perfluorononanoyl peroxide | 79754-26-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: perfluorononanoyl peroxide
• 英文别名: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Heptadecafluorononanoyl 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononaneperoxoate
• CAS: 79754-26-0
• 化学式: C₁₈F₃₄O₄
• 分子量: 926.141
• InChiKey: BECCBTJLCWDIHG-UHFFFAOYSA-N

物化性质

• 沸点：
  304.3±52.0 °C(Predicted)
• 密度：
  1.785±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  56
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  38

反应信息

• 作为反应物：
  描述：

  perfluorononanoyl peroxide 以 1,1,2-三氯三氟乙烷（CFC-113） 、 水 为溶剂， 生成 全氟壬酸
  参考文献：
  名称：

  Ostrizhko, F. N.; Yuminov, V. S.; Salivon, N. Ya., Journal of applied chemistry of the USSR, 1981, vol. 54, # 8, p. 1555 - 1559

  摘要：

  DOI：

文献信息

• NOVEL FLUORINE COMPOUND AND FLUOROPOLYMER
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1679311A1

  公开（公告）日：2006-07-12

  The present invention provides a fluoropolymer having excellent mechanical strength and transparency, having a high glass transition point suitable for high-temperature use, and having a high refractive index. The present invention provides a novel compound represented by the following formula (1) and a fluoropolymer comprising monomer unit (2) formed by the polymerization of such a compound. RAF, RBF, RCF, RDF: each independently is a fluorine atom, a chlorine atom, a perfluoro monovalent saturated hydrocarbon group or a perfluoro(partially chlorinated monovalent saturated hydrocarbon) group, provided that at least one of RAF, RBF, RCF and RDF is a perfluoro(partially chlorinated monovalent saturated hydrocarbon) group.

  本发明提供一种具有优异机械强度和透明度的氟聚合物，具有适用于高温使用的高玻璃转变点，并具有高折射率。本发明提供一种由以下式（1）表示的新型化合物以及由此类化合物聚合形成的单体单元（2）构成的氟聚合物。RAF、RBF、RCF、RDF：每个独立地是氟原子、氯原子、全氟单价饱和碳氢基团或全氟（部分氯化的单价饱和碳氢基团），前提是RAF、RBF、RCF和RDF中至少有一个是全氟（部分氯化的单价饱和碳氢基团）。
• Fluorine-containing diene, its production method and its polymer
  申请人：Asahi Glass Company, Limited

  公开号：US20010047115A1

  公开（公告）日：2001-11-29

  A fluorine-containing diene represented by the formula 1: CF 2 ═CF(CF 2 ) n CXYOCF═CF 2 Formula 1 wherein each of X and Y which are independent of each other, is an atom selected from a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom and an iodine atom, provided that X and Y are not simultaneously hydrogen atoms or fluorine atoms, and n is an integer of from 1 to 3.

  一种含氟二烯，其化学式为1:CF2═CF(CF2)nCXYOCF═CF2，其中X和Y分别为氢原子、氟原子、氯原子、溴原子或碘原子中的一种，且X和Y不能同时为氢原子或氟原子，n为1至3的整数。
• Method for production of fluorine-containing aromatic derivative
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0155093A2

  公开（公告）日：1985-09-18

  A fluorine-containing aromatic derivative useful as an intermediate for the synthesis of medicines, agricultural pesticides, and water-repellent oil-repellent agents is produced by a method characterized by causing a di(haloacyl)-peroxide of the general formula: wherein X denotes a fluorine, chlorine, or hydrogen atom and n denotes an integer of the value of 1 to 10, to react with benzene, a mono-substituted benzene, naphthalene, or a mono-substituted naphthalene thereby introducing an X(CF2)n-group into the benzene ring or the naphthalene ring.

  一种可用作合成药物、农用杀虫剂和憎水憎油剂中间体的含氟芳香族衍生物的制备方法，其特征在于使通式如下的二（卤代酰基）过氧化物发生反应： 其中 X 表示氟原子、氯原子或氢原子，n 表示 1 至 10 的整数，与苯、单取代苯、萘或单取代萘反应，从而将 X(CF2)n 基团引入苯环或萘环中。
• PERFLUOROALKYLATED NAPHTHALOCYANINE DERIVATIVE, PRODUCTION THEREOF, AND OPTICAL RECORDING MEDIUM
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0491951A1

  公开（公告）日：1992-07-01

  A perfluoroalkylated naphthalocyanine derivative which is excellent in weathering resistance and very highly soluble in various solvents and has a specified structure adapted for film formation; and an optical recording medium produced therefrom which enables recording by means of focused beams of a semiconductor laser. The above derivative is produced by the reaction of a perfluoroalkanoyl peroxide having a specified structure with a naphthalocyanine.

  一种全氟烷基化萘酞菁衍生物，其耐候性极佳，在各种溶剂中的溶解度极高，并具有适于成膜的特定结构；以及由其制成的一种光学记录介质，可通过半导体激光的聚焦光束进行记录。上述衍生物是由具有特定结构的全氟烷酰基过氧化物与萘酞菁反应生成的。
• PROCESS FOR PRODUCING TETRAFLUOROETHYLENE/HEXAFLUOROPROPYLENE COPOLYMER
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0606492A1

  公开（公告）日：1994-07-20

  A process for producing a tetrafluoroethylene/hexafluoropropylene copolymer by copolymerizing tetrafluoroethylene with hexafluoropropylene in an aqueous medium using di(fluoroacyl) peroxide as the polymerization initiator, wherein a fluoroalkylcarboxylic acid is fed to the reaction system. The obtained copolymer has a stabilized molecular weight and the polymerization initiator can be utilized more efficiently.

  一种生产四氟乙烯/六氟丙烯共聚物的工艺，其方法是使用二（氟酰基）过氧化物作为聚合引发剂，在水介质中使四氟乙烯与六氟丙烯共聚，其中向反应体系加入氟烷基羧酸。得到的共聚物分子量稳定，聚合引发剂的使用效率更高。