(tert-Butoxy)-diaethyl-silan | 18246-51-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (tert-Butoxy)-diaethyl-silan
• 英文别名: Diaethyl-(t)-butoxy-silan；Diethyl-[(2-methylpropan-2-yl)oxy]silane
• CAS: 18246-51-0
• 化学式: C₈H₂₀OSi
• 分子量: 160.332
• InChiKey: BSYHKFRUZBIPPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.57
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯乙烯 、 (tert-Butoxy)-diaethyl-silan 在 降冰片烯 、 RuH₂(CO)(PPh₃)₃ 作用下， 以 甲苯 为溶剂， 以85 %的产率得到(E)-tert-butoxydiethyl(styryl)silane
  参考文献：
  名称：

  钌催化脱氢分子间 OH/Si-H/CH 硅烷化：(E)-烯基甲硅烷基醚和甲硅烷基醚杂环的合成

  摘要：

  选择性脱氢硅烷化是合成有机硅化合物最有价值的工具之一。在这项研究中，首先开发了一种区域和立体选择性钌催化的脱氢分子间硅烷化反应，以获得具有良好官能团耐受性的(E)-烯基甲硅烷基醚衍生物和甲硅烷基醚杂环。此外，以H2SiEt2为氢硅烷试剂，研究了RuH2(CO)(PPh3)3/NBE催化的醇和烯烃的脱氢分子间硅烷化以及萘酚衍生物的分子间硅烷化的两种途径。

  DOI：

  10.3390/molecules28207186
• 作为产物：
  描述：

  Chlor--diaethyl-silan 在 lithium tri-t-butoxyaluminum hydride 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 生成 (tert-Butoxy)-diaethyl-silan
  参考文献：
  名称：

  Jirinec,S. et al., Collection of Czechoslovak Chemical Communications, 1961, vol. 26, p. 1815 - 1825

  摘要：

  DOI：

文献信息

• Radiochemical study of the gas phase reaction of nucleogenic diethylsilylium ions with methanol and butanol
  作者：T.A. Kochina、D.V. Vrazhnov、I.S. Ignatyev

  DOI：10.1016/s0022-328x(02)01625-x

  日期：2002.8

  The gas phase ion-molecule reactions between alcohols (methanol and n-butanol) and nucleogenic diethylsilylium ions generated by the beta-decay of the tritiated diethylsilane were studied by the radiochromatographic method. Among the labelled neutral products of the silylation of alcohols diethylsilylalkoxysilanes exhibit the major yield. Diethyl-butoxysilane contains not only n-butyl groups as in the substrate (21%), but also small amounts of s-butyl (5%) and t-butyl (7%) groups. In other alkoxysilanes the diethylsilyl group of the nascent nucleogenic cation is rearranged and isomerized. Products with the similar distribution of the silylium group isomers were observed earlier in the reaction of benzene, however the yield of the products with rearranged silylium groups was substantially greater for benzene. This difference in the yield of the products with rearranged sitylium groups between benzene and alcohols is rationalized taking into account the more acidic character of the proton in the adduct oxonium ions. (C) 2002 Elsevier Science B.V. All rights reserved.
• Jirinec,S. et al., Collection of Czechoslovak Chemical Communications, 1961, vol. 26, p. 1815 - 1825
  作者：Jirinec,S. et al.

  DOI：——

  日期：——
• Ruthenium-Catalyzed Dehydrogenative Intermolecular O-H/Si-H/C-H Silylation: Synthesis of (E)-Alkenyl Silyl-Ether and Silyl-Ether Heterocycle
  作者：Ziwei Huang、Qiao Lin、Jiefang Li、Shanshan Xu、Shaohuan Lv、Feng Xie、Jun Wang、Bin Li

  DOI：10.3390/molecules28207186

  日期：——

  Selective dehydrogenative silylation is one of the most valuable tools for synthesizing organosilicon compounds. In this study, a regio- and stereoselective ruthenium-catalyzed dehydrogenative intermolecular silylation was firstly developed to access (E)-alkenyl silyl-ether derivatives and silyl-ether heterocycles with good functional group tolerance. Furthermore, two pathways for RuH2(CO)(PPh3)3/NBE-catalyzed

  选择性脱氢硅烷化是合成有机硅化合物最有价值的工具之一。在这项研究中，首先开发了一种区域和立体选择性钌催化的脱氢分子间硅烷化反应，以获得具有良好官能团耐受性的(E)-烯基甲硅烷基醚衍生物和甲硅烷基醚杂环。此外，以H2SiEt2为氢硅烷试剂，研究了RuH2(CO)(PPh3)3/NBE催化的醇和烯烃的脱氢分子间硅烷化以及萘酚衍生物的分子间硅烷化的两种途径。