Iron(III) isopropoxide

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Iron(III) isopropoxide
• 英文别名: ferric isopropoxide；Fe(O(i)C3H7)3
• 化学式: C₉H₂₁FeO₃
• 分子量: 233.111
• InChiKey: SQNLZMPKTJBINR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.25
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.06
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Iron(III) isopropoxide 、 aluminum isopropoxide 以 苯 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Shah, A.; Gupta, R.; Singh, A., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1991, vol. 21, p. 609 - 622

  摘要：

  DOI：
• 作为产物：
  描述：

  sodium isopropylate 、 三氯化铁 以 正己烷 、 异丙醇 为溶剂， 生成 Iron(III) isopropoxide
  参考文献：
  名称：

  Turova, N. Ya.; Rogova, T. V.; Kozlova, N. I., Koordinatsionnaya Khimiya, 1983, vol. 9, p. 708 - 715

  摘要：

  DOI：
• 作为试剂：
  描述：

  3-苯基-2-丙炔-1-醇 、 4-苯基丁酸 在 zirconium(IV) tetraisopropoxide Iron(III) isopropoxide 作用下， 以 正庚烷 为溶剂， 反应 19.0h， 以99%的产率得到phenylpropargyl 4-phenylbutyrate
  参考文献：
  名称：

  Zr（IV）Fe（III），Ga（III）和Sn（IV）二元金属配合物作为增效和可重复使用的酯化催化剂

  摘要：

  结合使用Hf（O- i- Pr）4或Zr（O- i- Pr）4和Fe（O- i- Pr）3进行直接酯化的催化活性和一种非常简单的提取方法描述了用于回收和再利用的离子液体。这种Zr（IV）Fe（III）络合物具有高周转率，极弱的路易斯酸度，低毒性，可重复使用性以及低成本的商业可用性，因此对环境无害。

  DOI：

  10.1002/adsc.200505083

文献信息

• TAP study on carbon monoxide oxidation over supported gold catalysts Au/Ti(OH)∗4 and Au/Fe(OH)3: Moisture effect
  作者：M OLEA、M TADA、Y IWASAWA

  DOI：10.1016/j.jcat.2007.03.004

  日期：2007.5.15

  The effect of moisture on the behavior of the active supported gold catalysts developed by us, Au/Ti(OH)(4)* (1) and Au/Fe(OH)(3)* (II), during CO activation and CO oxidation in the temperature range 298-473 K was investigated by the temporal analysis of products (TAP) technique. The oxidation reaction over the Au/Ti(OH)(4)* catalyst was totally suppressed by the presence of water, independent of the water content of 200 and 1000 ppm, the carbon monoxide-to-oxygen ratio, and the temperature. In contrast, the presence of water vapors showed no effect on CO oxidation over the Au/Fe(OH)* catalyst. For both catalysts, the carbon monoxide adsorption feature was unalterable by the presence of water, namely CO molecules reversibly adsorbed on the catalyst surface, but the amount of CO adsorbed decreased by increasing water content. When a reaction mixture at a 1:1 ratio of CO to O-2 was pulsed on the catalyst in the absence of water, the CO response curve showed two peaks, whereas in the presence of water, the TAP response curve showed only one peak. At a 1:3 CO-to-O-2 ratio, the CO response curve showed only one peak, which shifted to a shorter time and narrowed in the absence of water. The shift was more pronounced on catalyst (II). The TAP experiments provided indirect evidence that CO and water adsorbed together (CO weakly and water strongly) and water blocked [irreversibly for Au/Ti(OH)(4)* and reversibly for Au/Fe(OH)(3)*], the adsorption sites for oxygen. (C) 2007 Elsevier Inc. All rights reserved.
• Shah, A.; Singh, A.; Mehrotra, R. C., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1987, vol. 26, # 6, p. 485 - 488
  作者：Shah, A.、Singh, A.、Mehrotra, R. C.

  DOI：——

  日期：——
• Lu, Chung-Hsin; Shinozaki, Kazuo; Mizutani, Nobuyasu, Journal of the American Ceramic Society, 1992, vol. 75, p. 1303 - 1306
  作者：Lu, Chung-Hsin、Shinozaki, Kazuo、Mizutani, Nobuyasu

  DOI：——

  日期：——
• Yanovskaya, M. I.; Rogova, T. V.; Ivanov, S. A., Inorganic Materials, <hi>1987</hi>, vol. 23, p. 1188 - 1192
  作者：Yanovskaya, M. I.、Rogova, T. V.、Ivanov, S. A.、Kolganova, N. V.、Turova, N. Ya.

  DOI：——

  日期：——
• Shah, A.; Gupta, R.; Singh, A., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1991, vol. 21, p. 609 - 622
  作者：Shah, A.、Gupta, R.、Singh, A.、Mehrotra, R. C.

  DOI：——

  日期：——