9-isopropylxanthenol | 101169-00-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 9-isopropylxanthenol
• 英文别名: 9-isopropyl-xanthen-9-ol；9-Propan-2-ylxanthen-9-ol
• CAS: 101169-00-0
• 化学式: C₁₆H₁₆O₂
• 分子量: 240.302
• InChiKey: UKGWZGGCNIITJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-isopropylxanthenol 在 正丁基锂 、 四甲基乙二胺 、 对甲苯磺酸 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 34.0h， 生成
  参考文献：
  名称：

  Microwave-assisted oxidation reaction of primary alcohols with sensitive functional groups to aldehydes using ruthenium diphosphorus complexes

  摘要：

  DOI：

  10.24820/ark.5550190.p011.197
• 作为产物：
  描述：

  占吨-9-甲酸甲酯 在 硫酸 作用下， 生成 9-isopropylxanthenol
  参考文献：
  名称：

  Rigaudy; Kha-Vang-Thang, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959, vol. 249, p. 1008

  摘要：

  DOI：

文献信息

• Syntheses of 9-cyclohepta-2,4,6-trien-1-yl-9H-xanthen-9-ol and related alcohols by a novel umpolung method
  作者：Ibraheem T. Badejo、Rafik Karaman、Nga Wing Irene Lee、Eric C. Lutz、Maria T. Mamanta、James L. Fry

  DOI：10.1039/c39890000566

  日期：——

  Several 9-alkyl derivatives of xanthen-9-ol have been synthesized by a novel umpolung method involving reactions of the dianion of xanthen-9-one with alkyl halides.

  黄嘌呤-9-醇的几种9-烷基衍生物已经通过新颖的化学合成方法合成，该方法涉及黄嘌呤-9-的二价阴离子与卤代烷的反应。
• Dissociation of 1,4-bis (4-phenoxybenzoyl)benzene—Lewis acid complex in a protic solvent
  申请人：Arkema France

  公开号：US10793500B2

  公开（公告）日：2020-10-06

  A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: reacting terephthaloyl chloride with diphenyl ether in the presence of a Lewis acid, so as to obtain a product mixture including 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex, wherein the 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex is, at least partly, in the form of a precipitate; carrying out a solid/liquid separation of the product mixture to obtain a cake comprising the 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex precipitate; putting the cake in contact with a decomplexing solvent, wherein the decomplexing solvent is a protic solvent, so as to dissociate the 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex into 1,4-bis(4-phenoxybenzoyl)benzene; and, recovering the 1,4-bis(4-phenoxybenzoyl)benzene. Also, a method for manufacturing a polyaryletherketone polymer starting from 1,4-bis(4-phenoxybenzoyl)benzene manufactured by the above method.

  一种制造 1,4-双(4-苯氧基苯甲酰基)苯的方法，包括在路易斯酸存在下，使对苯二甲酰氯与二苯醚反应，从而得到包括 1,4-双(4-苯氧基苯甲酰基)苯-路易斯酸络合物的产品混合物，其中 1,4-双(4-苯氧基苯甲酰基)苯-路易斯酸络合物至少部分以沉淀形式存在；对产品混合物进行固/液分离，得到含有 1,4-双（4-苯氧基苯甲酰基）苯-刘易斯酸络合物沉淀的滤饼；将滤饼与解络合溶剂接触，其中解络合溶剂为质子溶剂，从而将 1,4-双(4-苯氧基苯甲酰基)苯-刘易斯酸络合物解离成 1,4-双(4-苯氧基苯甲酰基)苯；以及，回收 1,4-双(4-苯氧基苯甲酰基)苯。此外，一种以上述方法制得的 1,4-双（4-苯氧基苯甲酰基）苯为原料生产聚芳醚酮聚合物的方法。
• Conant; Small; Sloan, Journal of the American Chemical Society, 1926, vol. 48, p. 1748
  作者：Conant、Small、Sloan

  DOI：——

  日期：——
• Carbonium Ions. VIII. Diarylolefin-Diarylalkyl Cation Equilibria¹
  作者：N. C. Deno、Paul T. Groves、George Saines

  DOI：10.1021/ja01530a059

  日期：1959.11
• FORMING CATALYTIC SITES FROM REDUCIBLE SILVER-HETEROCYCLIC COMPLEXES
  申请人：Shukla Deepak

  公开号：US20160167037A1

  公开（公告）日：2016-06-16

  A non-aqueous metal catalytic composition includes (a) a complex of silver and a hindered aromatic N-heterocycle comprising reducible silver ions in an amount of at least 2 weight %, (b) a silver ion photoreducing composition in an amount of at least 1 weight %, and (c) a photocurable component, a non-curable polymer, or a combination of a photocurable component and a non-curable polymer. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.