1-[2]naphthyloxy-2-vinyloxy-ethane | 26576-19-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-[2]naphthyloxy-2-vinyloxy-ethane
• 英文别名: 1-[2]Naphthyloxy-2-vinyloxy-aethan；2-(2-Ethenoxyethoxy)naphthalene
• CAS: 26576-19-2
• 化学式: C₁₄H₁₄O₂
• 分子量: 214.264
• InChiKey: NLDJRLVSKQKBQV-UHFFFAOYSA-N

物化性质

• 沸点：
  345.9±25.0 °C(Predicted)
• 密度：
  1.079±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(2-萘氧基)乙醇 、 乙炔 在 氢氧化钾 作用下， 生成 1-[2]naphthyloxy-2-vinyloxy-ethane
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：

文献信息

• COMPOUND FOR FORMING ORGANIC FILM, COMPOSITION FOR FORMING ORGANIC FILM, METHOD FOR FORMING ORGANIC FILM, AND PATTERNING PROCESS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20170184968A1

  公开（公告）日：2017-06-29

  A compound for forming an organic film shown by the formula (1A), R—(—X) m1 (1A) wherein R represents a single bond or an organic group having 1 to 50 carbon atoms; X represents a group shown by formula (1B); and ml represents an integer satisfying 2≦m1≦10, wherein X 2 represents a divalent organic group having 1 to 10 carbon atoms; n1 represents 0 or 1; n2 represents 1 or 2; X 3 represents a group shown by the formula (1C); and n5 represents 0, 1, or 2, wherein R 10 represents a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms, wherein a hydrogen atom of the benzene ring in formula (1C) may be substituted with a methyl group or methoxy group. This compound for forming an organic film can provide organic film composition having good dry etching resistance, heat resistance to 400° C. or higher, high filling and planarizing properties.

  一种用于形成有机薄膜的化合物，其化学式为(1A)，R—(—X)m1(1A)，其中R代表一个单键或具有1至50个碳原子的有机基团；X代表化学式(1B)所示的基团；m1代表满足2≦m1≦10的整数，其中X2代表具有1至10个碳原子的二价有机基团；n1代表0或1；n2代表1或2；X3代表化学式(1C)所示的基团；n5代表0、1或2，其中R10代表氢原子或具有1至10个碳原子的饱和或不饱和碳氢基团，化学式(1C)中苯环的氢原子可能被甲基基团或甲氧基取代。这种用于形成有机薄膜的化合物可以提供具有良好干法刻蚀抗性、耐高温至400°C或更高、高填充和平整化性能的有机薄膜组合物。
• Acting energy radiation curable ink-jet ink, ink-jet recoring method, and printed matter
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2228415A1

  公开（公告）日：2010-09-15

  The present invention provides an actinic energy radiation curable ink-jet ink exhibiting excellent ink storage stability, nozzle ink repellency, and ejection stability, and also exhibiting excellent curability, anti-abrasion properties, solvent resistance, flexibility, weather resistance, and substrate adhesion properties even under various ambience factors and irradiation conditions, as well as an ink-jet recording method and printed matter using the same. In an actinic energy radiation curable ink-jet ink containing a cationically polymerizable compound and a photo-cationic polymerization initiator, an actinic energy radiation curable ink-jet ink wherein a cationically polymerizable compound having a vinyl ether group as a reactive group is contained at 50.0% by mass or more and the halogen ion content is 1.0 µg/g of the ink - 100 µg/g of the ink.

  本发明提供了一种在各种环境因素和辐照条件下都能表现出优异的储墨稳定性、喷嘴拒墨性和喷出稳定性，并且还能表现出优异的固化性、抗磨损性、耐溶剂性、柔韧性、耐候性和基材附着性的可辐射固化喷墨墨水，以及使用该墨水的喷墨记录方法和印刷品。在含有阳离子可聚合化合物和光阳离子聚合引发剂的可辐射固化喷墨墨水中，阳离子可聚合化合物中具有乙烯基醚基团作为活性基团的阳离子可聚合化合物的质量含量为 50.0% 或以上，卤素离子含量为 1.0 µg/g - 100 µg/g。
• Actinic energy radiation curable ink-jet ink and ink-jet image forming method
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2236568A1

