N²,N²,N⁴,N⁴,N⁶-pentaethyl-[1,3,5]triazine-2,4,6-triyltriamine | 109099-13-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N²,N²,N⁴,N⁴,N⁶-pentaethyl-[1,3,5]triazine-2,4,6-triyltriamine
• 英文别名: N²,N²,N⁴,N⁴,N⁶-Pentaaethyl-[1,3,5]triazin-2,4,6-triyltriamin；2-N,2-N,4-N,4-N,6-N-pentaethyl-1,3,5-triazine-2,4,6-triamine
• CAS: 109099-13-0
• 化学式: C₁₃H₂₆N₆
• 分子量: 266.39
• InChiKey: MVKLXPLSPYLQFJ-UHFFFAOYSA-N

物化性质

• 沸点：
  120-121 °C(Press: 0.4 Torr)
• 密度：
  1.078±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  57.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  可乐津 、 乙胺 在 1,4-二氧六环 、 水 作用下， 生成 N²,N²,N⁴,N⁴,N⁶-pentaethyl-[1,3,5]triazine-2,4,6-triyltriamine
  参考文献：
  名称：

  Cyanuric Chloride Derivatives. II. Substituted Melamines

  摘要：

  DOI：

  10.1021/ja01151a002

文献信息

• METHODS FOR MODIFYING 1,3,5-TRIAZINE DERIVATIVES
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0882720A1

  公开（公告）日：1998-12-09

  A method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with an alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce an alkyl or alkenyl group into each amino or monosubstituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with a dihydric alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce a hydroxylated alkyl group into each amino or monosubstituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified substituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as high-purity compounds by a general separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification. According to applications (for example, use as modifier additives, in particular a flame-retardant and a plasticizer for resins), the reaction mixture can be used as it is without being separated. Many of the substituted triazine derivatives obtained have been relatively difficult to synthesize or expensive. Since many of the derivatives are interesting with respect to their physical properties, e.g., solubility in water and in various organic solvents, high-temp. stability, melting point, boiling point, and basicity, they are thought to have a wider range of applications than conventional ones.

  一种改性 1，3，5-三嗪衍生物的方法，其特征在于在金属催化剂和氢的存在下，通过加热使任一环碳原子上具有至少一个氨基或单取代氨基的 1，3，5-三嗪衍生物与醇反应，从而在每个氨基或单取代氨基中引入一个烷基或烯基；另一种改性 1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢气存在下，使任一环碳原子上具有至少一个氨基或单取代氨基的 1,3,5-三嗪衍生物与二元醇反应，从而在每个氨基或单取代氨基中引入羟基烷基；以及通过上述方法获得的 1,3,5-三嗪衍生物。这样制得的各种改性取代的 1,3,5-三嗪衍生物通常以混合物的形式获得。这些衍生物可作为高纯度化合物通过有机化合物的一般分离方法分离出来，这些化合物可用于说明书中提到的各种应用中。根据用途（例如用作改性添加剂，特别是阻燃剂和树脂增塑剂），反应混合物可以不经分离直接使用。所获得的许多取代三嗪衍生物都比较难以合成或价格昂贵。由于许多衍生物在物理性质（如在水和各种有机溶剂中的溶解性、高温稳定性、熔点、沸点和碱性）方面都很有趣，因此它们被认为比传统的衍生物具有更广泛的用途。
• ANTISENSE MODULATION OF CONNECTIVE TISSUE GROWTH FACTOR EXPRESSION
  申请人：ISIS PHARMACEUTICALS, INC.

  公开号：EP1461352A2

  公开（公告）日：2004-09-29
• ANTISENSE MODULATION OF VASCULAR ENDOTHELIAL GROWTH FACTOR RECEPTOR-1 EXPRESSION
  申请人：ISIS PHARMACEUTICALS, INC.

  公开号：EP1465578A2

  公开（公告）日：2004-10-13
• EASY-TO-CLEAN, MECHANICALLY STABLE COATING COMPOSITION FOR METALLIC SURFACES AND PROCESS FOR COATING A SUBSTRATE USING SAID COMPOSITION
  申请人：Posset Uwe

  公开号：US20090181175A1

  公开（公告）日：2009-07-16

  The present invention is directed to an optically clear coating made from a composition comprising an epoxy-melamine resin. The coating is obtained on a metallic substrate and has a very rigid structure and a unique combination of properties that includes hydrophobicity/easy-to-clean, adhesion to bright chrome, abrasion resistance and chemical resistance. The coating composition comprises (A) a mixture of at least one hydrolysable silane and one hydrolysable metal compound, the compounds of said mixture being partly or fully hydrolyzed and partly or fully condensed, (B) at least one melamine derivative selected from derivatives having formula (C 3 N 3 )(NR 4 R 5 ) 3 , and derivatives having formula (C 3 N 3 )(NR 4 R 5 ) 3-p (NR 4 R 6 ) p , wherein R 4 and R 5 are independently selected from H, hydroxymethylene and alkoxymethylene, with the proviso that at least one of the R 4 groups is a hydroxymethylene or alkoxymethylene group, and R 6 is —CH 2 —NR 4 (C 3 N 3 )(NR 4 R 5 ) 2 or —CH 2 -o—CH 2- NR 4 (C 3 N 3 )(NR 4 R 5 ) 2 , and p is 1 or 2, and either at least one partially or fully fluorinated, at least partly hydrolyzed and condensed silane compound, this compound being part of the said mixture (A) of hydrolysable silanes, or (C) at least one partially or fully fluorinated organic compound containing at least one group which may bind to hydroxy groups.
• Melamine Based Mannich-Compounds and a Process for Obtaining the Same
  申请人：Dicke René

  公开号：US20120277429A1

  公开（公告）日：2012-11-01

  The present invention relates to Melamine based Mannich compounds of the general formulae (1)-(12) and a process for synthesizing melamine based Mannich-products comprising the steps of a) reacting at least one substituted melamine with at least one aldehyde, in particular formaldehyde, under basic conditions to form at least one OH-containing compound, b) reacting the at least one OH-containing compound in the presence of a catalyst to form at least one mannich-base, c1) reacting the at least one mannich-base with at least one enol-forming carbonyl compound, or c2) reacting the at least one mannich-base with at least one aromatic compound, and d) working up the reaction mixture. The invention relates further to precondensates obtainable from these products.