[7-Formyl-6-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalen-2-yl] 4-(6-prop-2-enoyloxyhexoxy)benzoate | 1404198-28-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [7-Formyl-6-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalen-2-yl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• 英文别名: [7-formyl-6-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalen-2-yl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• CAS: 1404198-28-2
• 化学式: C₄₃H₄₄O₁₁
• 分子量: 736.816
• InChiKey: ROTOTQHDBCIQQB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  54
• 可旋转键数：
  27
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  141
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为反应物：
  描述：

  [7-Formyl-6-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalen-2-yl] 4-(6-prop-2-enoyloxyhexoxy)benzoate 、 2-肼基苯并噻唑 以 四氢呋喃 、 乙醇 为溶剂， 反应 7.0h， 以66.6%的产率得到
  参考文献：
  名称：

  POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL

  摘要：

  公开号：

  EP2703385B1
• 作为产物：
  描述：

  4-(6-acryloylhex-1-yloxy)benzoic acid 、 3,7-dihydroxynaphthalene-2-carboxaldehyde 在 N-甲基吡咯烷酮 、 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 反应 8.0h， 以64.2%的产率得到[7-Formyl-6-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxynaphthalen-2-yl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
  参考文献：
  名称：

  POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL

  摘要：

  公开号：

  EP2703385B1

文献信息

• Polymerizable compound, polymerizable composition, polymer, and optically anisotropic material
  申请人：ZEON CORPORATION

  公开号：US10647794B2

  公开（公告）日：2020-05-12

  The invention provides a polymerizable compound of formula (I), polymerizable composition, polymer, and optically anisotropic article capable of obtaining an optical film having a low melting point, excellent solubility, being manufactured at low cost, and of uniform polarized light conversion across a broad wavelength region. In formula (I): Y1 to Y6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—; G1 and G2 are independently a divalent C1-C20 aliphatic group; Z1 and Z2 are independently a C2-C10 alkenyl group substituted with a halogen atom; Ax is a C2-C30 organic group that includes at least one aromatic ring of an aromatic hydrocarbon ring or an aromatic hetero ring; Ay is H, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group; A1 is a trivalent aromatic group; A2 and A3 are independently a divalent C6-C30 aromatic group; and Q1 is H, or a C1-C6 alkyl group.

  本发明提供了一种可聚合的式(I)化合物、可聚合组合物、聚合物和光学各向异性制品，能够获得熔点低、溶解性好、制造成本低、在宽波长区域内偏振光转换均匀的光学薄膜。在式 (I) 中Y1 至 Y6 独立地为化学单键、-O-、-O-C(═O)-、-C(═O)-O-；G1 和 G2 独立地为二价 C1-C20 脂肪族基团；Z1 和 Z2 独立地为被卤原子取代的 C2-C10 烯基；Ax 是 C2-C30 有机基团，其中包括至少一个芳香烃环或芳香杂环；Ay 是 H、C1-C20 烷基、C2-C20 烯基、C3-C12 环烷基；A1 是三价芳香基团；A2 和 A3 独立地是二价 C6-C30 芳香基团；Q1 是 H 或 C1-C6 烷基。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC BODY
  申请人：Sakamoto Kei

  公开号：US20140142266A1

  公开（公告）日：2014-05-22

  The present invention relates to a polymerizable compound represented by a formula (I). The present invention provides a polymerizable compound, a polymerizable composition, a polymer, and an optically anisotropic article that are capable of obtaining an optical film having a low melting point, having excellent solubility, capable of being manufactured at low cost, and capable of uniform polarized light conversion across a broad wavelength region. [In formula: Y 1 to Y 6 are independently a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O— etc.; G 1 and G 2 are independently a divalent C1-C20 aliphatic group etc.; Z 1 and Z 2 are independently C2-C10 alkenyl group that is substituted with a halogen atom etc.; A x is a C2-C30 organic group that includes at least one aromatic ring selected from a group consisting of an aromatic hydrocarbon ring and an aromatic hetero ring; A y is a hydrogen atom, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C3-C12 cycloalkyl group etc.; A 1 is a trivalent aromatic group etc.; A 2 and A 3 are independently a divalent C6-C30 aromatic group etc.; and Q 1 is a hydrogen atom, or a C1-C6 alkyl group etc.]
• US9207360B2
  申请人：——

  公开号：US9207360B2

  公开（公告）日：2015-12-08
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC MATERIAL
  申请人：Zeon Corporation

  公开号：EP2703385B1

  公开（公告）日：2017-09-20