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4,6,10,12,16,18,11,24-octahydroxy-2,8,14,20-tetranonyl-5,11,17,23-tetrakis(piperidino)methylcalix[4]arene | 393510-89-9

中文名称
——
中文别名
——
英文名称
4,6,10,12,16,18,11,24-octahydroxy-2,8,14,20-tetranonyl-5,11,17,23-tetrakis(piperidino)methylcalix[4]arene
英文别名
2,8,14,20-Tetra(nonyl)-5,11,17,23-tetrakis(piperidin-1-ylmethyl)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol;2,8,14,20-tetra(nonyl)-5,11,17,23-tetrakis(piperidin-1-ylmethyl)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol
4,6,10,12,16,18,11,24-octahydroxy-2,8,14,20-tetranonyl-5,11,17,23-tetrakis(piperidino)methylcalix[4]arene化学式
CAS
393510-89-9
化学式
C88H140N4O8
mdl
——
分子量
1382.1
InChiKey
JLOWKKDAKMTVHK-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    26.2
  • 重原子数:
    100
  • 可旋转键数:
    40
  • 环数:
    9.0
  • sp3杂化的碳原子比例:
    0.73
  • 拓扑面积:
    175
  • 氢给体数:
    8
  • 氢受体数:
    12

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为反应物:
    参考文献:
    名称:
    摘要:
    The electrochemical oxidation of a number of aminomethylated calix[4]resorcinarenes (AMC) with different substituents at the nitrogen atom and the kinetics of nucleophilic substitution reactions of these compounds with p-nitrophenyl bis(chloromethyl)phosphinate were studied. The reactivity of the ionic associates of AMC in the nucleophilic substitution and the behavior of AMC in electrooxidation are determined by the same factors, namely, the amino-roup basicity and the nature of the substituents at the nitrogen atom. These factors influence the ratio of the zwitter-ionic and anionic forms of AMC.
    DOI:
    10.1023/a:1024713408780
  • 作为产物:
    描述:
    哌啶tetranonylcalix[4]recorcinolarene聚合甲醛乙醇 为溶剂, 反应 22.5h, 以75%的产率得到4,6,10,12,16,18,11,24-octahydroxy-2,8,14,20-tetranonyl-5,11,17,23-tetrakis(piperidino)methylcalix[4]arene
    参考文献:
    名称:
    氨甲基化杯[4]间苯二酚与磷酸酯反应的质子分解特性和反应性
    摘要:
    用电位计、紫外分光光度法研究了氨甲基化杯[4]间苯二酚(AMC)与磷酸的对硝基苯酯在丙-2-醇(80 vol.% PriOH)水溶液中的酸碱性质和反应动力学和 31 P NMR 光谱。研究了烃基的长度和氮原子上的取代基对AMC的质子分解性质和反应活性的影响。所研究的反应分两个阶段进行。在第一阶段,形成磷酸化的 AMC,在第二阶段水解成相应的酸。
    DOI:
    10.1007/bf02496160
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文献信息

  • Protolytic properties and reactivity of aminomethylated calix[4]resorcarenes in reactions with esters of phosphorus acids
    作者:I. S. Ryzhkina、L. A. Kudryavtseva、A. R. Mustafina、Yu. E. Morozova、E. Kh. Kazakova、K. M. Enikeev、A. I. Konovalov
    DOI:10.1007/bf02496160
    日期:1999.3
    acid-base properties and the kinetics of reactions of aminomethylated calix[4]resorcarenes (AMC) withp-nitrophenyl esters of phosphorus acids in aqueous solutions of propan-2-ol (80 vol.% PriOH) were studied by potentiometry, UV spectrophotometry, and31P NMR spectroscopy. The effect of the length of the hydrocarbon radical and substituents at the nitrogen atom on the protolytic properties and reactivity
    用电位计、紫外分光光度法研究了氨甲基化杯[4]间苯二酚(AMC)与磷酸的对硝基苯酯在丙-2-醇(80 vol.% PriOH)水溶液中的酸碱性质和反应动力学和 31 P NMR 光谱。研究了烃基的长度和氮原子上的取代基对AMC的质子分解性质和反应活性的影响。所研究的反应分两个阶段进行。在第一阶段,形成磷酸化的 AMC,在第二阶段水解成相应的酸。
  • ——
    作者:V. V. Yanilkin、I. S. Ryzhkina、N. V. Nastapova、T. N. Pashirova、Ya. A. Babkina、A. R. Burilov、V. I. Morozov、A. I. Konovalov
    DOI:10.1023/a:1024713408780
    日期:——
    The electrochemical oxidation of a number of aminomethylated calix[4]resorcinarenes (AMC) with different substituents at the nitrogen atom and the kinetics of nucleophilic substitution reactions of these compounds with p-nitrophenyl bis(chloromethyl)phosphinate were studied. The reactivity of the ionic associates of AMC in the nucleophilic substitution and the behavior of AMC in electrooxidation are determined by the same factors, namely, the amino-roup basicity and the nature of the substituents at the nitrogen atom. These factors influence the ratio of the zwitter-ionic and anionic forms of AMC.
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