16-[2,6-Di(propan-2-yl)phenyl]-5-[3-(3-oxo-2,4,5-triphenylcyclopenta-1,4-dien-1-yl)phenyl]-16-azahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione | 258339-64-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 16-[2,6-Di(propan-2-yl)phenyl]-5-[3-(3-oxo-2,4,5-triphenylcyclopenta-1,4-dien-1-yl)phenyl]-16-azahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione
• 英文别名: 16-[2,6-di(propan-2-yl)phenyl]-5-[3-(3-oxo-2,4,5-triphenylcyclopenta-1,4-dien-1-yl)phenyl]-16-azahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione
• CAS: 258339-64-9
• 化学式: C₆₃H₄₅NO₃
• 分子量: 864.055
• InChiKey: HJHPVXPCBMZMDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  67
• 可旋转键数：
  8
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  54.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  二苯基乙炔 、 16-[2,6-Di(propan-2-yl)phenyl]-5-[3-(3-oxo-2,4,5-triphenylcyclopenta-1,4-dien-1-yl)phenyl]-16-azahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione 以 二苯醚 为溶剂， 以85%的产率得到C₇₆H₅₅NO₂
  参考文献：
  名称：

  Fluorescence Detection from Single Dendrimers with Multiple Chromophores

  摘要：

  The differences in the fluorescence behavior of a polyphenylene dendrimer with eight peryleneimides chromophores (1) and a single hexaphenylperyleneimide chromophore have been investigated at a single-molecule level through the combination of ultrasensitive fluorescence detection and microscopy.

  DOI：

  10.1002/(sici)1521-3773(19991216)38:24<3752::aid-anie3752>3.0.co;2-y
• 作为产物：
  描述：

  N-(2,6-diisopropylphen-yl)-9-bromo-perylene-3,4-dicarboximide 在 四(三苯基膦)钯 四丁基氢氧化铵 、 碘 、 potassium carbonate 、 二甲基亚砜 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 25.0h， 生成 16-[2,6-Di(propan-2-yl)phenyl]-5-[3-(3-oxo-2,4,5-triphenylcyclopenta-1,4-dien-1-yl)phenyl]-16-azahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione
  参考文献：
  名称：

  Fluorescence Detection from Single Dendrimers with Multiple Chromophores

  摘要：

  The differences in the fluorescence behavior of a polyphenylene dendrimer with eight peryleneimides chromophores (1) and a single hexaphenylperyleneimide chromophore have been investigated at a single-molecule level through the combination of ultrasensitive fluorescence detection and microscopy.

  DOI：

  10.1002/(sici)1521-3773(19991216)38:24<3752::aid-anie3752>3.0.co;2-y

文献信息

• Fluorescence Detection from Single Dendrimers with Multiple Chromophores
  作者：Thomas Gensch、Johan Hofkens、Andreas Heirmann、Kenji Tsuda、Wendy Verheijen、Tom Vosch、Thomas Christ、Thomas Basché、Klaus Müllen、Frans C. De Schryver

  DOI：10.1002/(sici)1521-3773(19991216)38:24<3752::aid-anie3752>3.0.co;2-y

  日期：1999.12.16

  The differences in the fluorescence behavior of a polyphenylene dendrimer with eight peryleneimides chromophores (1) and a single hexaphenylperyleneimide chromophore have been investigated at a single-molecule level through the combination of ultrasensitive fluorescence detection and microscopy.