4,6-bis[3-(4-dibenzothienyl)phenyl]pyrimidine | 1425656-80-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 4,6-bis[3-(4-dibenzothienyl)phenyl]pyrimidine
• 英文别名: 4,6-bis[3-(dibenzothiophen-4-yl)phenyl]pyrimidine；4,6-Bis[3-(dibenzothiophen-4-yl)phenyl]pyrimidine；4,6-bis(3-dibenzothiophen-4-ylphenyl)pyrimidine
• CAS: 1425656-80-9
• 化学式: C₄₀H₂₄N₂S₂
• 分子量: 596.776
• InChiKey: ALEAISKRDWWJRK-UHFFFAOYSA-N

物化性质

• 密度：
  1.318±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,6-二氯嘧啶 、 B-[3-(4-二苯并噻吩基)苯基]硼酸 在 bis-triphenylphosphine-palladium(II) chloride 、 sodium carbonate 作用下， 以 水 为溶剂， 反应 1.5h， 以79%的产率得到4,6-bis[3-(4-dibenzothienyl)phenyl]pyrimidine
  参考文献：
  名称：

  Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Novel Organic Compound

  摘要：

  一种发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是一种具有大于或等于-3.5电子伏特且小于或等于-2.5电子伏特的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是具有嘧啶骨架的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。

  公开号：

  US20130048964A1

文献信息

• Organic Compound, Light-Emitting Element, Display Module, Lighting Module, Light-Emitting Device, Display Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150243892A1

  公开（公告）日：2015-08-27

  A light-emitting element with high emission efficiency. The light-emitting element includes a pair of electrodes and an EL layer between the pair of electrodes. In the light-emitting element, the EL layer contains at least a light-emitting material, the light-emitting material is a 1,6-bis(diphenylamino)pyrene derivative, and a structural change between an excited state and a ground state in the 1,6-bis(diphenylamino)pyrene derivative is smaller than that in a 1,6-bis(diphenylamino)pyrene derivative in which hydrogen is bonded to ortho positions of two phenyl groups of each of two diphenylamino groups.

  一个发光效率高的发光元件。该发光元件包括一对电极和一对电极之间的EL层。在发光元件中，EL层包含至少一种发光材料，发光材料为1,6-双(二苯基氨基)芘衍生物，且1,6-双(二苯基氨基)芘衍生物在激发态和基态之间的结构变化小于在每个二苯基氨基组的两个苯基的邻位上连接氢的1,6-双(二苯基氨基)芘衍生物。
• Organic compound, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US09419237B2

  公开（公告）日：2016-08-16

  A novel organic compound having a high hole-transport property is provided. A long-lifetime light-emitting element is provided. An organic compound represented by General Formula (G0) is provided. In General Formula (G0), Ar1 represents a substituted or unsubstituted naphthyl group, Ar2 represents a substituted or unsubstituted carbazolyl group, Ar3 represents a substituted or unsubstituted fluorenyl group or a substituted or unsubstituted spirofluorenyl group, and α1 and α2 each independently represent a substituted or unsubstituted phenylene group or a substituted or unsubstituted biphenyldiyl group.

  提供了一种具有高空穴传输性能的新型有机化合物。提供了一种长寿命的发光元件。提供了一种由通用式（G0）表示的有机化合物。在通用式（G0）中，Ar1代表取代或未取代的萘基团，Ar2代表取代或未取代的咔唑基团，Ar3代表取代或未取代的芴基团或取代或未取代的螺芴基团，α1和α2各自独立地代表取代或未取代的苯基团或取代或未取代的联苯基团。
• Light-Emitting Element, Lighting Device, Light-Emitting Device, and Electronic Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20160343968A1

  公开（公告）日：2016-11-24

  A light-emitting element includes a first electrode; a first light-emitting layer over the first electrode, containing a first phosphorescent compound and a first host material; a second light-emitting layer over the first light-emitting layer, containing a second phosphorescent compound and a second host material; a third light-emitting layer over the second light-emitting layer, containing a third phosphorescent compound and a third host material; and a second electrode over the third light-emitting layer. Between peaks of emission spectra of the first, second, and third phosphorescent compounds, the peak of the emission spectrum of the second phosphorescent compound is on the longest wavelength side and that of the emission spectrum of the third phosphorescent compound is on the shortest wavelength side. The third host material has higher triplet excitation energy than the first host material and the second host material.

