1,1-bis-(4-chloro-phenyl)-2,2-diphenyl-ethane-1,2-diol | 80039-87-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,1-bis-(4-chloro-phenyl)-2,2-diphenyl-ethane-1,2-diol
• 英文别名: 1,2-Dihydroxy-2,2-diphenyl-1,1-bis-(4-chlor-phenyl)-aethan；1,1-Bis-(4-chlor-phenyl)-2,2-diphenyl-aethan-1,2-diol；1,1-Bis(4-chlorophenyl)-2,2-diphenylethane-1,2-diol
• CAS: 80039-87-8
• 化学式: C₂₆H₂₀Cl₂O₂
• 分子量: 435.35
• InChiKey: FBTYPWJRYOYHQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis-(4-chloro-phenyl)-2,2-diphenyl-ethane-1,2-diol 、 碘 、 溶剂黄146 生成 alkaline earth salt of/the/ methylsulfuric acid 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Tribology of MEMS

  摘要：

  由于大表面积与体积比以及低恢复力，不受欢迎的粘附和摩擦可能主导微电子机械系统（MEMS）设备的性能。为了确保MEMS设备的功能和可靠性，摩擦学家必须了解从宏观到分子级的广泛长度尺度范围内粘附、摩擦和磨损的起源。在本文中，我们概述了挑战、成功以及朝着基本理解迈出的初步步骤。

  DOI：

  10.1557/mrs2001.65
• 作为产物：
  描述：

  二苯乙醇酸甲酯 、 4-氯苯基溴化镁 在 乙醚 、 苯 作用下， 生成 1,1-bis-(4-chloro-phenyl)-2,2-diphenyl-ethane-1,2-diol
  参考文献：
  名称：

  Tribology of MEMS

  摘要：

  由于大表面积与体积比以及低恢复力，不受欢迎的粘附和摩擦可能主导微电子机械系统（MEMS）设备的性能。为了确保MEMS设备的功能和可靠性，摩擦学家必须了解从宏观到分子级的广泛长度尺度范围内粘附、摩擦和磨损的起源。在本文中，我们概述了挑战、成功以及朝着基本理解迈出的初步步骤。

  DOI：

  10.1557/mrs2001.65

文献信息

• Reactive plastisol dispersion
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0124808A1

  公开（公告）日：1984-11-14

  This invention reiates to a reactive plastisol dispersion composition comprising (1) at least one polyvinyl acetal thermoplast in powder form, which is insoluble in the plasticizer at room temperature and plasticizable at a temperature at or above fluxing temperature, and which thermoplast has a flow temperature at 1,000 psi of between 100° and 200°C; (2) a liquid plasticizer comprising an epoxide resin having on average more than one epoxide group in the molecule or a mixture of said epoxide resins in combination with a member of the group consisting of (a) at least one ethylenically unsaturated monomer, oligomer or prepolymer of the formula: wherein R is H or CH3, R, is an organic moiety and n is 1 or more, (b) at least one unsaturated polyester containing the group: wherein R2 and R3 are organic moieties, x is 0-20 and y is 1-20 and y is 1-20, and (c) a mixture of (a) and (b); (3) an effective amount of a latent curing agent for said epoxide resin, which is inactive in the epoxide resin at room temperature and which is selected from the group consisting of dicyandiamide, melamine,guanamine, polycarboxylic acid polyhydrazides, carboxylic acid imides, imidazole derivatives, BF3 adducts and diaryliodonium salts; and, optionally, (4) a curing agent for the plasticizer group member comprising a free radical thermal initiator. The plastisol dispersion after fluxing can form a thermoset sealant, coating or adhesive on exposure to heat.

  本发明涉及一种反应性塑溶胶分散体组合物，其中包括 (1) 至少一种粉末状的聚乙烯醇缩醛热塑性塑料，它在室温下不溶于增塑剂，在助熔温度或更高的温度下可增塑，该热塑性塑料在 1,000 psi 下的流动温度在 100° 至 200°C 之间； (2) 液体增塑剂，包括分子中平均含有一个以上环氧基团的环氧树脂或上述环氧 树脂的混合物，并与以下组成成分结合使用 (a) 至少一种乙烯基不饱和单体、低聚物或预聚物，其式如下 其中 R 为 H 或 CH3，R 为有机分子，n 为 1 或更多、 (b) 至少一种含有以下基团的不饱和聚酯： 其中 R2 和 R3 为有机分子，x 为 0-20，y 为 1-20，以及 (c) (a)和(b)的混合物； (3) 有效量的用于所述环氧树脂的潜伏固化剂，该固化剂在室温下在环氧树脂中不活跃，且选 自二氰胺、三聚氰胺、胍胺、聚羧酸多酰肼、羧酸酰亚胺、咪唑衍生物、BF3 加合物和二元碘鎓盐组成的组； 以及 (4) 用于增塑剂基团成员的固化剂，包括自由基热引发剂。 经过助熔处理的塑溶胶分散体受热后可形成热固性密封剂、涂层或粘合剂。
• One component thermoset composition
  申请人：W.R. GRACE & CO.

  公开号：EP0130389A2

  公开（公告）日：1985-01-09

  @ This invention relates to a one component thermosettable reactive plastisol composition comprising (1) at least one thermoplast in powder form containing at least two active hydrogen groups, e.g., polyvinyl acetals, polyvinyl alcohol, acrylic or methacrylic acid copolymers, acrylamides, hydroxyethyl acrylate or methacrylate copolymer; (2) a liquid plasticizer having isocyanate or blocked isocyanate terminal groups, either per se or in combination with a plasticizer group member selected from the group consisting of (a) an acrylate terminated monomer, oligomer or propolymer, (b) an epoxide resin containing more than one epoxide group per molecule, and (c) a mixture of (a) and (b). The composition can optionally also contain a conventional accelerator for the reaction between isocyanate and active hydrogen groups as well as latent curing agents for the epoxide resin and free radical thermal initiators for the acrylate terminated monomer, oligomer or prepolymer. The composition is useful as an adhesive, sealant or coating and when heated at or above its fluxing temperature acquires good handling strength due to plasticization and good structural strength after heat curing. Further curing on aging is obtained through the reaction of moisture with any isocyanate residue.

