1,1-Bis[2-[(2-hydroxynaphthalen-1-yl)methylideneamino]ethyl]-3-(4-nitrophenyl)urea | 1418297-85-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1-Bis[2-[(2-hydroxynaphthalen-1-yl)methylideneamino]ethyl]-3-(4-nitrophenyl)urea
• CAS: 1418297-85-4
• 化学式: C₃₃H₂₉N₅O₅
• 分子量: 575.624
• InChiKey: HSOVLXLWAIOLJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  43
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  143
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2-羟基-1-萘甲醛 以 乙醇 、 二氯甲烷 为溶剂， 反应 24.0h， 生成 1,1-Bis[2-[(2-hydroxynaphthalen-1-yl)methylideneamino]ethyl]-3-(4-nitrophenyl)urea
  参考文献：
  名称：

  ‘Naked-eye’ detection of F− ions by two novel colorimetric receptors

  摘要：

  Two novel colorimetric receptors, S1 and S2, linked to one or two nitrophenylurea groups were synthesized in good yields, characterized and their chromogenic properties investigated towards various anions (F-, Cl-, Br-, I-, NO3-, AcO-, ClO4-, HSO4-, and H2PO4-) by UV-vis and H-1 NMR techniques. The receptors, effectively and selectively, recognized and distinguished the biologically important F- from other anions such as Cl-, Br-, I- etc. in CH3CN. This selectivity could be easily observed by the naked eye, indicating that receptors S1 and S2 are potential colorimetric sensors for fluoride ion. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.138