glioxalnitroguanidylosazone | 339193-64-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: glioxalnitroguanidylosazone
• 英文别名: 2,2'-(ethane-1,2-diylidene)bis(N'-nitrohydrazinecarboximidamide)；2-nitro-1-[2-[(N'-nitrocarbamimidoyl)hydrazinylidene]ethylideneamino]guanidine
• CAS: 339193-64-5
• 化学式: C₄H₈N₁₀O₄
• 分子量: 260.172
• InChiKey: GVQQLPFDPZNJMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.1
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  217
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  草酸醛 、 1-氨基-3-硝基胍 在 盐酸 作用下， 以 水 为溶剂， 反应 0.5h， 以93%的产率得到glioxalnitroguanidylosazone
  参考文献：
  名称：

  1-氨基-2-硝基胍与乙二醛的反应

  摘要：

  已经全面研究了在酸性和碱性催化条件下1-氨基-2-硝基胍与乙二醛的反应。得到的乙二醛二hydr，3-硝基氨基-1,2,4-三嗪钠盐，5-羟基-4,5-二氢-3-硝基氨基-1,2,4-三嗪及其5-烷氧基和5-氨基硝基胍衍生物（与1-氨基-2-硝基胍和醇反应的产物）已通过1 H，13 C– { 1 H} NMR，IR和UV光谱法进行了表征。

  DOI：

  10.1134/s1070363215110134

文献信息

• 2-Nitroguanidine derivatives: XI. Reactions of N′-nitrohydrazinecarboximidamide and 2-methylidene-N′-nitrohydrazinecarboximidamide with glyoxal
  作者：E. L. Metelkina

  DOI：10.1134/s1070428008040040

  日期：2008.4

  The reaction of glyoxal with N'-nitrohydrazinecarboximidamide (1-amino-2-nitroguanidine) in the presence of sodium hydroxide at a molar ratio of 1 : 1 : 1 gave N'-nitro-2-(2-oxoethylidene)hydrazinecarboximidamide as a mixture of syn and anti isomers, whereas at a reactant ratio of 1: 2:2 N'-nitro-2-[(5-nitroamino-2H-1,2,4-triazol-3-yl)methyl]hydrazinecarboximidamide and 3-nitroamino-4,5-dihydro-1,2,4-triazin-5-ol were formed. N'-Nitro-2-(2-oxoethylidene)hydrazinecarboximidamide reacted with N'-nitrohydrazinecarboximidamide in boiling ethanol to give N'-nitro-2-[(5-nitroamino-2H-1,2,4-triazol-3-yl)methyl]hydrazinecarboximidamide, while in glacial acetic acid 2,2'-(ethane-1,2-diylidene)bis(N'-nitrohydrazinecarboximidamide) was obtained. The latter was also formed in the reaction of glyoxal with N'-nitrohydrazinecarboximidamide in acetic acid at room temperature. The reaction of 2-methylidene-N'-nitrohydrazinecarboximidamide with glyoxal led to the formation of 3-nitroimino-2,3,4,5-tetrahydro-1,2,4-triazine-5-carbaldehyde or 1-(methylideneamino)-2-(nitroimino)imidazolidine-4,5-diol, depending on the conditions.
• Reactions of 1-amino-2-nitroguanidine with glyoxal
  作者：O. Yu. Ozerova、T. P. Efimova、T. A. Novikova、V. M. Berestovitskaya

  DOI：10.1134/s1070363215110134

  日期：2015.11

  The reactions of 1-amino-2-nitroguanidine with glyoxal under conditions of acidic and alkaline catalysis have been comprehensively studied. The obtained glyoxal dihydrazone, 3-nitroamino-1,2,4-triazine sodium salt, 5-hydroxy-4,5-dihydro-3-nitroamino-1,2,4-triazine, and its 5-alkoxy- and 5-aminonitroguanidyl derivatives (products of the reactions with 1-amino-2-nitroguanidine and alcohols) have been

  已经全面研究了在酸性和碱性催化条件下1-氨基-2-硝基胍与乙二醛的反应。得到的乙二醛二hydr，3-硝基氨基-1,2,4-三嗪钠盐，5-羟基-4,5-二氢-3-硝基氨基-1,2,4-三嗪及其5-烷氧基和5-氨基硝基胍衍生物（与1-氨基-2-硝基胍和醇反应的产物）已通过1 H，13 C– 1 H} NMR，IR和UV光谱法进行了表征。