cyclo[2,6-bis(naphthalene diethylphosphoramidite)] | 847556-67-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: cyclo[2,6-bis(naphthalene diethylphosphoramidite)]
• 英文别名: 6-N,6-N,17-N,17-N-tetraethyl-5,7,16,18-tetraoxa-6,17-diphosphapentacyclo[17.3.1.14,22.18,12.111,15]hexacosa-1(22),2,4(24),8(26),9,11,13,15(25),19(23),20-decaene-6,17-diamine
• CAS: 847556-67-6
• 化学式: C₂₈H₃₂N₂O₄P₂
• 分子量: 522.521
• InChiKey: OLCPKLUAAZARGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.36
• 重原子数：
  36.0
• 可旋转键数：
  6.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  43.4
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  cyclo[2,6-bis(naphthalene diethylphosphoramidite)] 在 双氧水 、 尿素 作用下， 以 二氯甲烷 为溶剂， 以94%的产率得到6-N,6-N,17-N,17-N-tetraethyl-6,17-dioxo-5,7,16,18-tetraoxa-6λ5,17λ5-diphosphapentacyclo[17.3.1.14,22.18,12.111,15]hexacosa-1(22),2,4(24),8(26),9,11,13,15(25),19(23),20-decaene-6,17-diamine
  参考文献：
  名称：

  2,6- and 1,6-Dihydroxynaphthalenes in the Synthesis of Phosphacyclophanes

  摘要：

  Peculiar phosphacyclophanes were prepared from symmetrical 2,6- and unsymmetrical 1,6-dihydroxynaphthalenes. The position of the hydroxy groups in dihydroxynaphthalenes considerably affects their reactivity, the structure of the phosphacyclophanes obtained, and also the disproportionation of bisphosphoramidites. Oxo and thio derivatives of these phosphoramidites as well as their molybdenum complexes were prepared.

  DOI：

  10.1023/b:rugc.0000045868.37162.87
• 作为产物：
  描述：

  bis(2,6-tetraethyldiamidophosphito)naphthalene 以 二氯甲烷 为溶剂， 反应 528.0h， 生成 cyclo[2,6-bis(naphthalene diethylphosphoramidite)] 、 六乙基亚磷酸胺
  参考文献：
  名称：

  Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

  摘要：

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.

  DOI：

  10.1134/s1070363206020046

文献信息

• Rhodium(I) carbonyl complexes based on naphthophosphacyclophanes
  作者：P. V. Slitikov、V. S. Boldyrev、Yu. B. Evdokimenkova

  DOI：10.1007/s11172-017-1831-7

  日期：2017.5

  Naphthphosphacyclophanes based on symmetrical dihydroxynaphthalenes linked by diethylamidophospite groups were used to synthesize rhodium(I) complexes containing carb-onyl and acetylacetonato fragments. The physicochemical and spectral characteristics of the synthesized coordination systems were studied.

  基于由二乙基酰胺基亚磷酸酯基团连接的对称二羟基萘的萘并磷杂环芳被用于合成含有羰基和乙酰丙酮基片段的铑 (I) 配合物。研究了合成配位体系的理化和光谱特性。