  公开（公告）日：2010-10-06

  Provided is an actinic energy radiation curable ink-jet ink, an ink-jet recording method, and printed matter satisfying ink storage stability, ejection stability, weather resistance, flexibility, safety, odorless properties. An actinic energy radiation curable ink-jet ink comprises a cationically polymerizable compound and a photo-cationic polymerization initiator, wherein the cationically polymerizable compound comprises a vinyl ether group as a. reactive group, the photo-cationic polymerization initiator is a photo acid generator, a amount of generation of protonic acid from the photo acid generator is 1 x 10-4 mol/L or less, and comprising a radical polymerization inhibitor; wherein the amount of generation of protonic acid is defined as a difference of a hydrogen ion concentration (mol/L) in dioxane solution between immediately after preparation and after refluxing when 0.02 mol/L of the photo acid generator in dioxane solution are refluxed 20 hours under atmospheric pressure.

  本发明提供了一种可辐射固化的喷墨墨水、一种喷墨记录方法以及满足墨水储存稳定性、弹射稳定性、耐候性、柔韧性、安全性和无味特性的印刷品。一种可辐射固化的喷墨墨水由阳离子可聚合化合物和光阳离子聚合引发剂组成，其中阳离子可聚合化合物由乙烯基醚基作为反应基团，光阳离子聚合引发剂由乙烯基醚基作为反应基团。其中，阳离子可聚合化合物由乙烯基醚基团作为反应基团，光阳离子聚合引发剂是一种光酸发生剂，光酸发生剂生成质子酸的量为 1 x 10-4 mol/L 或更少，还包括一种自由基聚合抑制剂；其中，质子酸的生成量定义为在大气压下将 0.02 mol/L 的光酸发生剂在二噁烷溶液中回流 20 小时后，制备后立即与回流后二噁烷溶液中氢离子浓度（mol/L）之差。
• Image forming method using actinic energy radiation curable ink-jet ink and printed matter obtained thereby
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2266812A2

  公开（公告）日：2010-12-29

  Provided is an actinic radiation curable inkjet ink capable of high sensitivity and high glossy image; and an image forming method utilizing the same. An actinic radiation curable inkjet ink comprising a photo polymerization initiator and a polymerizable monomer, wherein a surface free energy γs of an ink layer cured by an actinic radiation is in the range of 30 to 50 mJ/m2 and a polar component γsp is in the range of 5 to 15 mJ/m2; wherein γsd, γsp and γsh each represent a non-polar component, a polar component and a hydrogen bond component of a surface free energy of a solid surface based on Young-Fowkes Equation, provided that the surface free energy is represented by γs=γsd+γsp+γsh.

  本发明提供了一种能产生高灵敏度和高光泽度图像的光辐射固化喷墨墨水，以及利用该墨水的图像形成方法。一种光辐射固化喷墨墨水，由光聚合引发剂和可聚合单体组成，其中光辐射固化墨层的表面自由能 γs 在 30 至 50 mJ/m2 之间，极性分量 γsp 在 5 至 15 mJ/m2 之间；其中，γsd、γsp 和 γsh 分别代表基于 Young-Fowkes 方程的固体表面自由能的非极性分量、极性分量和氢键分量，条件是表面自由能由γs=γsd+γsp+γsh 表示。
• Actinic ray curable ink-jet ink composition, image formation method employing the same, and ink-jet recording apparatus
  申请人：Takabayashi Toshiyuki

  公开号：US20050113483A1

  公开（公告）日：2005-05-26

  Disclosed is an actinic ray curable ink-jet ink composition containing a photopolymerizable compound, a sulfonium salt (compound A) as a photoinitiator, which does not release benzene on actinic ray exposure, and a compound (compound B) as a sensitizing agent selected from the group consisting of (i) a polycyclic aromatic compound having a hydroxyl group, a substituted or unsubstituted aralkyloxy group or a substituted or unsubstituted alkoxy group, (ii) a carbazole derivative, and (iii) a thioxanthone derivative.

  本发明公开了一种可紫外线固化的喷墨墨水组合物，该组合物含有一种可光聚合的化合物、一种作为光引发剂的锍盐（化合物 A），该化合物在紫外线照射下不会释放苯、 以及作为敏化剂的化合物（化合物 B），该化合物选自以下组别：(i) 具有羟基、取代或未取代的烷氧基或取代或未取代的烷氧基的多环芳烃化合物；(ii) 咔唑衍生物；以及 (iii) 硫酮衍生物。