having a structure wherein at least 8-position or 9-position of fluoranthene is replaced by a nitrogen atom, a material for organic electroluminescence devices including the compound, and an organic electroluminescence device and an electronic equipment each including the material are provided. The compound is represented by formula (1): wherein A represents CR0 or N; R0 to R8 each independently represent a hydrogen atom or a substituent; at least one selected from R0 to R8 represents a substituent other than hydrogen atom; and groups selected from R0 to R8 which are bonded to adjacent carbon atoms may be bonded to each other to form a saturated or unsaturated ring structure.

  本发明提供了一种具有氟蒽至少 8 位或 9 位被氮原子取代的结构的化合物、一种包括该化合物的有机电致发光器件材料，以及一种包括该材料的有机电致发光器件和一种电子设备。该化合物由式（1）表示： 其中 A 代表 CR0 或 N；R0 至 R8 各自独立地代表氢原子或取代基；从 R0 至 R8 中选出的至少一个代表氢原子以外的取代基；从 R0 至 R8 中选出的与相邻碳原子键合的基团可相互键合以形成饱和或不饱和环结构。
• COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL USING SAME, ORGANIC ELECTROLUMINESCENT ELEMENT USING THIS MATERIAL, AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD

  公开号：US20160226002A1

  公开（公告）日：2016-08-04

  A compound having a structure wherein at least 8-position or 9-position of fluoranthene is replaced by a nitrogen atom, a material for organic electroluminescence devices including the compound, and an organic electroluminescence device and an electronic equipment each including the material are provided. The compound is represented by formula (1): wherein A represents CR 0 or N; R 0 to R 8 each independently represent a hydrogen atom or a substituent; at least one selected from R 0 to R 8 represents a substituent other than hydrogen atom; and groups selected from R 0 to R 8 which are bonded to adjacent carbon atoms may be bonded to each other to form a saturated or unsaturated ring structure.