4-(N,N-diphenylamino)-biphenyl-N'-naphthylamine | 902763-20-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(N,N-diphenylamino)-biphenyl-N'-naphthylamine
• 英文别名: 4-(N,N-diphenylamino)-biphenyl-N'-1-naphthylamine；N-[4-[4-(N-phenylanilino)phenyl]phenyl]naphthalen-1-amine
• CAS: 902763-20-6
• 化学式: C₃₄H₂₆N₂
• 分子量: 462.594
• InChiKey: HWWHBPWWCGGASO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4'-氯-N,N-二苯基联苯-4-胺 、 1-萘胺 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以61%的产率得到4-(N,N-diphenylamino)-biphenyl-N'-naphthylamine
  参考文献：
  名称：

  COMPOUNDS AND ORGANIC LIGHT EMITTING DIODE USING THE SAME

  摘要：

  本发明公开了新化合物及其所使用的有机发光二极管。根据本发明所使用的新化合物的有机发光二极管在驱动电压、光效率和寿命方面表现出优异的特性。

  公开号：

  US20100065827A1

文献信息

• Use of Rylene Derivatives as Photosensitizers in Solar Cells
  申请人：Pschirer Neil Gregory

  公开号：US20080269482A1

  公开（公告）日：2008-10-30

  Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR 1 R 2 (y1) -L-Z-R 3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR 1 R 2 ; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO 3 M; —PO 3 M 2 ; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR 5 ] 4 + ; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R 1 , R 2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R 3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R 5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.

  使用以下变量定义的莱伦衍生物I的用途： X一起 两者都是-COOM; Y是一个基团 -L-NR 1 R 2 (y1) -L-Z-R 3 (y2) 另一个基团是氢; 一起 两者都是氢; R可选择地被取代为(het)芳氧基，(het)芳基硫基; P是-NR 1 R 2 ; B是烷基; 可选择地被取代的苯基; 它们的组合; A是-COOM; -SO 3 M; -PO 3 M 2 ; D可选择地被取代为苯基，萘基，吡啶基; M是氢; 碱金属阳离子; [NR 5 ] 4 + ; L是化学键; 可选择地间接键合，可选择地被取代的(het)芳基基团; R 1 ，R 2 可选择地被取代的(环)烷基，(het)芳基; 一起可选择地被取代的环，其中包括氮原子; Z是-O-; -S-; R 3 可选择地被取代的烷基，(het)芳基; R′是氢; 可选择地被取代的(环)烷基，(het)芳基; R 5 是氢; 可选择地被取代的烷基(het)芳基; m为0, 1, 2; n, p, m=0: 0, 2, 4其中：n+p=2, 4，如果适用为0; m=1: 0, 2, 4其中：n+p=0, 2, 4; m=2: 0, 4, 6其中：n+p=0, 4, 6， 或者作为太阳能电池中的光敏剂的混合物。
• Arylamine compound and synthetic method thereof
  申请人：Nakashima Harue

  公开号：US20070037011A1

  公开（公告）日：2007-02-15

  It is an object of the present invention to provide an arylamine compound which has resistance to repeated oxidation reactions. The present invention provides a secondary arylamine compound represented by General Formula 1. (In the formula, Ar 11 is an aryl group having 7 to 25 carbon atoms or a heteroaryl group having 7 to 25 carbon atoms. Ar 12 and Ar 13 may be identical or different, and are individually either an aryl group having 6 to 25 carbon atoms or a heteroaryl group having 5 to 9 carbon atoms. X is either a bivalent aromatic hydrocarbon group having 6 to 25 carbon atoms or a bivalent heterocyclic group having 5 to 10 carbon atoms.)

  本发明的目的是提供一种具有抗重复氧化反应的芳基胺化合物。本发明提供了由通式1表示的二级芳基胺化合物。(在公式中，Ar11是具有7至25个碳原子的芳基基团或具有7至25个碳原子的杂环基团。Ar12和Ar13可以相同也可以不同，分别是具有6至25个碳原子的芳基基团或具有5至9个碳原子的杂环基团。X是具有6至25个碳原子的双价芳香烃基团或具有5至10个碳原子的双价杂环基团。)
• VERWENDUNG VON RYLENDERIVATEN ALS PHOTOSENSIBILISATOREN IN SOLARZELLEN
  申请人：BASF SE

  公开号：EP1951842A1

  公开（公告）日：2008-08-06
• USE OF RYLENE DERIVATIVES AS PHOTOSENSITIZERS IN SOLAR CELLS
  申请人：PSCHIRER Neil Gregory

  公开号：US20120283432A1

  公开（公告）日：2012-11-08

  Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR 1 R 2 (y1) -L-Z—R 3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR 1 R 2 ; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO 3 M; —PO 3 M 2 ; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR 5 ] 4 + ; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R 1 , R 2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R 3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R 5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
• US8231809B2
  申请人：——

  公开号：US8231809B2

  公开（公告）日：2012-07-31