1,2-dilithio-1,1,2,2-tetrakis(tert-butyldimethylsilyl)disilane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-dilithio-1,1,2,2-tetrakis(tert-butyldimethylsilyl)disilane
• 英文别名: 1,2-dilithiotetrakis(tert-butyldimethylsilyl)disilane；tetrakis(tert-butyldimethylsilyl)dilithiodisilane
• 化学式: C₂₄H₆₀Li₂Si₆
• 分子量: 531.135
• InChiKey: WGYHWXBCQPIKBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.64
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-dilithio-1,1,2,2-tetrakis(tert-butyldimethylsilyl)disilane 、 金刚烷酮 在 lithium (tert-butyl)dimethylsilanolate 作用下， 以 苯 为溶剂， 以70.1%的产率得到1,3-disilabicyclo[1.1.0]butane
  参考文献：
  名称：

  具有长桥硅-硅键的第一个1,3-二硅双环[1.1.0]丁烷。

  摘要：

  DOI：

  10.1021/ja011658v

文献信息

• Comparison of structures between platinum and palladium complexes of a tetrasilyldisilene
  作者：Hisako Hashimoto、Yumiko Sekiguchi、Yohei Sekiguchi、Takeaki Iwamoto、Chizuko Kabuto、Mistuo Kira

  DOI：10.1139/v03-108

  日期：2003.11.1

  The first η2-disilene–palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine)dichloropalladiums with a 1,2-dilithiotetrakis(trialkylsilyl)disilane, which was prepared by the reaction of a stable tetrakis(trialkylsilyl)disilene with lithium (Method A) and the direct reactions of the bis(phosphine)dichloropalladiums with the stable disilene (Method B). Comparison

  第一个 η2-二硅烯 ??钯配合物是使用两种不同的反应合成的；双（膦）二氯钯与 1,2-二硫代四（三烷基甲硅烷基）乙硅烷的反应二氯钯与稳定的二硅烯（方法 B）。二硅烯-钯配合物与相应铂配合物的X射线结构参数对比表明钯配合物是金属环，但其π-配合物特征强于铂配合物。 关键词：二硅烯配合物，钯，铂，X-射线结构，金属环，π-络合物。
• Ligand dependence of π-complex character in disilene–palladium complexes
  作者：Takeaki Iwamoto、Yumiko Sekiguchi、Naoki Yoshida、Chizuko Kabuto、Mitsuo Kira

  DOI：10.1039/b512414j

  日期：——

  synthesis and structures of new 16-electron disilene palladium complexes with 2,6-dimethylphenyl isocyanide and phenyldimethylphosphine ligands [L1L2Pd(t-BuMe2Si)2SiSi(SiMe2Bu-t)2}, where L1 = L2 = PhMe2P; L1 = (cyclohexyl)3P, L2 = 2,6-dimethylphenyl isocyanide; L1 = L2 = 2,6-dimethylphenyl isocyanide] are described. Comparison of the X-ray structural parameters around the disilene moiety among these

  新的16电子的合成与结构 二烯 钯配合物 2,6-二甲基苯基异氰化物 和 苯基二甲基膦 配体[L 1 L 2 Pd （t- BuMe 2 Si）2 Si Si（SiMe 2 Bu- t）2 }，其中L 1 = L 2 = PhMe 2 P；L 1 =（环己基）3 P，L 2 =2,6-二甲基苯基异氰化物; L 1 = L 2 =2,6-二甲基苯基异氰化物]的描述。比较这些配合物与相关双（三甲基膦）（二烯）钯和14电子（三环己基膦）（二烯）钯中二烯成分周围的X射线结构参数，发现π配合物特征对残留物敏感配体 并随着σ捐赠强度的降低而增加。 配体。
• 14-Electron Disilene Palladium Complex Having Strong π-Complex Character
  作者：Mitsuo Kira、Yumiko Sekiguchi、Takeaki Iwamoto、Chizuko Kabuto

  DOI：10.1021/ja046354y

  日期：2004.10.1

  The first 14-electron disilene palladium complex eta2-[tetrakis(tert-butyldimethylsilyl)disilene](tricyclohexylphosphine)palladium (4) was synthesized. In the solid state, complex 4 has one tricyclohexylphosphine ligand bound unsymmetrically to the palladium center in regard to the eta2-disilene moiety. The elongation of the Si-Si bond length from that of the corresponding free disilene (3.2%) and the bent back angles of the disilene moiety (4.41 degrees and 9.65 degrees ) for 4 were much smaller than those for the corresponding 16-electron eta2-disilene complex (Me3P)2Pd[tetrakis(tert-butyldimethylsilyl)disilene] (4.6% and 27.2 degrees , respectively). Complex 4 is regarded as the complex having the strongest pi-complex character among the known disilene complexes. Highly symmetric NMR spectra were observed for 4; central Si1 and Si2 nuclei were equivalent and appeared as a doublet with 2J(29Si-31P) of 19 Hz, indicating facile flipping of the phosphine ligand in the Pd-Si-Si plane.
• Synthesis and X-ray Structure of a Platinum <i>η</i>²-Disilene Complex
  作者：Hisako Hashimoto、Yohei Sekiguchi、Takeaki Iwamoto、Chizuko Kabuto、Mitsuo Kira

  DOI：10.1021/om010914+

  日期：2002.2.1

  The platinum silyl-substituted eta(2)-disilene complex (Me3P)(2)Pt[Si(SiMe2(t-Bu))(2)](2) (4) was synthesized by the reaction of cis-(Me3P)(2)PtCl2 (5) with 1,2-dilithiotrakis(tert-butyldimethylsilyl)disilane (6) in THF at -50 degreesC for 3 h. The X-ray structural analysis revealed that 4 can be regarded as a metalladisilacyclopropane with very weak pi-complex character.