D131 | 652145-29-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: D131
• 英文别名: 3-{1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylvinyl)phenyl]cyclopenta[b]indole-7-yl}-2-cyanoacrylic acid；2-cyano-3-{4-[4-(2,2-diphenylethenyl)phenyl]-1H,2H,3H,3aH,8bH-cyclopenta[b]indol-7-yl}prop-2-enoic acid；2-cyano-3-[4-[4-(2,2-diphenylethenyl)phenyl]-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]indol-7-yl]prop-2-enoic acid
• CAS: 652145-29-4
• 化学式: C₃₅H₂₈N₂O₂
• 分子量: 508.62
• InChiKey: GOTRYMLNXIJMCB-UHFFFAOYSA-N

物化性质

• 沸点：
  690.6±55.0 °C(Predicted)
• 密度：
  1.262±0.06 g/cm3(Predicted)
• 最大波长(λmax)：
  464nm(CHCl3)(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  64.3
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-丙烷磺内酯 、 D131 、 三乙胺 以 乙腈 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  [EN] METHINE DYES WITH LARGE ORGANIC COUNTER ANION FOR DYE SENSITIZED SOLAR CELLS
  [FR] COLORANTS À BASE DE MÉTHINE COMPRENANT UN CONTRE-ANION ORGANIQUE DE GRANDE TAILLE POUR CELLULES SOLAIRES À PIGMENT PHOTOSENSIBLE

  摘要：

  本发明涉及一种电极层，该电极层包括由氧化物半导体细颗粒制成的多孔薄膜，该薄膜被一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的反离子敏化的偏亚甲基染料。此外，本发明涉及一种包括所述电极层的光电转换装置，一种包括所述光电转换装置的染料敏化太阳能电池，一种包括所述光电转换装置的有机电子器件，以及一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的新型偏亚甲基染料。

  公开号：

  WO2015011638A1
• 作为产物：
  描述：

  1,2,3,3a,4,8b-hexahydro-4-[4-(2,2-diphenylethenyl)phenyl]cyclopent[b]indole 在 哌啶 、 三氯氧磷 作用下， 以 乙腈 为溶剂， 生成 D131
  参考文献：
  名称：

  Comparison of performance between benzoindoline and indoline dyes in zinc oxide dye-sensitized solar cell

  摘要：

  The cell performance of novel benzoindoline dyes on zinc oxide prepared by template cathode electro-deposition method was compared with that of known indoline dyes. Among cyanoacrylic, single and double rhodanine acetic acid derivatives, the cyanoacrylic benzoindoline dye showed better performance than the indoline dye (D131) due to larger J(sc) value which comes from its positive E., level and bathochromic UV-vis absorption band. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.02.009

文献信息

• [EN] METHINE DYES WITH LARGE ORGANIC COUNTER ANION FOR DYE SENSITIZED SOLAR CELLS<br/>[FR] COLORANTS À BASE DE MÉTHINE COMPRENANT UN CONTRE-ANION ORGANIQUE DE GRANDE TAILLE POUR CELLULES SOLAIRES À PIGMENT PHOTOSENSIBLE
  申请人：BASF SE

  公开号：WO2015011638A1

  公开（公告）日：2015-01-29

  The present invention relates to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with a methine dye having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm. Moreover the present invention relates to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device, an organic electronic device comprising said photoelectric conversion device and to novel methine dyes having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm.

  本发明涉及一种电极层，该电极层包括由氧化物半导体细颗粒制成的多孔薄膜，该薄膜被一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的反离子敏化的偏亚甲基染料。此外，本发明涉及一种包括所述电极层的光电转换装置，一种包括所述光电转换装置的染料敏化太阳能电池，一种包括所述光电转换装置的有机电子器件，以及一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的新型偏亚甲基染料。
• Comparison of performance between benzoindoline and indoline dyes in zinc oxide dye-sensitized solar cell
  作者：Masaki Matsui、Masaya Kotani、Yasuhiro Kubota、Kazumasa Funabiki、Jiye Jin、Tsukasa Yoshida、Shinji Higashijima、Hidetoshi Miura

  DOI：10.1016/j.dyepig.2011.02.009

  日期：2011.11

  The cell performance of novel benzoindoline dyes on zinc oxide prepared by template cathode electro-deposition method was compared with that of known indoline dyes. Among cyanoacrylic, single and double rhodanine acetic acid derivatives, the cyanoacrylic benzoindoline dye showed better performance than the indoline dye (D131) due to larger J(sc) value which comes from its positive E., level and bathochromic UV-vis absorption band. (C) 2011 Elsevier Ltd. All rights reserved.