4-methyl-2,6-bis(2-chlorophenyliminomethylene)-phenol | 135713-66-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-methyl-2,6-bis(2-chlorophenyliminomethylene)-phenol
• 英文别名: 2,6-Bis[(2-chlorophenyl)iminomethyl]-4-methylphenol
• CAS: 135713-66-5
• 化学式: C₂₁H₁₆Cl₂N₂O
• 分子量: 383.277
• InChiKey: UNIIEFGLFWNACO-UHFFFAOYSA-N

物化性质

• 沸点：
  596.8±50.0 °C(Predicted)
• 密度：
  1.23±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  45
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-methyl-2,6-bis(2-chlorophenyliminomethylene)-phenol 、 三甲基镓 以 苯 为溶剂， 以75%的产率得到dimethyl[4-methyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato] gallium
  参考文献：
  名称：

  Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium

  摘要：

  Eight new dimethylgallium complexes bearing 4-alkyl-2.6-bis(aryliminomethlene))-phenol ligands of type Me2GaL (L = 4-methyl-2, 6-bis-(phenyliminomethylene)-phenolato (3); L = 4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phejiolato (4); L = 4-methyl-2,6-bis-(1-naphthyliminomethylene)- phenolato (5); L = 4-methyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato (6); 4-tert-butyl-2,6-bis(phenyliminomethylene)-phenolato (7); L = 4-tert-butyl-2.6-bis-)-methylphenyliminomethylene)-phenolato (8); L = 4-tert-butyl-2,6bis-(1-naphthyliminomethylene)-phenolato (9); and L = 4-tert-butyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato](3) have been synthesized by the reaction of trimethylgallium with appropriate phenol. The complexes obtained have been characterized by elemental analysis, 'H NMR, IR and mass spectroscopy, respectively. The solid-state structures of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium (4) have been determined by X-ray single crystal analysis. In the structure, Ga atom is coordinated by one nitrogen atom and the other nitrogen atom remains constant. The distorted tetrahedron geometry around gallium is presented. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.11.048

文献信息

• Catalytic and magnetic properties of a new series of binuclear copper(II) complexes
  作者：B. Srinivas、N. Arulsamy、P.S. Zacharias

  DOI：10.1016/s0277-5387(00)83761-4

  日期：1991.1

  Cu2LCl3 complexes are chloro-bridged, as evidenced by two intense IR bands centred around 300 and 320 cm−1. Magnetic susceptibility measurements show that Cu2LCl3 complexes have low μefff values indicating magnetically interacting copper(II) centres and Cu2L′Cl2 complexes have non-interacting copper(II) centres. Cu2LCl3 complexes undergo single-step quasi-reversible reduction at - 0.62 V vs SCE. Catalysis

  已经合成了由2，6-二甲酰基-4-甲基苯酚与各种芳族单胺和二胺缩合得到的配体的双核铜（II）配合物。衍生自单胺的配合物具有Cu 2 LCl 3组成，衍生自二胺的配合物具有Cu 2 L'Cl 2组成，其中L和L'代表配体。分析数据，电导和光谱研究支持了这些公式。Cu 2 LCl 3络合物是氯桥联的，如两个以300和320 cm -1为中心的强烈IR波段所证明的。磁化率测量结果表明，铜2 LCL 3配合物具有低μ EFFf值表示磁性相互作用的铜（II）中心和Cu 2 L'Cl 2络合物具有不相互作用的铜（II）中心。与SCE相比，Cu 2 LCl 3络合物在-0.62 V时经历了单步准可逆还原。研究了Cu 2 LCl 3配合物催化双氧氧化3,5-二叔丁基邻苯二酚（3,5-DTBC）和抗坏血酸的方法。
• Shetti, Ullas N.; Revankar, Vidyanand K.; Mahale, Vinayak B., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1998, vol. 37, # 6, p. 540 - 543
  作者：Shetti, Ullas N.、Revankar, Vidyanand K.、Mahale, Vinayak B.

  DOI：——

  日期：——
• Shetti, Ullas N.; Revankar, Vidyanand K.; Mahale, Vinayak B., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1998, vol. 37, # 4, p. 361 - 363
  作者：Shetti, Ullas N.、Revankar, Vidyanand K.、Mahale, Vinayak B.

  DOI：——

  日期：——