(N-naphthyl)-4-[N-(naphthalene-2-yl)-N-phenylamino]-1,8-naphthalimide | 1270931-47-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: (N-naphthyl)-4-[N-(naphthalene-2-yl)-N-phenylamino]-1,8-naphthalimide
• 英文别名: NBID-2；2-naphthalen-1-yl-6-(N-naphthalen-2-ylanilino)benzo[de]isoquinoline-1,3-dione
• CAS: 1270931-47-9
• 化学式: C₃₈H₂₄N₂O₂
• 分子量: 540.621
• InChiKey: COSZRCLRZHRMKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  42
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  6-bromo-2-(naphthalen-1-yl)-1H-benzo[de]isoquinoline-1,3(2H)-dione 、 N-苯基-2-萘胺 在 三叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以74%的产率得到(N-naphthyl)-4-[N-(naphthalene-2-yl)-N-phenylamino]-1,8-naphthalimide
  参考文献：
  名称：

  A New Orange-Light-Emitting Materials Based on (N-naphthyl)-1,8-naphthalimide for OLED Applications

  摘要：

  A new orange emitters consisting of 2-naphthalene-1-yl-benzo[de]isoquinoline-1, 3-dione (NBID) as core, and bulky diphenylamine or naphthylphenylamine substituted as a side units were synthesized and characterized. These compounds have a non-planar molecule conformation, donor-acceptor structure, and high thermal stability. Using these materials as dopant, we fabricated electroluminescence device with a structure of ITO/DNTPD/NPD/NBID-1, 2 (3 wt% in Alq(3))/Alq(3)/LiF/Al. The luminance-efficiency of NBID derivatives (1 and 2) were showed 6.6 cd/A and 5.9 cd/A, respectively. The orange emissions were observed with Commission International de I'Eclairage (CIE) coordinates of (0.46, 0.52) for NBID-1 and (0.48, 0.52) for NBID-2, respectively.

  DOI：

  10.1080/15421400903217751

文献信息

• A New Orange-Light-Emitting Materials Based on (N-naphthyl)-1,8-naphthalimide for OLED Applications
  作者：Sung Ouk Jung、Wei Yuan、Jin Uk Ju、Shuang Zhang、Yun Hi Kim、Jong Tae Je、Soon Ki Kwon

  DOI：10.1080/15421400903217751

  日期：2009.11.11

  A new orange emitters consisting of 2-naphthalene-1-yl-benzo[de]isoquinoline-1, 3-dione (NBID) as core, and bulky diphenylamine or naphthylphenylamine substituted as a side units were synthesized and characterized. These compounds have a non-planar molecule conformation, donor-acceptor structure, and high thermal stability. Using these materials as dopant, we fabricated electroluminescence device with a structure of ITO/DNTPD/NPD/NBID-1, 2 (3 wt% in Alq(3))/Alq(3)/LiF/Al. The luminance-efficiency of NBID derivatives (1 and 2) were showed 6.6 cd/A and 5.9 cd/A, respectively. The orange emissions were observed with Commission International de I'Eclairage (CIE) coordinates of (0.46, 0.52) for NBID-1 and (0.48, 0.52) for NBID-2, respectively.