  一个发光元件包括：第一电极；设置在第一电极上的第一发光层，包含第一磷光化合物和第一主体材料；设置在第一发光层上的第二发光层，包含第二磷光化合物和第二主体材料；设置在第二发光层上的第三发光层，包含第三磷光化合物和第三主体材料；以及设置在第三发光层上的第二电极。在第一、第二和第三磷光化合物的发射光谱的峰值之间，第二磷光化合物的发射光谱峰值位于最长波长侧，而第三磷光化合物的发射光谱峰值位于最短波长侧。第三主体材料具有高于第一主体材料和第二主体材料的三重态激发能。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20160028027A1

  公开（公告）日：2016-01-28

  An object is to provide a novel organometallic complex. Another object is to provide an organometallic complex exhibiting green to blue phosphorescence. Another object is to provide an organometallic complex having deep HOMO and exhibiting green to blue phosphorescence. Another object is to provide a light-emitting element with high emission efficiency. Another object is to provide a light-emitting element exhibiting green to blue phosphorescence and having low drive voltage. To provide an organometallic complex which includes a 1,2,4-triazole skeleton and in which an N-carbazolyl group is bonded to the 3-position of the 1,2,4-triazole skeleton via a phenylene group, a phenyl group is bonded to the 4-position of the 1,2,4-triazole skeleton, the 2-position of the 1,2,4-triazole skeleton coordinates to iridium, and the phenylene group is bonded to the iridium. To provide a light-emitting element including the organometallic complex as an emission center.

  一个目的是提供一种新型的有机金属配合物。另一个目的是提供一种显示绿色到蓝色磷光的有机金属配合物。另一个目的是提供一种具有深层HOMO并能显示绿色到蓝色磷光的有机金属配合物。另一个目的是提供一种具有高发射效率的发光元件。另一个目的是提供一种显示绿色到蓝色磷光且驱动电压低的发光元件。提供一种包括1,2,4-三唑骨架的有机金属配合物，其中，一个N-咔唑基团通过一个苯环基团与1,2,4-三唑骨架的3-位键合，一个苯基团与1,2,4-三唑骨架的4-位键合，1,2,4-三唑骨架的2-位与铱配位，并且苯环基团与铱键合。提供一种包括上述有机金属配合物作为发射中心的发光元件。
• [EN] ORGANOMETALLIC COMPLEX, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2016012910A1

  公开（公告）日：2016-01-28

  An object is to provide a novel organometallic complex. Another object is to provide an organometallic complex exhibiting green to blue phosphorescence. Another object is to provide an organometallic complex having deep HOMO and exhibiting green to blue phosphorescence. Another object is to provide a light-emitting element with high emission efficiency. Another object is to provide a light-emitting element exhibiting green to blue phosphorescence and having low drive voltage. To provide an organometallic complex which includes a 1,2,4-triazole skeleton and in which an N-carbazolyl group is bonded to the 3-position of the 1,2,4-triazole skeleton via a phenylene group, a phenyl group is bonded to the 4-position of the 1,2,4-triazole skeleton, the 2-position of the 1,2,4-triazole skeleton coordinates to iridium, and the phenylene group is bonded to the iridium. To provide a light-emitting element including the organometallic complex as an emission center.

  一个目标是提供一种新型的有机金属配合物。另一个目标是提供一种显示绿色到蓝色磷光的有机金属配合物。再一个目标是提供一种具有深层HOMO并能显示绿色到蓝色磷光的有机金属配合物。另一个目标是提供一种具有高发射效率的发光元件。再一个目标是提供一种显示绿色到蓝色磷光且具有低驱动电压的发光元件。提供一个包括1,2,4-三唑骨架的有机金属配合物，其中，一个N-咔唑基团通过一个苯基团连接到1,2,4-三唑骨架的3位，一个苯基团连接到1,2,4-三唑骨架的4位，1,2,4-三唑骨架的2位与铱配位，并且苯基团与铱相连。提供一个以该有机金属配合物作为发射中心的发光元件。