十七氟-N,N-二(2-羟基乙基)辛烷磺酰胺 | 40630-61-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: 十七氟-N,N-二(2-羟基乙基)辛烷磺酰胺
• 英文名称: heptadecafluoro-N,N-bis(2-hydroxyethyl)octanesulfonamide
• 英文别名: Heptadecafluoro-N,N-bis(2-hydroxyethyl)octanesulphonamide；1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N,N-bis(2-hydroxyethyl)octane-1-sulfonamide
• CAS: 40630-61-3
• 化学式: C₁₂H₁₀F₁₇NO₄S
• 分子量: 587.255
• InChiKey: SSTHBHCRNGPPAI-UHFFFAOYSA-N

物化性质

• 沸点：
  359.2±52.0 °C(Predicted)
• 密度：
  1.712±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  35
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.2
• 氢给体数：
  2
• 氢受体数：
  22

反应信息

• 作为反应物：
  描述：

  十七氟-N,N-二(2-羟基乙基)辛烷磺酰胺 、 全氟辛基磺酰胺 、 2-氯乙醇 、 环氧氯丙烷 、 sodium hydroxide 在 氯化钠 、 环氧氯丙烷 、 sodium hydroxide 作用下， 反应 8.0h， 生成 N,N-Bis(2-glycidoxyethyl)perfluorooctanesulfonamide
  参考文献：
  名称：

  Fluoroaliphaticsulfonamides containing oxirane groups and/or

  摘要：

  化合物包含(a)含有氟代烷基磺酰胺基团的部分，以及(b)含有(1)至少两个环氧基团、(2)至少两个非末端的N-.beta.-羟基烷基基团，或(3)至少一个环氧基团和至少一个非末端的N-.beta.-羟基烷基基团的部分。该化合物能够与固化剂一起固化，形成具有优异的耐水性和耐油性的固化产物。

  公开号：

  US04533713A1
• 作为产物：
  描述：

  全氟辛基磺酰胺 、 2-氯乙醇 在 sodium hydroxide 作用下， 以 1,4-二氧六环 为溶剂， 以85%的产率得到十七氟-N,N-二(2-羟基乙基)辛烷磺酰胺
  参考文献：
  名称：

  DE2310357

  摘要：

  公开号：

文献信息

• TONER, METHOD FOR PRODUCING THE TONER, AND IMAGE FORMING METHOD
  申请人：Yamashita Hiroshi

  公开号：US20130164669A1

  公开（公告）日：2013-06-27

  A toner including a binder resin containing an ester bond, and a releasing agent, wherein the releasing agent includes first C30-C50 alkyl monoester compound and second C30-C50 alkyl monoester compound, wherein the number of carbon atoms of the first C30-C50 alkyl monoester compound is different from that of the second C30-C50 alkyl monoester compound, wherein the amount of the first C30-C50 alkyl monoester compound is largest and the amount of the second C30-C50 alkyl monoester compound is second largest or same as the amount of the first C3OC50 alkyl monoester compound, wherein the amount of the first C30-C50 alkyl monoester compound is 30% by mass or more but less than 50% by mass to the releasing agent, and wherein the amount of the second C30-C50 alkyl monoester compound is 10% by mass or more but less than 50% by mass to the releasing agent.

  一种包括酯键的粘合剂树脂和释放剂的调色剂，其中，释放剂包括第一种C30-C50烷基单酯化合物和第二种C30-C50烷基单酯化合物，第一种C30-C50烷基单酯化合物的碳原子数与第二种C30-C50烷基单酯化合物不同，第一种C30-C50烷基单酯化合物的量最大，第二种C30-C50烷基单酯化合物的量次大或与第一种C30-C50烷基单酯化合物的量相同，第一种C30-C50烷基单酯化合物的量在释放剂中为质量的30％或更多但小于50％，第二种C30-C50烷基单酯化合物的量在释放剂中为质量的10％或更多但小于50％。
• Fluorochemical polyesters and fibrous substrates treated therewith
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0113217A2

  公开（公告）日：1984-07-11

  Fluoroaliphatic radical-containing compounds having aliphatic polyester segments useful in the form of organic solutions or aqueous dispersions in the treatment of fibrous substrates, such as textile fibers, to impart oil and water repellency.

