N,N'-bis(5-nitrosalicylidene)-1,3-propanediamine | 98178-15-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N,N'-bis(5-nitrosalicylidene)-1,3-propanediamine
• 英文别名: 2-OH-5-O2NC6H3CHNCH2CH2CH2NCHC6H3-2-OH-5-NO2；2-[3-[(2-Hydroxy-5-nitrophenyl)methylideneamino]propyliminomethyl]-4-nitrophenol
• CAS: 98178-15-5
• 化学式: C₁₇H₁₆N₄O₆
• 分子量: 372.337
• InChiKey: AHMDBYWREAVCIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  157
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N,N'-bis(5-nitrosalicylidene)-1,3-propanediamine 生成
  参考文献：
  名称：

  Watkinson, Michael; Fondo, Matilde; Bermejo, Manuel R., Journal of the Chemical Society, Dalton Transactions, 1999, # 1, p. 31 - 42

  摘要：

  DOI：
• 作为产物：
  描述：

  5-硝基水杨醛 、 1,3-丙二胺 以 乙醇 为溶剂， 反应 0.5h， 生成 N,N'-bis(5-nitrosalicylidene)-1,3-propanediamine
  参考文献：
  名称：

  铱（I）同核复合物包含salen型配体作为桥

  摘要：

  摘要由四齿席夫碱配体[N，N'-亚乙基双（5-R）反应生成的具有通式[Ir2（η4-cod）2（μ-SB）]（1-12）的新双核铱（I）配合物-（水杨酰亚胺）（5,5'-R-salenH2），[N，N'-1,3-丙二双（5-R-水杨酰亚胺）（5,5'-R-salpenH2）和[N，N合成了带有[Ir（cod）（μ-Cl）] 2的'-邻苯撑双（5-R-水杨酰亚胺）（5,5'-R-salphenH2）（R = H，MeO，Cl，NO2）。该铱络合物的同核性质通过元素分析，FAB-Mass和1H NMR光谱得到证实。通过红外光谱，13 C NMR和二维NMR实验（COSY，HSQC，HMBC和NOESY）完成了全部表征。此外，铱配合物[（Ir（η4-cod）2（μ-5,5'-MeO-salen）]（2）用X射线晶体学表征，表明乙烯桥是s-trans构象，Schiff碱配体起着向两个铱原子桥接的N，O-双齿配体的作用，而1

  DOI：

  10.1016/j.poly.2019.01.022

文献信息

• Mechanochemical Reaction of Polymeric Oxovanadium(IV) Complexes with Schiff Base Ligands Derived from 5-Nitrosalicylaldehyde and Diamines
  作者：Masanobu Tsuchimoto、Gakuse Hoshina、Naoki Yoshioka、Hidenari Inoue、Kiyohiko Nakajima、Mayumi Kamishima、Masaaki Kojima、Shigeru Ohba

  DOI：10.1006/jssc.2000.8710

  日期：2000.8

  N′-di-5-nitrosalicylidene-1,2-ethanediamine) and orange [VO(5-NO2sal-meso-stien)]·0.5H2O (2; H2(5-NO2sal-meso-stien)=N,N′-di-5-nitrosalicylidene-(R,S)(S,R)-1,2-diphenyl-1,2-ethanediamine) which have linear chain structures in the solid state turn dark brown and yellow-brown, respectively, when ground thoroughly in mortars. The IR spectra of 1 and 2 in Nujol mulls show strong V=O stretching bands at 875 and 905 cm−1

  浅棕色[VO（5-NO 2萨伦）]·2H 2 O（1; H 2（5-NO 2萨伦）= N，N'-二-5-硝基水杨亚基-1,2-乙二胺）和橙色[VO （5-NO 2 sal-内消旋-stien）]·0.5H 2 O（2; H 2（5-NO 2 sal-内消旋-stien）= ñ，ñ ' -二-5- nitrosalicylidene-（[R ，小号） （S，R当在研钵中彻底研磨时，呈固态直链结构的）-1,2-二苯基-1,2-乙二胺）分别变成深棕色和黄棕色。Nujol鸥的1和2的IR光谱分别在875和905 cm -1处显示出强大的V = O拉伸带。另一方面，Nujol细粉中精细研磨的复合物的光谱显示出非常弱的V = O拉伸带。地面配合物的X射线粉末衍射图谱几乎没有显示出衍射峰。光谱和磁数据表明，研磨后破坏了1和2晶体中的线性链结构，产生了聚合物链的片段。
• Synthesis and characterization of nitro-Schiff bases derived from 5-nitro-salicylaldehyde and various diamines and their complexes of Co(II)
  作者：Hossein Naeimi、Mohsen Moradian

