Cd(1,10-phenanthroline)(NO3)2 | 68136-04-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: Cd(1,10-phenanthroline)(NO3)2
• 英文别名: Cd(phen)(NO3)2
• CAS: 68136-04-9；88425-75-6
• 化学式: C₁₂H₈CdN₄O₆
• 分子量: 416.629
• InChiKey: WPODHFDNTNNJJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cd(1,10-phenanthroline)(NO3)2 、 均苯四甲酸 以 N,N-二甲基甲酰胺 为溶剂， 以84%的产率得到[Cd2(benzene-1,2,4,5-tetracarboxylate)(1,10-phenanthroline)2]n
  参考文献：
  名称：

  Synthesis of two-dimensional metal–organic networks from 1,10-phenanthroline-chelated cadmium complex and polycarboxylate

  摘要：

  The design of two 2D metal-organic frameworks using a 1, 10-phenanthroline-chelated cadmium complex as precursor and a bridging polycarboxylate as linker is described. The reaction of Cd(NO3)(2)center dot 4H(2)O with the chelating ligand 1,10-phenanthroline (phen) at room temperature gave [Cd(phen)(NO3)(2)] (1) in high yield. Treatment of the inorganic precursor 1 with the polycarboxylate bridge ligand, benzene-1,4-dicarboxylic acid (H2BDC) or benzene-1,2,4,5-tetracarboxylic acid (H(4)btec), under mild hydrothermal conditions led to the formation of two metal-organic networks {[Cd(BDC)(phen)]-DMF}(n) (2) and [Cd-2(btec)(phen)(2)](n) (3). Single-crystal X-ray diffraction analyses showed that both products have two-dimensional sheet architectures. Compound 2 was constructed via the use of [Cd-2(O2C-)(4)] unit and BDC linker, whereas compound 3 involved the use of [CdO4] core and btec bridge. The cadmium ions in compounds 2 and 3 are hepta- and hexa-coordinated, respectively. Thermogravimetric (TG) analyses showed that 2 and 3 are thermally stable (T-decom. > 360 degrees C). Photoluminescence studies revealed that compounds 1-3 displayed a strong fluorescent emission in the solid state at room temperature. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2006.03.078
• 作为产物：
  描述：

  1,10-菲罗啉 、 cadmium(II) nitrate tetrhydrate 以 乙醇 为溶剂， 以80%的产率得到Cd(1,10-phenanthroline)(NO3)2
  参考文献：
  名称：

  Synthesis of two-dimensional metal–organic networks from 1,10-phenanthroline-chelated cadmium complex and polycarboxylate

  摘要：

  The design of two 2D metal-organic frameworks using a 1, 10-phenanthroline-chelated cadmium complex as precursor and a bridging polycarboxylate as linker is described. The reaction of Cd(NO3)(2)center dot 4H(2)O with the chelating ligand 1,10-phenanthroline (phen) at room temperature gave [Cd(phen)(NO3)(2)] (1) in high yield. Treatment of the inorganic precursor 1 with the polycarboxylate bridge ligand, benzene-1,4-dicarboxylic acid (H2BDC) or benzene-1,2,4,5-tetracarboxylic acid (H(4)btec), under mild hydrothermal conditions led to the formation of two metal-organic networks {[Cd(BDC)(phen)]-DMF}(n) (2) and [Cd-2(btec)(phen)(2)](n) (3). Single-crystal X-ray diffraction analyses showed that both products have two-dimensional sheet architectures. Compound 2 was constructed via the use of [Cd-2(O2C-)(4)] unit and BDC linker, whereas compound 3 involved the use of [CdO4] core and btec bridge. The cadmium ions in compounds 2 and 3 are hepta- and hexa-coordinated, respectively. Thermogravimetric (TG) analyses showed that 2 and 3 are thermally stable (T-decom. > 360 degrees C). Photoluminescence studies revealed that compounds 1-3 displayed a strong fluorescent emission in the solid state at room temperature. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2006.03.078