  具有脂肪族聚酯段的含氟脂肪族自由基化合物，以有机溶液或水分散液的形式用于处理纤维基材（如纺织纤维），以赋予其防油防水性能。
• Fluoroaliphatic sulfonamides containing oxirane groups and/or N-B-hydroxyalkylene groups
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0125826A2

  公开（公告）日：1984-11-21

  This invention relates to fluoroaliphatic-sulfonamides and to epoxy compounds modified by the addition of fluoroaliphaticsulfonamido groups. Epoxy resins have been cured in many applications where their propertie, such as chemical resistance, thermal stability, durability, and insulation resistance, are advantageous. for some applications, their relatively high surface energy is a detriment. The high surface energy makes wetting of low energy, hard-to-wet surfaces difficult. This problem can lead to inferior coatings, particularly with respect to appearance and corrosion protection. Compounds containing fluorocarbon groups exhibit low surface enrgy, low oil solubility, low water solubility, low refractive index, low rate of sound transmission, and low dielectric constant. The present invention provides compounds containing (a) a fluoroaliphaticsulfonamido moiety, and (b) a moiety containing (1) at least two oxirane groups, (2) at least two non-terminal N- -hydroxyalkylene groups, or (3) at least one oxirane group and at least one non-terminal N--hydroxyalkylene group. The compound is capable of being cured to give a product having excellent water resistance and oil resistance.

  本发明涉及氟脂族磺酰胺和通过添加氟脂族磺酰胺基团改性的环氧化合物。环氧树脂已在许多应用中固化，在这些应用中，环氧树脂的耐化学性、热稳定性、耐久性和绝缘性等特性都是有利的。高表面能使低能、难润湿的表面难以润湿。这个问题会导致涂层质量下降，尤其是在外观和防腐蚀方面。含有碳氟化合物基团的化合物具有低表面能、低油溶性、低水溶性、低折射率、低声音传播率和低介电常数。本发明提供了含有(a)氟脂基磺酰胺基，和(b)含有(1)至少两个环氧乙烷基团，(2)至少两个非末端 N-羟基烷基，或(3)至少一个环氧乙烷基团和至少一个非末端 N-羟基烷基的基团的化合物。该化合物经固化后可制成具有优异耐水性和耐油性的产品。
• Release composition and photosensitive rubber plate with layer of the same
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0751433A2

  公开（公告）日：1997-01-02

  A release composition for an aqueous processible photosensitive rubber plate, which comprises 100 parts by weight of a water-soluble high-molecular weight compound such as polyvinyl alcohol and 0.5 to 7 parts by weight of an amino alcohol. An aqueous processible photosensitive rubber plate is made by laminating a layer of the release composition on a layer of a photosensitive elastomer composition usually comprising an elastomer, a photopolymerizable ethylenically unsaturated monomer, and a photopolymerization initiator.

  一种用于水溶液可加工感光橡胶板的脱模组合物，它由 100 重量份的水溶性高分子量化合物（如聚乙烯醇）和 0.5 至 7 重量份的氨基醇组成。在一层光敏弹性体组合物（通常包括弹性体、可光聚合的乙烯基不饱和单体和光聚合引发剂）上层叠一层离型组合物，就制成了水性可加工光敏橡胶板。
• Water-absorbent resin and method for production thereof
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0827753A2

  公开（公告）日：1998-03-11

  A method for the production of a water-absorbent resin capable of fast water absorption is disclosed which comprises the steps of dispersing bubbles of an inert gas in an aqueous monomer solution of a mixture of a water-soluble unsaturated monomer and a water-soluble cross-linking monomer and subjecting the mixture to copolymerization under the condition that a volume of the monomer solution wherein the inert gas is dispersed is in the range of 1.02 to 5 times of a volume of non-dispersant state.

  该方法包括以下步骤：在水溶性不饱和单体和水溶性交联单体混合物的单体水溶液中分散惰性气体气泡，并在分散惰性气体的单体水溶液体积为非分散状态体积的 1.02 至 5 倍的条件下，使混合物进行共聚。