  DOI：10.1080/00958970903225866

  日期：2010.1.10

  Some neutral tetradentate N2O2 type complexes of Co(II) have been synthesized using Schiff bases formed by condensation of 5-nitro-salicylaldehyde with various diamines in alcohol. The nature of the ligands and complexes was established by spectroscopic techniques. The Schiff bases are bivalent anions with tetradentate ONNO donors derived from phenolic oxygen and azomethine nitrogen. IR and UV-Vis spectral data suggest that all the complexes are square-planar.
• Gallium(III) complexes based on N,N′-bis(salicylidene)propane-1,3-diamine and its derivatives
  作者：Sotiria Tella、Vlasoula Bekiari、Vadim G. Kessler、Giannis S. Papaefstathiou

  DOI：10.1016/j.poly.2013.02.057

  日期：2013.11

  The reactions of N,N'-bis(salicylidene)propane-1,3-diamine (salpropH(2)) and its substituted derivatives with Ga(acac)(3) afforded the complexes [Ga(acac)(salprop)]center dot 0.5H(2)O (1), [Ga(acac)(5Clsalprop)] (2), [Ga(acac)(5Brsalprop)] (3), [Ga(acac)(5NO(2)salprop)] (4) and [Ga(acac)(5Mesalprop)] (5), in high yields. The crystal structures of all complexes have been determined by single-crystal X-ray crystallography. All complexes are mononuclear with the Ga(III) atoms being in octahedral environments surrounded by one tetradentate chelate 5Rsalprop(2-) ligand and one bidentate chelate acac(-) ligand. The free ligands exhibit photoluminescence which was found to be increased upon complex formation. The substituted derivatives of the salpropH(2) ligand bearing either electron-donating methyl groups or electron-withdrawing groups, such as Cl, Br and NO2 at the fifth position of both salicylidene rings were found to modify the emission maximum of the free ligands and the complexes. (C) 2013 Elsevier Ltd. All rights reserved.
• Synthesis and structural characterisation of new manganese(II) and (III) complexes. Study of their photolytic and catalase activity and X-ray crystal structure of [Mn(3-OMe, 5-Br-salpn)(EtOH)(H2O)]ClO4
  作者：M Maneiro、M.R Bermejo、A Sousa、M Fondo、A.M González、A Sousa-Pedrares、Charles A McAuliffe

  DOI：10.1016/s0277-5387(99)00321-6

  日期：2000.1

  New [(MnL)-L-II(H2O)(2)] and [(MnL)-L-III(H2O)(2)]ClO4 complexes, where L are substituted N,N'-bis(salicylidene)propane-1,3-diamine (H(2)salpn) ligands have been prepared and thoroughly characterised by elemental analysis, IR and mass spectroscopy, conductivity and magnetic measurements at room temperature (and, in the case of 1, at variable temperature). Cyclic and normal pulse voltammetry measurements were also performed. All these studies support an octahedral geometry around the metal with the Schiff base in the equatorial plane acting as tetradentate and solvent molecules in the axial positions. Crystallographic characterisation of 6 confirms this geometry and shows a supramolecular structure involving pi-pi stacking and hydrogen bonding interactions. The ability to split water by these complexes and their catalase activity has also been studied. (C) 2000 Elsevier Science Ltd All rights reserved.
• Watkinson, Michael; Fondo, Matilde; Bermejo, Manuel R., Journal of the Chemical Society, Dalton Transactions, 1999, # 1, p. 31 - 42
  作者：Watkinson, Michael、Fondo, Matilde、Bermejo, Manuel R.、Sousa, Antonio、McAuliffe, Charles A.、et al.

  DOI：——

  日期：——