| 932750-91-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• CAS: 932750-91-9
• 化学式: C₃₄H₅₀N₁₀O₄Yb
• 分子量: 835.876
• InChiKey: GLQJWDLQGIJSKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 以 乙醇 为溶剂， 以80%的产率得到[Yb((CH₃)2NC(O)CH₂N(C₂H₄N(CH₂C(O)N(CH₃)2)C₂H₄)2NCH₂C(O)NHC₁₂H₇N₂)Ru(2,2'-bipyridine)2]⁽⁵⁺⁾
  参考文献：
  名称：

  Sensitized Near-Infrared Lanthanide Luminescence from Nd(III)- and Yb(III)-Based Cyclen−Ruthenium Coordination Conjugates

  摘要：

  The development of novel mixed lanthanide-transition-metal (f-d) based supramolecular self-assemblies made from neodymium-and ytterbium-based tetraamide-functionalized cyclen complexes bearing a single 1,10-phenanthroline moiety coordinating to a Ru-II-(bipy)(2) (bipy = bipyridine) unit is described. Excitation of the Ru(II) metal-to-ligand charge-transfer band in water gave rise to long-wavelength sensitized emission from the Yb(III) or Nd(III) centers, observed in the near-infrared.

  DOI：

  10.1021/ic061706i
• 作为产物：
  描述：

  ytterbium(III) triflate 、 N-[1,10]-phenanthrolin-5-yl-2-(4,7,10-tris-dimethylcarbamoylmethyl-1,4,7,10-tetraaza-cyclododec-1-yl)-acetamide 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Sensitized Near-Infrared Lanthanide Luminescence from Nd(III)- and Yb(III)-Based Cyclen−Ruthenium Coordination Conjugates

  摘要：

  The development of novel mixed lanthanide-transition-metal (f-d) based supramolecular self-assemblies made from neodymium-and ytterbium-based tetraamide-functionalized cyclen complexes bearing a single 1,10-phenanthroline moiety coordinating to a Ru-II-(bipy)(2) (bipy = bipyridine) unit is described. Excitation of the Ru(II) metal-to-ligand charge-transfer band in water gave rise to long-wavelength sensitized emission from the Yb(III) or Nd(III) centers, observed in the near-infrared.

  DOI：

  10.1021/ic061706i

文献信息

• Mixed f−d Coordination Complexes as Dual Visible- and Near-Infrared-Emitting Probes for Targeting DNA
  作者：Aline M. Nonat、Susan J. Quinn、Thorfinnur Gunnlaugsson

  DOI：10.1021/ic900422z

  日期：2009.6.1

  A new family of mixed-lanthanide (Yb-III and Nd-III) transition-metal (f-d) cyclen-Ru-II(phen)(3) (phen = 1,10-phenanthroline) complexes were synthesized as dual visible- and near-infrared (NIR)-emitting DNA probes/sensors. Significant changes were seen in both the Ru-II visible and the Yb-III-centered NIR emission, which was switched off upon binding to DNA at pH 7.4. In contrast, no changes were seen in the Nd-III emission of the analogue f-d conjugate.