  @ 本发明涉及一种单组分热固性反应型塑溶胶组合物，其中包括 (1) 至少一种含有至少两个活性氢基的粉末状热塑性塑料，例如聚乙烯醇、聚乙烯醇、丙烯酸或甲基丙烯酸共聚物、丙烯酰胺、丙烯酸羟乙酯或甲基丙烯酸酯共聚物； (2) 具有异氰酸酯或嵌段异氰酸酯末端基团的液体增塑剂，其本身或与增塑剂基 团成员结合使用均可，增塑剂基团成员选自以下组别 (a) 以丙烯酸酯为末端的单体、低聚物或预聚物、 (b) 分子中含有一个以上环氧基团的环氧树脂，以及 (c) (a) 和 (b) 的混合物。 该组合物还可选择含有异氰酸酯与活性氢基反应的常规促进剂，以及环氧化物树脂的潜在固化剂和丙烯酸酯端单体、低聚物或预聚物的自由基热引发剂。 该组合物可用作粘合剂、密封剂或涂料，在助熔温度或更高的温度下加热时，由于塑化作用可获得良好的操作强度，热固化后可获得良好的结构强度。通过水分与异氰酸酯残留物的反应，可在老化过程中进一步固化。
• Reactive plastisol
  申请人：W.R. GRACE & CO.

  公开号：EP0209658A2

  公开（公告）日：1987-01-28

  This invention relates to a thermosetting plastisol dispersion composition comprising (1) poly(phenylene oxide) (PPO) in powder form, which is insoluble in the reactive plasticizer at room temperature and plasticizable at a temperature at or above the fluxing temperature; (2) a liquid reactive plasticizer member of the group consisting of (a) at least one epoxide resin having an average of more than one epoxide group in the molecule, (b) at least one liquid monomer, oligomer or prepolymer containing at least one ethylenically unsaturated group and (c) a mixture of - (a) and (b); said liquid reactive plasticizer being capable of solvating the PPO at the fluxing temperature and being present in an amount ranging from 5 to 2,000 parts per 100 parts by weight of (1); and (3) 0.01 to 10% by weight of (2) of either a thermal initiator or photoinitiator for plasticizers present in the composition. The plastisol dispersion after fluxing can form a thermoset after the crosslinking reaction.

  本发明涉及一种热固性塑料溶胶分散体组合物，其中包括 (1) 粉末状聚环氧苯(PPO)，常温下不溶于活性增塑剂，在助熔温度或更高的温度下可增塑； (2) 一种液态活性增塑剂，属于以下组别：(a) 分子中平均含有一个以上环氧基团的 至少一种环氧树脂，(b) 含有至少一个乙烯不饱和基团的至少一种液态单体、 低聚物或预聚物，(c) (a)和(b)的混合物；所述液态活性增塑剂能在助熔温度下溶解 PPO，其含量为每 100 份（重量）(1) 含 5 至 2,000 份；以及 (3) 以重量计，(2)中的热引发剂或光引发剂占组合物中增塑剂的 0.01 至 10%。 经助焊剂处理后的塑料溶胶分散体可在交联反应后形成热固性塑料。
• Uv or heat curable reinforced elastomer compositions
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0238863A2

  公开（公告）日：1987-09-30

  A radiation or heat cured elastomer is described which exhibits enhanced physical properties by virtue of its cure resulting in phase segregation.

  描述了一种辐射或热固化弹性体，这种弹性体因固化导致相分离而显示出更强的物理性能。
• Storage stable, heat curable, coating composition
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0240939A2

  公开（公告）日：1987-10-14

  This invention provides a novel storage stable, heat curable, coating composition comprising (a) a ketoxime blocked polyisocyanate, (b) a polyol containing 2-4 terminal OH groups, (c) at least one ethylenically unsaturated monomer, oligomer or prepolymer of the formula: wherein R is H or CH3, R is an organic moiety and n is 1 and preferably at least 2, (d) a free radical thermal initiator for (c), and (e) a deblocking and curing catalyst for (a). The reaction between (a) and (b) in the composition results in a thermoset material which is believed to form an interpenetrating network with the resulting thermoset from (c) on the thermal curing. The coating composition which is airless sprayable, storage stable and can be cured at low temperatures (about 80 - 120°C) provides a coating having good adhesion to metal surfaces with good abrasion resistance and good corrosion protection.

  本发明提供了一种新型贮存稳定、热固化涂层组合物，包括 (a) 酮肟封端多异氰酸酯、 (b) 含有 2-4 个末端羟基的多元醇、 (c) 至少一种式中的乙烯基不饱和单体、低聚物或预聚物： 其中 R 为 H 或 CH3，R 为有机分子，n 为 1，最好至少为 2、 (d) 用于(c)的自由基热引发剂，以及 (e) (a)的解锁和固化催化剂。 组合物中的(a)和(b)反应会产生一种热固性材料，这种材料在热固化时会与(c)产生的热固性材料形成互穿网络。 这种涂料组合物可无气喷涂，储存稳定，可在低温（约 80 - 120°C）下固化，可提供一种与金属表面有良好附着力的涂料，具有良好的耐磨性和防腐性。