1-(3-氰基苯基)萘 | 7731-49-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-(3-氰基苯基)萘
• 英文名称: 3-(naphthalen-1-yl)benzonitrile
• 英文别名: 3-Naphthalen-1-ylbenzonitrile
• CAS: 7731-49-9
• 化学式: C₁₇H₁₁N
• 分子量: 229.281
• InChiKey: BFXNGWKZHSBQQV-UHFFFAOYSA-N

物化性质

• 沸点：
  396.5±21.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(3-氰基苯基)萘 在 氢溴酸 作用下， 生成 1-(3'-carbomethoxyphenyl)naphthalene
  参考文献：
  名称：

  Synthesis of substituted 1,8-diphenylnaphthalenes

  摘要：

  DOI：

  10.1021/jo01278a060
• 作为产物：
  描述：

  (3-chlorophenyl)magnesium bromide 生成 1-(3-氰基苯基)萘
  参考文献：
  名称：

  Photocyclization reactions of aryl polyenes. The photocychzation of 1-substitutedphenyl-4-phenyl-1,3-butadienes

  摘要：

  对1-对位取代苯基-4-苯基-1,3-丁二烯的辐照产生了1-对位取代苯基萘和7-取代-1-苯基萘的混合物。对1-间位取代苯基-4-苯基-1,3-丁二烯的光环化反应产生了1-间位取代苯基萘、6-取代-1-苯基萘和8-取代-1-苯基萘。通过独立方法合成来对光产物进行表征。

  DOI：

  10.1139/v70-304

文献信息

• 一种溴单质促进极低剂量钯催化的水相Suzuki偶联反应方法
  申请人：合肥工业大学

  公开号：CN114031475A

  公开（公告）日：2022-02-11

  本发明公开了一种溴单质促进极低剂量钯催化的水相Suzuki偶联反应方法，是以溴代芳烃和芳基硼酸为原料，纯水为溶剂，在碱、极低剂量催化剂存在下，添加溴单质即可以较高收率实现Suzuki偶联。本发明具有绿色安全、成本较低、操作简单、收率较高等优点。
• Well-defined, air- and moisture-stable palladium–imidazo[1,5-<i>a</i>]pyridin-3-ylidene complexes: a versatile catalyst platform for cross-coupling reactions by L-shaped NHC ligands
  作者：Tongliang Zhou、Pengcheng Gao、Elwira Bisz、Błażej Dziuk、Roger Lalancette、Roman Szostak、Michal Szostak

  DOI：10.1039/d2cy01136k

  日期：——

  ligands. Finally, a scalable synthesis of C5-substituted imidazo[1,5-a]pyridin-3-ylidene ligands through Ni-catalyzed Kumada cross-coupling is disclosed. The method obviates chromatographic purification at any of the steps, resulting in a facile and modular access to ImPy ligands. We anticipate that well-defined [Pd–ImPy] complexes will find broad utility in organic synthesis and catalysis for activation

  我们描述了 ImPy 的 [(NHC)Pd(cinnamyl)Cl] 配合物（ImPy = 咪唑并[1,5- a ]pyridin-3-ylidene）作为交叉偶联反应的多功能预催化剂的开发。这些预催化剂的特点是在刚性咪唑并[1,5- a ]吡啶-3-亚基模板中以 1:1 Pd 与配体的比例快速活化单配位 Pd(0)。催化剂框架催化袋中 C5 取代基和 N2 翼尖的空间匹配导致发现 ImPyMesDipp 作为高反应性咪唑并[1,5- a ]吡啶-3-亚基配体，用于 Pd 催化交叉偶联通过挑战 C-NO 2活化来生成硝基芳烃。动力学研究表明，这类结构明确的 ImPy-Pd 催化剂具有快速活化和高反应活性。结构研究提供了这类新型咪唑并[1,5- a ]吡啶-3-亚基配体的全部特征。计算研究确定了空间限制的咪唑并[1,5- a ]吡啶-3-亚基配体的电子特性。最后，公开了通过 Ni 催化的 Kumada
• 10.1016/j.tet.2024.134052
  作者：Li, Zixu、Wang, Fei、Ma, Kai、Fang, Chao、Jia, Qiang、Chu, Changhu

  DOI：10.1016/j.tet.2024.134052

  日期：——

  could be used as an alternative substrate for Suzuki cross coupling. In this manuscript, a novel ppm-Pd-Fe/C catalyst has been developed by reduction of palladium acetate and iron trichloride with aqueous hydrazine in situ and supported on activated charcoal. In combined with Sphos, and metal zinc as additives, this catalyst, with 300 ppm palladium loading, could be applied in the Suzuki cross coupling

  芳基三氟甲磺酸酯是一种容易获得的化合物，可用作 Suzuki 交叉偶联的替代底物。在这篇手稿中，通过用肼水溶液原位还原乙酸钯和三氯化铁并负载在活性炭上，开发了一种新型 ppm-Pd-Fe/C 催化剂。与 Sphos 和金属锌作为添加剂相结合，该催化剂的钯负载量为 300 ppm，可应用于芳基三氟甲磺酸酯与芳基新戊基乙二醇硼酸酯之间的 Suzuki 交叉偶联。
• Preparation of unsymmetrical biaryls via palladium-catalyzed coupling reaction of aryl halides
  作者：Jwanro Hassan、Chokri Hathroubi、Christel Gozzi、Marc Lemaire

  DOI：10.1016/s0040-4020(01)00752-9

  日期：2001.9

  The synthesis of unsymmetrical biaryls is achieved using Pd(OAc)(2) as the catalyst. A great variety of aryl halides having electron withdrawing and electron donating functional groups in para, meta and ortho positions have been successfully coupled. (C) 2001 Elsevier Science Ltd. All rights reserved.
• PYRENE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DIODE COMPRISING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20140183468A1

  公开（公告）日：2014-07-03

  A pyrene-based compound and an organic light-emitting diode including the pyrene-based compound are provided. The pyrene-based compound of Formula 1 above may emit blue light having high color purity. For example, an organic light-emitting diode including the pyrene-based compounds of the invention may emit blue light having a y coordinate with a color purity of 0.1 or less, for example, a color purity of 0.09 or less, which is near to the NTSC or sRGB specification. A thin film including the pyrene-based compounds of the invention may be highly amorphous, and thus may have improved electrical stability. Accordingly, an organic light-emitting diode including the pyrene-based compounds of the invention may have improved lifetime characteristics.