methylcarbonyl(methylthiolato)(1,2-bis(diisopropylphosphino)ethane)platinium(II) | 1334109-51-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环戊烷
• 英文名称: methylcarbonyl(methylthiolato)(1,2-bis(diisopropylphosphino)ethane)platinium(II)
• 英文别名: (1,2-bis(diisopropylphosphino)ethane)Pt(C(O)Me)(SMe)；(dippe)Pt(C(O)Me)(SMe)
• CAS: 1334109-51-1
• 化学式: C₁₇H₃₈OP₂PtS
• 分子量: 547.582
• InChiKey: JQDQQMBBQAPUQO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  methylcarbonyl(methylthiolato)(1,2-bis(diisopropylphosphino)ethane)platinium(II) 以 further solvent(s) 为溶剂， 生成 bis(ethylthiolato)(1,2-bis(diisopropylphosphino)ethane)platinum(II)
  参考文献：
  名称：

  C–S Bond Activation of Thioesters Using Platinum(0)

  摘要：

  C-S bond activation of both cyclic and acyclic thioesters using (dippe)Pt(NBE)(2) (NBE = norbomene) are reported. In the cases of S-methyl thio acetate and S-ethyl thioacetate, (dippe)Pt(C(O)Me)(SR) (R = Me, Et) formed initially. Further heating in the presence of excess thioester led to formation of the final complex (dippe)Pt(SR)(2) along with acetone and RSMe as organic side products. Pt(IV) intermediates are proposed to be involved in the reaction mechanism.

  DOI：

  10.1021/om200452z
• 作为产物：
  描述：

  硫代乙酸甲酯 、 (dippe)Pt(norbornene)₂ 以 氘代苯 为溶剂， 以87%的产率得到methylcarbonyl(methylthiolato)(1,2-bis(diisopropylphosphino)ethane)platinium(II)
  参考文献：
  名称：

  C–S Bond Activation of Thioesters Using Platinum(0)

  摘要：

  C-S bond activation of both cyclic and acyclic thioesters using (dippe)Pt(NBE)(2) (NBE = norbomene) are reported. In the cases of S-methyl thio acetate and S-ethyl thioacetate, (dippe)Pt(C(O)Me)(SR) (R = Me, Et) formed initially. Further heating in the presence of excess thioester led to formation of the final complex (dippe)Pt(SR)(2) along with acetone and RSMe as organic side products. Pt(IV) intermediates are proposed to be involved in the reaction mechanism.

  DOI：

  10.1021/om200452z